scholarly journals Luminescence control in hybrid perovskites and their applications

2017 ◽  
Vol 5 (17) ◽  
pp. 4098-4110 ◽  
Author(s):  
Josep Albero ◽  
Hermenegildo García
Keyword(s):  
Metal Halide ◽  
Luminescence Properties ◽  
Light Emitting ◽  
Composition Design ◽  
Light Emitting Devices ◽  
Halide Perovskites

Hybrid metal halide perovskites have emerged as promising photoluminescence materials in efficient light emitting devices and lasing applications. The review focus on the perovskite composition design as a tool to modulate the luminescence properties.

Metal-halide perovskites for photovoltaic and light-emitting devices

2015 ◽  
Vol 10 (5) ◽  
pp. 391-402 ◽  
Author(s):  
Samuel D. Stranks ◽  
Henry J. Snaith
Keyword(s):  
Metal Halide ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Halide Perovskites

Stable down-conversion white light-emitting devices based on highly luminescent copper halides synthesized at room temperature

2021 ◽  
Author(s):  
Lintao Wang ◽  
Zhuang zhuang Ma ◽  
Fei Zhang ◽  
Meng Wang ◽  
Xu Chen ◽  
...  
Keyword(s):  
Solid State ◽  
White Light ◽  
Room Temperature ◽  
Metal Halide ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Halide Perovskites ◽  
Commercial Applications ◽  
Copper Halides ◽  
Down Conversion

As a newly-emerging candidate for solid-state phosphors, metal-halide perovskites have attracted intensive attention in the field of white light-emitting devices (WLEDs) recently. However, their further commercial applications are severely hampered...

scholarly journals Photostable and Uniform CH3NH3PbI3 Perovskite Film Prepared via Stoichiometric Modification and Solvent Engineering

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 405
Author(s):  
Daocheng Hong ◽  
Mingyi Xie ◽  
Yuxi Tian
Keyword(s):  
Solar Cells ◽  
Optoelectronic Devices ◽  
Solvent Engineering ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Coverage Ratio ◽  
Fabrication Procedure ◽  
Fabrication Condition ◽  
Halide Perovskites ◽  
Photoluminescence Efficiency

Solution-processed organometal halide perovskites (OMHPs) have been widely used in optoelectronic devices, and have exhibited brilliant performance. One of their generally recognized advantages is their easy fabrication procedure. However, such a procedure also brings uncertainty about the opto-electric properties of the final samples and devices, including morphology, stability, coverage ratio, and defect concentration. Normally, one needs to find a balanced condition, because there is a competitive relation between these parameters. In this work, we fabricated CH3NH3PbI3 films by carefully changing the ratio of the PbI2 to CH3NH3I, and found that the stoichiometric and solvent engineering not only determined the photoluminescence efficiency and defects in the materials, but also affected the photostability, morphology, and coverage ratio. Combining solvent engineering and the substitution of PbI2 by Pb(Ac)2, we obtained an optimized fabrication condition, providing uniform CH3NH3PbI3 films with both high photoluminescence efficiency and high photostability under either I-rich or Pb-rich conditions. These results provide an optimized fabrication procedure for CH3NH3PbI3 and other OMHP films, which is crucial for the performance of perovskite-based solar cells and light emitting devices.

scholarly journals Origin of unusual bandgap shift and dual emission in organic-inorganic lead halide perovskites

2016 ◽  
Vol 2 (10) ◽  
pp. e1601156 ◽  
Author(s):  
M. Ibrahim Dar ◽  
Gwénolé Jacopin ◽  
Simone Meloni ◽  
Alessandro Mattoni ◽  
Neha Arora ◽  
...  
Keyword(s):  
Density Functional ◽  
Valence Band Maximum ◽  
Dual Emission ◽  
Time Resolved ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Perovskite Materials ◽  
Halide Perovskites ◽  
Dynamics Simulations ◽  
Increasing Temperature

