scholarly journals Synergistic effects of chlorination and a fully two-dimensional side-chain design on molecular energy level modulation toward non-fullerene photovoltaics

2018 ◽  
Vol 6 (7) ◽  
pp. 2942-2951 ◽  
Author(s):  
Pengjie Chao ◽  
Huan Wang ◽  
Daize Mo ◽  
Hong Meng ◽  
Wei Chen ◽  
...  

By taking the advantage of chlorination and fully conjugated side chains, 2D-PBTCl shows a PCE of up to 8.81% in non-fullerene solar cells, which corresponds to an approximately 28% improvement compared to that of PTB7-Th-based devices.

2018 ◽  
Vol 6 (46) ◽  
pp. 23270-23277 ◽  
Author(s):  
Jing Liu ◽  
Lik-Kuen Ma ◽  
Zhengke Li ◽  
Huawei Hu ◽  
Fu Kit Sheong ◽  
...  

The synergistic effects of overfluorination and alkylthiophene side chain strategies led to 10.60% efficiency for non-fullerene organic solar cells.


2019 ◽  
Vol 7 (2) ◽  
pp. 716-726 ◽  
Author(s):  
Chentong Liao ◽  
Ming Zhang ◽  
Xiaopeng Xu ◽  
Feng Liu ◽  
Ying Li ◽  
...  

By a combination of side chain and ternary blend strategies, novel BDT-TT-based copolymer donors were developed to improve the green solvent solubility, crystallinity, energy level, carrier mobility and blend morphology. Non-fullerene binary and ternary blend devices based on PTB-EDOTS exhibited high PCEs of 10.18% and 12.26%, respectively.


2020 ◽  
Vol 8 (1) ◽  
pp. 139-146
Author(s):  
Enfang He ◽  
Yi Lu ◽  
Zhi Zheng ◽  
Fengyun Guo ◽  
Shiyong Gao ◽  
...  

In this work, two novel two-dimensional (2D) benzo[1,2-b:4,5-b′]difuran (BDF)-based wide bandgap polymers were designed using a halogenation strategy by incorporating fluorine- and chlorine-substituted conjugated side chains, respectively.


Author(s):  
Liang Zeng ◽  
Ruijie Ma ◽  
Qiang Zhang ◽  
Tao Liu ◽  
Yiqun Xiao ◽  
...  

We are developing both copolymers with quinoxaline (Qx) as acceptor units by fine tuning the side chains with halogen atom chlorine (Cl) and flexible alkyl engineering for efficient non-fullerene polymer solar cells.


2013 ◽  
Vol 117 (47) ◽  
pp. 24700-24709 ◽  
Author(s):  
Enwei Zhu ◽  
Jiefeng Hai ◽  
Zixuan Wang ◽  
Bin Ni ◽  
Yaohua Jiang ◽  
...  

2015 ◽  
Vol 3 (35) ◽  
pp. 18115-18126 ◽  
Author(s):  
Haimei Wu ◽  
Baofeng Zhao ◽  
Weiping Wang ◽  
Zhaoqi Guo ◽  
Wei Wei ◽  
...  

Over the past few years, it has been proven that deepening the highest occupied molecular orbital (HOMO) levels of conjugated polymers is one of the most successful strategies to develop novel materials for high performance bulk heterojunction polymer solar cells.


2017 ◽  
Vol 5 (4) ◽  
pp. 937-942 ◽  
Author(s):  
Xue Gong ◽  
Guangwu Li ◽  
Shiyu Feng ◽  
Liangliang Wu ◽  
Yahui Liu ◽  
...  

The side chains of polymers had a great influence on their molecular packing, energy level, blend morphology and photovoltaic performance. The PCEs of 7.28% and 1.55% were obtained for alkoxy and alkylthio-substituted polymer based non-fullerene solar cells, respectively.


RSC Advances ◽  
2018 ◽  
Vol 8 (69) ◽  
pp. 39231-39240
Author(s):  
N. A. Mica ◽  
S. A. J. Almahmoud ◽  
L. Krishnan Jagadamma ◽  
G. Cooke ◽  
I. D. W. Samuel

The chemical nature of the acceptor side chain plays an important role in the processability and photovoltaic performance of EDOT-based small molecule donors.


2021 ◽  
Vol 4 (9) ◽  
pp. 9913-9922
Author(s):  
You-Dan Zhang ◽  
Xunchang Wang ◽  
Xian Fei ◽  
Lei Zhang ◽  
Pengzhi Guo ◽  
...  

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