Egg-shell structured LiCoO2 by Cu2+ substitution to Li+ sites via facile stirring in an aqueous copper(ii) nitrate solution

2017 ◽  
Vol 5 (47) ◽  
pp. 24892-24900 ◽  
Author(s):  
Jaemin Kim ◽  
Hyunchul Kang ◽  
Nakgyu Go ◽  
Seonghun Jeong ◽  
Taeeun Yim ◽  
...  

For practical, high-energy lithium ion batteries, we introduce an egg-shell structured LiCoO2, enabling a credible performance with a high cut-off potential of 4.4 V, simply prepared by only stirring in 0.5 mM Cu(NO3)2 aqueous solution at room temperature without costly heat treatment.

2021 ◽  
pp. 130335
Author(s):  
Wei Wu ◽  
Zhenyao Wei ◽  
Jun Wang ◽  
Jian Shang ◽  
Man Wang ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (19) ◽  
pp. 15279-15285 ◽  
Author(s):  
QiGang Han ◽  
Zheng Yi ◽  
Yong Cheng ◽  
Yaoming Wu ◽  
LiMin Wang

Cu6Sn5/Sn composites are directly fabricated by a high energy mechanical milling technique and subsequent heat treatment.


2011 ◽  
Vol 399-401 ◽  
pp. 1467-1472 ◽  
Author(s):  
Li Bin Kang ◽  
Shi Chao Zhang ◽  
Ruo Xu Lin

Tin nano-spheres film was synthesized by electrodeposition based on the copper-nickel nano-pillars which were prepared by electrochemical method on the copper foil in an aqueous solution containing Cu (II) and Ni (II) at room temperature. The morphology, structure and composition of the as-prepared copper-nickel nano-pillars and tin nano-spheres were characterized by SEM, XRD, and EDS. The tin nano-spheres film anode features the large surface area, good electronic conductivity, and adhesion with the current collector, leading to the enhanced performance in lithium-ion batteries.


Rare Metals ◽  
2021 ◽  
Author(s):  
Chao-Chao Zhou ◽  
Zhi Su ◽  
Xin-Lei Gao ◽  
Rui Cao ◽  
Shi-Chun Yang ◽  
...  

Nanoscale ◽  
2021 ◽  
Author(s):  
Dongdong Wang ◽  
Qizhang Yan ◽  
Mingqian Li ◽  
Hongpeng Gao ◽  
Jianhua Tian ◽  
...  

Nickel (Ni)-rich layered oxides such as LiNi0.6Co0.2Mn0.2O2 (NCM622) represent one of the most promising candidates for the next-generation high-energy lithium-ion batteries (LIBs). However, the pristine Ni-rich cathode materials usually suffer...


Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1091
Author(s):  
Eva Gerold ◽  
Stefan Luidold ◽  
Helmut Antrekowitsch

The consumption of lithium has increased dramatically in recent years. This can be primarily attributed to its use in lithium-ion batteries for the operation of hybrid and electric vehicles. Due to its specific properties, lithium will also continue to be an indispensable key component for rechargeable batteries in the next decades. An average lithium-ion battery contains 5–7% of lithium. These values indicate that used rechargeable batteries are a high-quality raw material for lithium recovery. Currently, the feasibility and reasonability of the hydrometallurgical recycling of lithium from spent lithium-ion batteries is still a field of research. This work is intended to compare the classic method of the precipitation of lithium from synthetic and real pregnant leaching liquors gained from spent lithium-ion batteries with sodium carbonate (state of the art) with alternative precipitation agents such as sodium phosphate and potassium phosphate. Furthermore, the correlation of the obtained product to the used type of phosphate is comprised. In addition, the influence of the process temperature (room temperature to boiling point), as well as the stoichiometric factor of the precipitant, is investigated in order to finally enable a statement about an efficient process, its parameter and the main dependencies.


2021 ◽  
Vol 490 ◽  
pp. 229527
Author(s):  
Min Wang ◽  
Wentao Yao ◽  
Peichao Zou ◽  
Shengyu Hu ◽  
Haojie Zhu ◽  
...  

2016 ◽  
Vol 307 ◽  
pp. 435-442 ◽  
Author(s):  
Xiulin Fan ◽  
Yujie Zhu ◽  
Chao Luo ◽  
Tao Gao ◽  
Liumin Suo ◽  
...  

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