Flexible self-supported metal–organic framework mats with exceptionally high porosity for enhanced separation and catalysis

2018 ◽  
Vol 6 (2) ◽  
pp. 334-341 ◽  
Author(s):  
Huixin Liang ◽  
Xiuling Jiao ◽  
Cheng Li ◽  
Dairong Chen

A wide range of flexible MOF-only mats are prepared and exhibit enhanced performances in water treatment, air purification and catalysis.

2018 ◽  
Vol 6 (4) ◽  
pp. 1866-1866 ◽  
Author(s):  
Huixin Liang ◽  
Xiuling Jiao ◽  
Cheng Li ◽  
Dairong Chen

Correction for ʻFlexible self-supported metal–organic framework mats with exceptionally high porosity for enhanced separation and catalysisʼ by Huixin Liang et al., J. Mater. Chem. A, 2018, DOI: 10.1039/c7ta08210j.


Author(s):  
Jiajun Song ◽  
Jianzhong Zheng ◽  
Anneng Yang ◽  
Hong Liu ◽  
Zeyu Zhao ◽  
...  

Two-dimensional (2D) conductive metal-organic frameworks (MOFs) can not only inherit the high porosity and tailorability of traditional MOFs but also exhibit unique charge transport properties, offering promising opportunities for applications...


2017 ◽  
Vol 9 (43) ◽  
pp. 37848-37855 ◽  
Author(s):  
Xuerui Wang ◽  
Linzhi Zhai ◽  
Yuxiang Wang ◽  
Ruitong Li ◽  
Xuehong Gu ◽  
...  

2009 ◽  
Vol 49 (3) ◽  
pp. 548-551 ◽  
Author(s):  
Yan-Shuo Li ◽  
Fang-Yi Liang ◽  
Helge Bux ◽  
Armin Feldhoff ◽  
Wei-Shen Yang ◽  
...  

2021 ◽  
Author(s):  
Yong-Mei Wang ◽  
Xinxin Zhang ◽  
Dingyi Yang ◽  
Liting Wu ◽  
Jiaojiao Zhang ◽  
...  

Abstract The high porosity, controllable size, high surface area, and chemical versatility of a metal-organic framework (MOF) enable it a good material for a triboelectric nanogenerator (TENG), and some MOFs have been incorporated in the fabrication of TENGs. However, the understanding of effects of MOFs on the energy conversion of a TENG is still lacking, which inhibits the improvement of the performance of MOF-based TENGs. Here, UiO-66-NH2 MOFs were found to significantly increase the power of a TENG and the mechanism was carefully examined. The electron-withdrawing ability of Zr-based UiO-66-family MOFs was enhanced by designing the amino functionalized 1,4-terephthalic acid (1,4-BDC) as ligand. The chemically modified UiO-66-NH2 was found to increase the surface roughness and surface potential of a composite film with MOFs embedded in polydimethylsiloxane (PDMS) matrix. Thus the total charges due to the contact electrification increased significantly. The composite-based TENG was found to be very durable and its output voltage and current were 4 times and 60 times higher than that of a PDMS-based TENG. This work revealed an effective strategy to design MOFs with excellent electron-withdrawing abilities for high-performance TENGs.


2017 ◽  
Vol 4 (11) ◽  
pp. 2205-2214 ◽  
Author(s):  
Hsiang Ting ◽  
Heng-Yu Chi ◽  
Chon Hei Lam ◽  
Kuan-Ying Chan ◽  
Dun-Yen Kang

This paper reports on a novel membrane adsorber comprising metal–organic frameworks (MOFs) for water treatment.


2021 ◽  
Author(s):  
Sujing Wang ◽  
Antoine Tissot ◽  
Guillaume Maurin ◽  
Tatjana Parac-Vogt ◽  
Christian Serre ◽  
...  

<div>The discovery of nanozymes for selective cleavage of proteins would boost the emerging areas of modern proteomics, however, the development of efficient and reusable artificial catalysts for peptide bond hydrolysis is challenging. Here we report the detailed catalytic properties of a microporous zirconium carboxylate metal-organic framework, MIP-201, in promoting peptide bond hydrolysis in a simple dipeptide, as well as in horse-heart myoglobin (Mb) protein that consists of 153 amino acids. We demonstrate that MIP-201 features an excellent catalytic activity and selectivity, a good tolerance toward reaction conditions covering a wide range of different pH values, and importantly, an exceptional recycling ability associated with easy regeneration process. Taking into account the excellent catalytic performance of MIP-201 and its other advantages such as 6-connected Zr6 cluster active sites, the green, scalable and cost-effective synthesis, and an outstanding chemical and architectural stability, our finding suggests that MIP-201 may be a promising and practical alternative to the current commercially available catalysts for peptide bond hydrolysis.</div>


2021 ◽  
Author(s):  
Sujing Wang ◽  
Antoine Tissot ◽  
Guillaume Maurin ◽  
Tatjana Parac-Vogt ◽  
Christian Serre ◽  
...  

<div>The discovery of nanozymes for selective cleavage of proteins would boost the emerging areas of modern proteomics, however, the development of efficient and reusable artificial catalysts for peptide bond hydrolysis is challenging. Here we report the detailed catalytic properties of a microporous zirconium carboxylate metal-organic framework, MIP-201, in promoting peptide bond hydrolysis in a simple dipeptide, as well as in horse-heart myoglobin (Mb) protein that consists of 153 amino acids. We demonstrate that MIP-201 features an excellent catalytic activity and selectivity, a good tolerance toward reaction conditions covering a wide range of different pH values, and importantly, an exceptional recycling ability associated with easy regeneration process. Taking into account the excellent catalytic performance of MIP-201 and its other advantages such as 6-connected Zr6 cluster active sites, the green, scalable and cost-effective synthesis, and an outstanding chemical and architectural stability, our finding suggests that MIP-201 may be a promising and practical alternative to the current commercially available catalysts for peptide bond hydrolysis.</div>


2021 ◽  
Vol 02 ◽  
Author(s):  
Xinxin Liu ◽  
Jiaqing Ren ◽  
Jiaqi Fang ◽  
An Pan ◽  
Nianqiao Qin ◽  
...  

: Photocatalytic degradation is an energy-efficient, cost-effective, and stable process that has a wide-range of applications. It is considered a promising method for the removal of organic pollutants. As a new type of porous materials, Metal-organic framework (MOF) composites have been proven to be an ideal catalyst for the degradation of organic pollutants due to their small size and large specific surface area. In this review, several common preparation methods of MOF composites are evaluated:microwave synthesis, solvent-thermal method, electrochemical method and layer by layer growth method. The degradation effects of MOF composites on different organic pollutants are summarized, and the excellent photocatalytic performances of some MOF composites are demonstrated. Finally, the prospect of photocatalytic degradation of organic pollutants by MOF composites is examined, and the challenges of further development of MOF composites are discussed.


Sign in / Sign up

Export Citation Format

Share Document