Evolving molecular architectures of donor–acceptor conjugated polymers for photovoltaic applications: from one-dimensional to branched to two-dimensional structures

2017 ◽  
Vol 5 (46) ◽  
pp. 24051-24075 ◽  
Author(s):  
Yu-Wei Su ◽  
Yu-Che Lin ◽  
Kung-Hwa Wei

We discuss the packing characteristics and photovoltaic device performance of the donor–acceptor conjugated polymers with 1-D, branched and 2-D molecular architectures.

2005 ◽  
Vol 98 (12) ◽  
pp. 124903 ◽  
Author(s):  
Jiangeng Xue ◽  
Barry P. Rand ◽  
Soichi Uchida ◽  
Stephen R. Forrest

2017 ◽  
Vol 1 (3) ◽  
pp. 499-506 ◽  
Author(s):  
Liqian Liu ◽  
Guichuan Zhang ◽  
Baitian He ◽  
Shengjian Liu ◽  
Chunhui Duan ◽  
...  

Three novel conjugated polymers based on 2,3,8,9-tetrakis(3-(alkoxy)phenyl)-6,12-di(thiophen-2-yl)-2,3,8,9-tetrahydroquinoxalino[6,5-f]quinoxaline (DTNQx) were designed and synthesized, and were applied in photovoltaic cells.


2013 ◽  
Vol 4 (11) ◽  
pp. 3333 ◽  
Author(s):  
Yu-Ying Lai ◽  
Yen-Ju Cheng ◽  
Chiu-Hsiang Chen ◽  
Sheng-Wen Cheng ◽  
Fong-Yi Cao ◽  
...  

2015 ◽  
Vol 68 (11) ◽  
pp. 1759 ◽  
Author(s):  
Michael E. Mulholland ◽  
Kristine L. Konkol ◽  
Trent E. Anderson ◽  
Ryan L. Schwiderski ◽  
Seth C. Rasmussen

Four donor–acceptor (D-A) copolymers of 2,3-difunctionalized thieno[3,4-b]pyrazine (TP) and 9,9-dioctylfluorene were prepared in order to illustrate the ability to tune the electronic and optical properties of TP-based D-A polymers by the choice of side chains on the TP unit. In addition, analogous polymers were prepared with and without thiophene spacer units in order to allow discussion of their effect on the material properties. This combination of effects allowed tuning of the band gap over the range of 1.6–2.1 eV. Full optical and electrochemical characterization is reported for all materials, as well as initial photovoltaic device data for representative materials.


2016 ◽  
Vol 1 (1) ◽  
pp. 10-24 ◽  
Author(s):  
Kenley M. Pelzer ◽  
Seth B. Darling

One of the most important factors in determining organic photovoltaic device performance is the efficiency of exciton dissociation and charge separation at donor/acceptor heterojunctions. This review discusses theoretical and computational approaches to modeling this crucial process of charge generation.


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