Interfacial engineering via inserting functionalized water-soluble fullerene derivative interlayers for enhancing the performance of perovskite solar cells

2018 ◽  
Vol 6 (8) ◽  
pp. 3435-3443 ◽  
Author(s):  
Tiantian Cao ◽  
Peng Huang ◽  
Kaicheng Zhang ◽  
Ziqi Sun ◽  
Kai Zhu ◽  
...  

Two novel fullerene derivatives were synthesized and utilized as buffer layers in perovskite solar cells for the first time.

2017 ◽  
Vol 9 (44) ◽  
pp. 38530-38536 ◽  
Author(s):  
Tin Kang ◽  
Cheng-Min Tsai ◽  
Yu-He Jiang ◽  
Ganesh Gollavelli ◽  
Nayantara Mohanta ◽  
...  

2019 ◽  
Vol 7 (11) ◽  
pp. 6213-6219 ◽  
Author(s):  
Peng Huang ◽  
Qiaoyun Chen ◽  
Kaicheng Zhang ◽  
Ligang Yuan ◽  
Yi Zhou ◽  
...  

In planar n–i–p perovskite solar cells (Pero-SCs), interfacial engineering plays a critically important role in charge extraction and transportation, and hence influences the photovoltaic performances.


Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1640
Author(s):  
Massimiliano Lanzi ◽  
Debora Quadretti ◽  
Martina Marinelli ◽  
Yasamin Ziai ◽  
Elisabetta Salatelli ◽  
...  

A new side-chain C60-fullerene functionalized thiophene copolymer bearing tributylphosphine-substituted hexylic lateral groups was successfully synthesized by means of a fast and effective post-polymerization reaction on a regioregular ω-alkylbrominated polymeric precursor. The growth of the polymeric intermediate was followed by NMR spectrometry in order to determine the most convenient reaction time. The obtained copolymer was soluble in water and polar solvents and was used as a photoactive layer in single-material organic photovoltaic (OPV) solar cells. The copolymer photovoltaic efficiency was compared with that of an OPV cell containing a water-soluble polythiophenic homopolymer, functionalized with the same tributylphosphine-substituted hexylic side chains, in a blend with a water-soluble C60-fullerene derivative. The use of a water-soluble double-cable copolymer made it possible to enhance the control on the nanomorphology of the active blend, thus reducing phase-segregation phenomena, as well as the macroscale separation between the electron acceptor and donor components. Indeed, the power conversion efficiency of OPV cells based on a single material was higher than that obtained with the classical architecture, involving the presence of two distinct ED and EA materials (PCE: 3.11% vs. 2.29%, respectively). Moreover, the synthetic procedure adopted to obtain single material-based cells is more straightforward and easier than that used for the preparation of the homopolymer-based BHJ solar cell, thus making it possible to completely avoid the long synthetic pathway which is required to prepare water-soluble fullerene derivatives.


Author(s):  
Ping Hou ◽  
Wenxiang Yang ◽  
Ning Wan ◽  
Zhi Fang ◽  
Jinju Zheng ◽  
...  

We report a facile BiBr3(DMSO)2 adduct process to produce high-quality Cs2AgBiBr6 films with large grains for the first time, which leads to an enhancement of over 40% on the PCE of Cs2AgBiBr6-based solar cells compared to that of the control sample.


2021 ◽  
Author(s):  
Sandeep Pandey ◽  
Amit Kumar ◽  
Manoj Karakoti ◽  
Kuldeep K. Garg ◽  
Aniket Rana ◽  
...  

Herein, we report the first time application of waste plastic derived 3D graphene nanosheets (GNs) for hole transport material (HTM) free perovskite solar cells (PSCs), where 3D GNs has been...


Author(s):  
Li Zhang ◽  
Hui Li ◽  
Jing Zhuang ◽  
Yigang Luan ◽  
Sixuan Wu ◽  
...  

The low-cost material antimony trifluoride (SbF3) was doped into the commonly used tin dioxide (SnO2) for the first time, and the SbF3-doped SnO2 as an electron transport layer (ETL) was...


2021 ◽  
Vol 1031 ◽  
pp. 222-227
Author(s):  
Ekaterina A. Savinova ◽  
Elizaveta S. Ershova ◽  
Olga A. Kraevaya ◽  
Pavel A. Troshin ◽  
S.V. Kostyuk

It is important to take into consideration the new fullerene derivatives genotoxicity. In the present is study, we analyzed the new water-soluble fullerene C70 (F350) effects on the human embryonic lung fibroblasts (HELF) oxidative damage and DNA breaks. We found that the studied compound causes cellular DNA damage and affects the transcriptional activity of cell cycle and cell apoptosis regulating genes.


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