Combining 2D inorganic semiconductors and organic polymers at the frontier of the hard–soft materials interface

2017 ◽  
Vol 5 (43) ◽  
pp. 11158-11164 ◽  
Author(s):  
A. Ramasubramaniam ◽  
R. Selhorst ◽  
H. Alon ◽  
M. D. Barnes ◽  
T. Emrick ◽  
...  

Recent advances in combining functional organic polymers with inorganic 2D semiconductors for nanoscale electronics are highlighted.

Author(s):  
Rongchang Luo ◽  
Min Chen ◽  
Farong Zhou ◽  
Jiamin Zhan ◽  
Qi Deng ◽  
...  

This review summarized the recent advances made in the task-specific design and synthesis of metalloporphyrin-based porous organic polymers (POPs) and their functionalization for conversion of CO2 into cyclic carbonates.


2019 ◽  
Vol 23 ◽  
pp. 106-114 ◽  
Author(s):  
Nicholas E Jackson ◽  
Michael A Webb ◽  
Juan J de Pablo

2020 ◽  
Vol 12 (02) ◽  
pp. 2050014 ◽  
Author(s):  
Rong Huang ◽  
Shoujing Zheng ◽  
Zishun Liu ◽  
Teng Yong Ng

Hydrogels and shape memory polymers (SMPs) possess excellent and interesting properties that may be harnessed for future applications. However, this is not achievable if their mechanical behaviors are not well understood. This paper aims to discuss recent advances of the constitutive models of hydrogels and SMPs, in particular the theories associated with their deformations. On the one hand, constitutive models of six main types of hydrogels are introduced, the categorization of which is defined by the type of stimulus. On the other hand, constitutive models of thermal-induced SMPs are discussed and classified into three main categories, namely, rheological models; phase transition models; and models combining viscoelasticity and phase transition, respectively. Another feature in this paper is a summary of the common hyperelastic models, which can be potentially developed into the constitutive models of hydrogels and SMPs. In addition, the main advantages and disadvantages of these constitutive modes are discussed. In order to provide a compass for researchers involved in the study of mechanics of soft materials, some research gaps and new research directions for hydrogels and SMPs constitutive modes are presented. We hope that this paper can serve as a reference for future hydrogel and SMP studies.


ChemInform ◽  
2014 ◽  
Vol 45 (37) ◽  
pp. no-no
Author(s):  
Prospero J. Taroni ◽  
Itziar Hoces ◽  
Natalie Stingelin ◽  
Martin Heeney ◽  
Emiliano Bilotti

2016 ◽  
Vol 83 (8) ◽  
Author(s):  
Xianhong Meng ◽  
Boya Liu ◽  
Yu Wang ◽  
Taihua Zhang ◽  
Jianliang Xiao

In flexible electronics, multilayer hard/soft materials are widely used to utilize both the superior electrical properties of inorganic semiconductors and robust mechanical properties of polymers simultaneously. However, the huge mismatch in mechanical properties of the hard and soft materials makes mechanics analysis challenging. We here present an analytical model to study the mechanics of multilayer hard/soft materials in flexible electronics. Third-order polynomials are adopted to describe the displacement field, which can be used to easily derive both strain and stress fields. Then, the principle of virtual work was used to derive the governing equations and boundary conditions, which can be solved numerically. Two types of loadings, pure bending and transverse shear, are studied. The normal strain distributions along thickness direction in the bimaterial regions clearly show zigzag profiles, due to the huge mismatch in the mechanical properties of the hard and soft materials. The effect of very different mechanical properties of the hard and soft materials on shear stress distributions can also be predicted by this model. The results from this analytical mode show good agreement with finite-element modeling (FEM). This model can be useful in systems with multilayer hard/soft materials, to predict mechanical behavior and to guide design and optimization.


2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Feng Li ◽  
Tao Shen ◽  
Cong Wang ◽  
Yupeng Zhang ◽  
Junjie Qi ◽  
...  

AbstractThe development of two-dimensional (2D) semiconductors has attracted widespread attentions in the scientific community and industry due to their ultra-thin thickness, unique structure, excellent optoelectronic properties and novel physics. The excellent flexibility and outstanding mechanical strength of 2D semiconductors provide opportunities for fabricated strain-sensitive devices and utilized strain tuning their electronic and optic–electric performance. The strain-engineered one-dimensional materials have been well investigated, while there is a long way to go for 2D semiconductors. In this review, starting with the fundamental theories of piezoelectric and piezoresistive effect resulted by strain, following we reviewed the recent simulation works of strain engineering in novel 2D semiconductors, such as Janus 2D and 2D-Xene structures. Moreover, recent advances in experimental observation of strain tuning PL spectra and transport behavior of 2D semiconductors are summarized. Furthermore, the applications of strain-engineered 2D semiconductors in sensors, photodetectors and nanogenerators are also highlighted. At last, we in-depth discussed future research directions of strain-engineered 2D semiconductor and related electronics and optoelectronics device applications.


Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 909 ◽  
Author(s):  
Yinhang Zhang ◽  
Soo-Jin Park

In the past few decades, organic thermoelectric materials/devices, which can exhibit remarkable potential in green energy conversion, have drawn great attention and interest due to their easy processing, light weight, intrinsically low thermal conductivity, and mechanical flexibility. Compared to traditional batteries, thermoelectric materials have high prospects as alternative power generators for harvesting green energy. Although crystalline inorganic semiconductors have dominated the fields of thermoelectric materials up to now, their practical applications are limited by their intrinsic fragility and high toxicity. The integration of organic polymers with inorganic nanoparticles has been widely employed to tailor the thermoelectric performance of polymers, which not only can combine the advantages of both components but also display interesting transport phenomena between organic polymers and inorganic nanoparticles. In this review, parameters affecting the thermoelectric properties of materials were briefly introduced. Some recently developed n-type and p-type thermoelectric films and related devices were illustrated along with their thermoelectric performance, methods of preparation, and future applications. This review will help beginners to quickly understand and master basic knowledge of thermoelectric materials, thus inspiring them to design and develop more efficient thermoelectric devices.


2018 ◽  
Vol 47 (46) ◽  
pp. 16377-16387 ◽  
Author(s):  
Oxana Kotova ◽  
Samuel J. Bradberry ◽  
Aramballi J. Savyasachi ◽  
Thorfinnur Gunnlaugsson

Here we discuss the emerging field of luminescent lanthanide-based soft materials with our focus on the different approaches used for their design and synthesis as well as manipulations of their functional properties.


Nanoscale ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 1281-1306 ◽  
Author(s):  
Jun Li ◽  
Wai-Yeung Wong ◽  
Xiao-ming Tao

This review discusses the recent progress of three kinds of soft materials, namely gels, foams and elastomers, with emphasis on materials, properties and applications in flexible sensors, soft actuators, energy convention and storage.


2013 ◽  
Vol 58 (24) ◽  
pp. 2352-2359
Author(s):  
Qi CHEN ◽  
BaoHang HAN ◽  
YanChao ZHAO ◽  
DePeng LIU

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