Bimetal–organic framework assisted polymerization of pyrrole involving air oxidant to prepare composite electrodes for portable energy storage

2017 ◽  
Vol 5 (45) ◽  
pp. 23744-23752 ◽  
Author(s):  
Yang Jiao ◽  
Gang Chen ◽  
Dahong Chen ◽  
Jian Pei ◽  
Yongyuan Hu

Heterocyclic pyrrole molecules arein situpolymerized in the absence of an oxidant between the layers of bimetal–organic frameworks, resulting in high energy density and power density simultaneously.

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3586
Author(s):  
Qi An ◽  
Xingru Zhao ◽  
Shuangfu Suo ◽  
Yuzhu Bai

Lithium-ion capacitors (LICs) have been widely explored for energy storage. Nevertheless, achieving good energy density, satisfactory power density, and stable cycle life is still challenging. For this study, we fabricated a novel LIC with a NiO-rGO composite as a negative material and commercial activated carbon (AC) as a positive material for energy storage. The NiO-rGO//AC system utilizes NiO nanoparticles uniformly distributed in rGO to achieve a high specific capacity (with a current density of 0.5 A g−1 and a charge capacity of 945.8 mA h g−1) and uses AC to provide a large specific surface area and adjustable pore structure, thereby achieving excellent electrochemical performance. In detail, the NiO-rGO//AC system (with a mass ratio of 1:3) can achieve a high energy density (98.15 W h kg−1), a high power density (10.94 kW kg−1), and a long cycle life (with 72.1% capacity retention after 10,000 cycles). This study outlines a new option for the manufacture of LIC devices that feature both high energy and high power densities.


2018 ◽  
Vol 6 (19) ◽  
pp. 9109-9115 ◽  
Author(s):  
Xiaoya Chang ◽  
Lei Zang ◽  
Song Liu ◽  
Mengying Wang ◽  
Huinan Guo ◽  
...  

Yolk–shell ZnCo2O4 with in situ formed carbon shows great potential for supercapacitors, which delivers high energy density and power density.


2019 ◽  
Vol 7 (36) ◽  
pp. 20604-20613 ◽  
Author(s):  
Dongxue Wang ◽  
Zhixuan Wei ◽  
Yunxiang Lin ◽  
Nan Chen ◽  
Yu Gao ◽  
...  

Benefiting from the intercalation pseudocapacitance property and structural stability of NASICON-type Na2CrTi(PO4)3@C, the [Active carbon|| Na2CrTi(PO4)3@C] hybrid ion capacitor delivers high energy density as well as superior power density.


2015 ◽  
Vol 44 (5) ◽  
pp. 2333-2339 ◽  
Author(s):  
Yaya Feng ◽  
Xiangyu Liu ◽  
Linqiang Duan ◽  
Qi Yang ◽  
Qing Wei ◽  
...  

A 3D heterometallic metal–organic framework has been synthesized in situ using Mtta formed from acetonitrile and azide, and structurally characterized.


2018 ◽  
Vol 6 (48) ◽  
pp. 24860-24868 ◽  
Author(s):  
Hao Chen ◽  
Chunlong Dai ◽  
Yanan Li ◽  
Renming Zhan ◽  
Min-Qiang Wang ◽  
...  

Hybrid ion capacitors, especially sodium ion capacitors (SICs), have recently attracted enormous attention due to their combined merits of high energy density from the battery-type anode and high power density from the capacitor-type cathode.


2019 ◽  
Vol 31 (9) ◽  
pp. 1970064
Author(s):  
Yunxiang Bai ◽  
Boyuan Shen ◽  
Shenli Zhang ◽  
Zhenxing Zhu ◽  
Silei Sun ◽  
...  

2016 ◽  
Vol 4 (10) ◽  
pp. 3828-3834 ◽  
Author(s):  
Qiufan Wang ◽  
Yunlong Wu ◽  
Ting Li ◽  
Daohong Zhang ◽  
Menghe Miao ◽  
...  

A two-ply yarn supercapacitor fabricated from Pt/CNT@PANI nanowire composite electrodes exhibits a high specific capacitance of 91.67 mF cm−2and a high energy density of 12.68 μW h cm−2.


Nanoscale ◽  
2018 ◽  
Vol 10 (43) ◽  
pp. 20414-20425 ◽  
Author(s):  
Balakrishnan Kirubasankar ◽  
Vignesh Murugadoss ◽  
Jing Lin ◽  
Tao Ding ◽  
Mengyao Dong ◽  
...  

A NiSe–G∥AC asymmetric supercapacitor with both pseudocapacitance and EDLC mechanisms provides an energy density of 50.1 W h kg−1 and a power density of 816 W kg−1.


Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 122
Author(s):  
Renwei Lu ◽  
Xiaolong Ren ◽  
Chong Wang ◽  
Changzhen Zhan ◽  
Ding Nan ◽  
...  

Lithium-ion hybrid capacitors (LICs) are regarded as one of the most promising next generation energy storage devices. Commercial activated carbon materials with low cost and excellent cycling stability are widely used as cathode materials for LICs, however, their low energy density remains a significant challenge for the practical applications of LICs. Herein, Na0.76V6O15 nanobelts (NaVO) were prepared and combined with commercial activated carbon YP50D to form hybrid cathode materials. Credit to the synergism of its capacitive effect and diffusion-controlled faradaic effect, NaVO/C hybrid cathode displays both superior cyclability and enhanced capacity. LICs were assembled with the as-prepared NaVO/C hybrid cathode and artificial graphite anode which was pre-lithiated. Furthermore, 10-NaVO/C//AG LIC delivers a high energy density of 118.9 Wh kg−1 at a power density of 220.6 W kg−1 and retains 43.7 Wh kg−1 even at a high power density of 21,793.0 W kg−1. The LIC can also maintain long-term cycling stability with capacitance retention of approximately 70% after 5000 cycles at 1 A g−1. Accordingly, hybrid cathodes composed of commercial activated carbon and a small amount of high energy battery-type materials are expected to be a candidate for low-cost advanced LICs with both high energy density and power density.


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