Emission characteristics of metal halide perovskites play a key role in the current widespread investigations into their potential uses in optoelectronics and photonics. However, a fundamental understanding of the molecular origin of the unusual blueshift of the bandgap and dual emission in perovskites is still lacking. In this direction, we investigated the extraordinary photoluminescence behavior of three representatives of this important class of photonic materials, that is, CH3NH3PbI3, CH3NH3PbBr3, and CH(NH2)2PbBr3, which emerged from our thorough studies of the effects of temperature on their bandgap and emission decay dynamics using time-integrated and time-resolved photoluminescence spectroscopy. The low-temperature (<100 K) photoluminescence of CH3NH3PbI3and CH3NH3PbBr3reveals two distinct emission peaks, whereas that of CH(NH2)2PbBr3shows a single emission peak. Furthermore, irrespective of perovskite composition, the bandgap exhibits an unusual blueshift by raising the temperature from 15 to 300 K. Density functional theory and classical molecular dynamics simulations allow for assigning the additional photoluminescence peak to the presence of molecularly disordered orthorhombic domains and also rationalize that the unusual blueshift of the bandgap with increasing temperature is due to the stabilization of the valence band maximum. Our findings provide new insights into the salient emission properties of perovskite materials, which define their performance in solar cells and light-emitting devices.

Tunable ultra-uniform Cs4PbBr6 perovskites with efficient photoluminescence and excellent stability for high-performance white light-emitting diodes

2021 ◽  
Author(s):  
Yao Li ◽  
Kaimin Du ◽  
Manli Zhang ◽  
Xuan Gao ◽  
Yu Lu ◽  
...  
Keyword(s):  
White Light ◽  
High Performance ◽  
Light Emitting Diodes ◽  
Metal Halide ◽  
Light Emitting ◽  
New Class ◽  
Halide Perovskites ◽  
White Light Emitting Diodes ◽  
Lead Halide ◽  
Excellent Stability

Metal halide perovskites are a new class of promising materials in optoelectronic applications. As optoelectronic properties of the lead halide perovskites are determined largely by their morphology, the morphology of...

Mixed Dimensional 0D/3D Perovskite Heterostructure for Efficient Green Light Emitting Diodes

2021 ◽  
Author(s):  
Lyuchao Zhuang ◽  
Lingling Zhai ◽  
Yanyong Li ◽  
Ren Hui ◽  
Mingjie Li ◽  
...  
Keyword(s):  
Light Emitting Diodes ◽  
Optoelectronic Devices ◽  
Green Light ◽  
Metal Halide ◽  
Next Generation ◽  
Light Emitting ◽  
Photoelectric Characteristics ◽  
Halide Perovskites

Metal halide perovskites are emerging materials for next-generation optoelectronic devices, of which all-inorganic CsPbBr3 perovskite has attracted increasing attention due to outstanding stability and excellent photoelectric characteristics compared with organic-inorganic...

scholarly journals The dark exciton ground state promotes photon-pair emission in individual perovskite nanocrystals

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Philippe Tamarat ◽  
Lei Hou ◽  
Jean-Baptiste Trebbia ◽  
Abhishek Swarnkar ◽  
Louis Biadala ◽  
...  
Keyword(s):  
Near Infrared ◽  
Exciton State ◽  
Lead Iodide ◽  
Electron Hole ◽  
Light Emitting ◽  
Perovskite Nanocrystals ◽  
Light Emitting Devices ◽  
Optical And Electronic Properties ◽  
Wide Range ◽  
Halide Perovskites

AbstractCesium lead halide perovskites exhibit outstanding optical and electronic properties for a wide range of applications in optoelectronics and for light-emitting devices. Yet, the physics of the band-edge exciton, whose recombination is at the origin of the photoluminescence, is not elucidated. Here, we unveil the exciton fine structure of individual cesium lead iodide perovskite nanocrystals and demonstrate that it is governed by the electron-hole exchange interaction and nanocrystal shape anisotropy. The lowest-energy exciton state is a long-lived dark singlet state, which promotes the creation of biexcitons at low temperatures and thus correlated photon pairs. These bright quantum emitters in the near-infrared have a photon statistics that can readily be tuned from bunching to antibunching, using magnetic or thermal coupling between dark and bright exciton sublevels.

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