Influence of metal substitution on hybrid halide perovskites: towards lead-free perovskite solar cells

2018 ◽  
Vol 6 (9) ◽  
pp. 3793-3823 ◽  
Author(s):  
Soumyo Chatterjee ◽  
Amlan J. Pal
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Lead Free ◽  
Metal Substitution ◽  
Halide Perovskites

Approaches to tune the properties of hybrid halide perovskites and their performance in solar cells through metal substitution have been summarized in this review.

scholarly journals Lead-Free Halide Double Perovskites: A Review of the Structural, Optical, and Stability Properties as Well as Their Viability to Replace Lead Halide Perovskites

Metals ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 667 ◽  
Author(s):  
Edson Meyer ◽  
Dorcas Mutukwa ◽  
Nyengerai Zingwe ◽  
Raymond Taziwa
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Lead Free ◽  
Double Perovskites ◽  
Stability Properties ◽  
Perovskite Materials ◽  
Halide Perovskites ◽  
Halide Perovskite ◽  
Light Absorbers ◽  
Lead Halide

Perovskite solar cells employ lead halide perovskite materials as light absorbers. These perovskite materials have shown exceptional optoelectronic properties, making perovskite solar cells a fast-growing solar technology. Perovskite solar cells have achieved a record efficiency of over 20%, which has superseded the efficiency of Gräztel dye-sensitized solar cell (DSSC) technology. Even with their exceptional optical and electric properties, lead halide perovskites suffer from poor stability. They degrade when exposed to moisture, heat, and UV radiation, which has hindered their commercialization. Moreover, halide perovskite materials consist of lead, which is toxic. Thus, exposure to these materials leads to detrimental effects on human health. Halide double perovskites with A2B′B″X6 (A = Cs, MA; B′ = Bi, Sb; B″ = Cu, Ag, and X = Cl, Br, I) have been investigated as potential replacements of lead halide perovskites. This work focuses on providing a detailed review of the structural, optical, and stability properties of these proposed perovskites as well as their viability to replace lead halide perovskites. The triumphs and challenges of the proposed lead-free A2B′B″X6 double perovskites are discussed here in detail.

A‐Site Cation Engineering of Metal Halide Perovskites: Version 3.0 of Efficient Tin‐Based Lead‐Free Perovskite Solar Cells

2020 ◽  
Vol 30 (34) ◽  
pp. 2000794 ◽  
Author(s):  
Weiyin Gao ◽  
Changshun Chen ◽  
Chenxin Ran ◽  
Hao Zheng ◽  
He Dong ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Metal Halide ◽  
Lead Free ◽  
Halide Perovskites ◽  
A Site

scholarly journals Lead-Free Perovskite Materials for Solar Cells

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Minghao Wang ◽  
Wei Wang ◽  
Ben Ma ◽  
Wei Shen ◽  
Lihui Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Large Scale ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Experimental Studies ◽  
Field Application ◽  
First Principles Calculation ◽  
Lead Free ◽  
Perovskite Materials ◽  
Halide Perovskites

AbstractThe toxicity issue of lead hinders large-scale commercial production and photovoltaic field application of lead halide perovskites. Some novel non- or low-toxic perovskite materials have been explored for development of environmentally friendly lead-free perovskite solar cells (PSCs). This review studies the substitution of equivalent/heterovalent metals for Pb based on first-principles calculation, summarizes the theoretical basis of lead-free perovskites, and screens out some promising lead-free candidates with suitable bandgap, optical, and electrical properties. Then, it reports notable achievements for the experimental studies of lead-free perovskites to date, including the crystal structure and material bandgap for all of lead-free materials and photovoltaic performance and stability for corresponding devices. The review finally discusses challenges facing the successful development and commercialization of lead-free PSCs and predicts the prospect of lead-free PSCs in the future.

scholarly journals Lead-free organic–inorganic tin halide perovskites for photovoltaic applications

2014 ◽  
Vol 7 (9) ◽  
pp. 3061-3068 ◽  
Author(s):  
Nakita K. Noel ◽  
Samuel D. Stranks ◽  
Antonio Abate ◽  
Christian Wehrenfennig ◽  
Simone Guarnera ◽  
...  
Keyword(s):  
Solar Cells ◽  
Potential Barrier ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Lead Free ◽  
Photovoltaic Applications ◽  
Halide Perovskites

Perovskite solar cells based on abundant low cost materials promise to compete on performance with mainstream PV. Here we demonstrate lead-free perovskite solar cells, removing a potential barrier to widespread deployment.

Roles of SnX2 (X = F, Cl, Br) Additives in Tin-Based Halide Perovskites toward Highly Efficient and Stable Lead-Free Perovskite Solar Cells

2018 ◽  
Vol 9 (20) ◽  
pp. 6024-6031 ◽  
Author(s):  
Jin Hyuck Heo ◽  
Jongseob Kim ◽  
Hyungjun Kim ◽  
Sang Hwa Moon ◽  
Sang Hyuk Im ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Lead Free ◽  
Highly Efficient ◽  
Halide Perovskites

High Purity Solvent-Coordinated Tin Halide Complexes for Lead Free Perovskite Solar Cells

2017 ◽  
Author(s):  
Jiewei Liu ◽  
Masashi Ozaki ◽  
Yukie Katsuki ◽  
Taketo Handa ◽  
Ryosuke Nishikubo ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Purity ◽  
Perovskite Solar Cells ◽  
Lead Free ◽  
Halide Complexes

scholarly journals The Main Progress of Perovskite Solar Cells in 2020–2021

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Tianhao Wu ◽  
Zhenzhen Qin ◽  
Yanbo Wang ◽  
Yongzhen Wu ◽  
Wei Chen ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Lead Free ◽  
Manufacturing Cost ◽  
Practical Application ◽  
The World ◽  
Photovoltaic Technology

AbstractPerovskite solar cells (PSCs) emerging as a promising photovoltaic technology with high efficiency and low manufacturing cost have attracted the attention from all over the world. Both the efficiency and stability of PSCs have increased steadily in recent years, and the research on reducing lead leakage and developing eco-friendly lead-free perovskites pushes forward the commercialization of PSCs step by step. This review summarizes the main progress of PSCs in 2020 and 2021 from the aspects of efficiency, stability, perovskite-based tandem devices, and lead-free PSCs. Moreover, a brief discussion on the development of PSC modules and its challenges toward practical application is provided.

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