Towards predicting the power conversion efficiencies of organic solar cells from donor and acceptor molecule structures

2018 ◽  
Vol 6 (13) ◽  
pp. 3276-3287 ◽  
Author(s):  
Yecheng Zhou ◽  
Guankui Long ◽  
Ailin Li ◽  
Angus Gray-Weale ◽  
Yongsheng Chen ◽  
...  

In this study, we developed a multiscale simulation framework to estimate the power conversion efficiencies of bulk heterojunction organic solar cells only based on the molecular structures of the donor and acceptor.

2020 ◽  
Vol 8 (4) ◽  
pp. 1475-1476
Author(s):  
Yecheng Zhou ◽  
Guankui Long ◽  
Ailin Li ◽  
Angus Gray-Weale ◽  
Yongsheng Chen ◽  
...  

Correction for ‘Towards predicting the power conversion efficiencies of organic solar cells from donor and acceptor molecule structures’ by Yecheng Zhou et al., J. Mater. Chem. C, 2018, 6, 3276–3287.


2021 ◽  
Author(s):  
Haifen Liu ◽  
Zixuan Zhu ◽  
Huafeng Li ◽  
Weili Fan ◽  
Kaihua Ning ◽  
...  

Non-fullerene acceptors have received a great deal of attention over the past several years, and numerous modifications on the molecular structures significantly boosted the power conversion efficiencies (PCEs). To be...


2021 ◽  
Author(s):  
Zhaofan Yang ◽  
Shijie Liang ◽  
Baiqiao Liu ◽  
Jing Wang ◽  
Fan Yang ◽  
...  

Single-component organic solar cells (SCOSCs) have been recognized as the promising photovoltaic technology due to the excellent stability, but their power conversion efficiencies (PCEs) are far lagging their bulk-heterojunction counterparts....


2013 ◽  
Vol 4 ◽  
pp. 680-689 ◽  
Author(s):  
Gisela L Schulz ◽  
Marta Urdanpilleta ◽  
Roland Fitzner ◽  
Eduard Brier ◽  
Elena Mena-Osteritz ◽  
...  

The optimization of solution-processed organic bulk-heterojunction solar cells with the acceptor-substituted quinquethiophene DCV5T-Bu 4 as donor in conjunction with PC61BM as acceptor is described. Power conversion efficiencies up to 3.0% and external quantum efficiencies up to 40% were obtained through the use of 1-chloronaphthalene as solvent additive in the fabrication of the photovoltaic devices. Furthermore, atomic force microscopy investigations of the photoactive layer gave insight into the distribution of donor and acceptor within the blend. The unique combination of solubility and thermal stability of DCV5T-Bu 4 also allows for fabrication of organic solar cells by vacuum deposition. Thus, we were able to perform a rare comparison of the device characteristics of the solution-processed DCV5T-Bu 4 :PC61BM solar cell with its vacuum-processed DCV5T-Bu 4 :C60 counterpart. Interestingly in this case, the efficiencies of the small-molecule organic solar cells prepared by using solution techniques are approaching those fabricated by using vacuum technology. This result is significant as vacuum-processed devices typically display much better performances in photovoltaic cells.


2015 ◽  
Vol 3 (47) ◽  
pp. 23905-23916 ◽  
Author(s):  
Michèle Chevrier ◽  
Judith E. Houston ◽  
Jurgen Kesters ◽  
Niko Van den Brande ◽  
Ann E. Terry ◽  
...  

Conjugated polyelectrolyte–surfactant cathodic interface layers lead to improved power conversion efficiencies in organic solar cells.


2015 ◽  
Vol 8 (2) ◽  
pp. 520-525 ◽  
Author(s):  
Jingbo Zhao ◽  
Yunke Li ◽  
Haoran Lin ◽  
Yuhang Liu ◽  
Kui Jiang ◽  
...  

Non-fullerene organic solar cells with power conversion efficiencies of up to 6.3% are reported using properly matched donor and acceptor.


2018 ◽  
Vol 2018 ◽  
pp. 1-6 ◽  
Author(s):  
Hardeep Singh Gill ◽  
Lian Li ◽  
Haizhou Ren ◽  
Ravi Mosurkal ◽  
Jayant Kumar

The effect of nanoimprinted structures on the performance of organic bulk heterojunction solar cells was investigated. The nanostructures were formed over the active layer employing the soft lithographic technique. The measured incident photon-to-current efficiency revealed that the nanostructured morphology over the active layer can efficiently enhance both light harvesting and charge carrier collection due to improvement of the absorption of incident light and the buried nanostructured cathode, respectively. The devices prepared with the imprinted nanostructures exhibited significantly higher power conversion efficiencies as compared to those of the control cells.


2014 ◽  
Vol 2 (1) ◽  
Author(s):  
Simon Steinberger ◽  
Amaresh Mishra ◽  
Gisela Schulz ◽  
Christian Uhrich ◽  
Martin Pfeiffer ◽  
...  

AbstractThe electron-deficient, fused-heterocyclebenzo[c][1,2,5]thiadiazole (BTDA) is investigated as acceptor group in A-D-A-type oligothiophenes in order to correlate their relative acceptor strength with opto-electronic and photovoltaic properties. In this respect, two novel BDTA-capped oligothiopheneswere synthesized and characterized by optical and electrochemical measurements. They showed broad absorptions in the visible spectrum and HOMO-LUMO energies well suited for organic solar cells. The attachment of terminal BTDA acceptor units to the conjugated oligothiophene backbone resulted in a hypsochromic shift in UV-Vis absorption and larger band gap in comparison to previously reported analogous dicyanovinylene (DCV)-substituted oligothiophenes indicating that BDTA is a weaker acceptor than DCV. Vacuumprocessed m-i-p (metal-intrinsic-p-doped)-type bilayer solar cells using these co-oligomers as donor and C60 as acceptor gave moderate power conversion efficiencies of around 1.0%. Bulk-heterojunction (BHJ) solar cells prepared by solution-processing using fullerene PC61BM as acceptor generated slightly lower efficiencies of 0.9%, whichwere increased to 1.5% by using the higher fullerene PC71BM. It was found that the cell efficiencies were mostly limited by the low photocurrent densities due to moderate light absorption in the bilayer devices and low fill factors coming from inefficient charge transport in the solutionprocessed BHJ devices.


RSC Advances ◽  
2015 ◽  
Vol 5 (112) ◽  
pp. 92312-92317 ◽  
Author(s):  
Liangang Xiao ◽  
Chang Liu ◽  
Ke Gao ◽  
Yajing Yan ◽  
Junbiao Peng ◽  
...  

Fabricated with non-halogenated solvents toluene and o-xylene, the bulk-heterojunction organic solar cells based on a porphyrin small molecule show high power conversion efficiencies up to 5.46% and 5.85%, respectively.


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