Significant enhancement of photovoltaic performance through introducing S⋯N conformational locks

2017 ◽  
Vol 5 (41) ◽  
pp. 21674-21678 ◽  
Author(s):  
Simiao Yu ◽  
Yusheng Chen ◽  
Lei Yang ◽  
Pan Ye ◽  
Jianfei Wu ◽  
...  
Keyword(s):  
Small Molecule ◽  
Photovoltaic Performance ◽  
Significant Enhancement

A novel high photovoltaic performance small molecule was achieved through introducing S⋯N noncovalent conformational locks.

Significant enhancement of the photovoltaic performance of organic small molecule acceptors via side-chain engineering

2018 ◽  
Vol 6 (17) ◽  
pp. 7988-7996 ◽  
Author(s):  
Wenyan Su ◽  
Qunping Fan ◽  
Xia Guo ◽  
Juan Chen ◽  
Yan Wang ◽  
...  
Keyword(s):  
Small Molecule ◽  
Photovoltaic Performance ◽  
Significant Enhancement ◽  
Side Chain ◽  
Chain Architecture

The photovoltaic performance of PSC based on PTZ1 and IT-M is significantly improved by modulating side-chain architecture of IT-M from para-hexylphenyl to para-hexyloxylphenyl to meta-hexyloxylphenyl and a high PCE of 11.6% has been achieved.

Significantly improved photovoltaic performance of the triangular-spiral TPA(DPP–PN)3 by appending planar phenanthrene units into the molecular terminals

2015 ◽  
Vol 3 (2) ◽  
pp. 886-893 ◽  
Author(s):  
Youming Zhang ◽  
Xichang Bao ◽  
Manjun Xiao ◽  
Hua Tan ◽  
Qiang Tao ◽  
...  
Keyword(s):  
Small Molecule ◽  
Photovoltaic Performance

A new small molecule of TPA(DPP–PN)3 was obtained with appending planar phenanthrene units in the molecular terminals, and displayed a maximum PCE of 3.67% in the OSCs.

scholarly journals Correction: Effect of dye end groups in non-fullerene fluorene- and carbazole-based small molecule acceptors on photovoltaic performance

RSC Advances ◽  
2015 ◽  
Vol 5 (92) ◽  
pp. 75173-75173
Author(s):  
Yujeong Kim ◽  
Chang Eun Song ◽  
Sang-Jin Moon ◽  
Eunhee Lim
Keyword(s):  
Small Molecule ◽  
Photovoltaic Performance ◽  
Correction Effect ◽  
End Groups

Correction for ‘Effect of dye end groups in non-fullerene fluorene- and carbazole-based small molecule acceptors on photovoltaic performance’ by Yujeong Kim et al., RSC Adv., 2015, 5, 62739–62746.

scholarly journals With PBDB-T as the Donor, the PCE of Non-Fullerene Organic Solar Cells Based on Small Molecule INTIC Increased by 52.4%

Materials ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1324 ◽  
Author(s):  
Weifang Zhang ◽  
Zicha Li ◽  
Suling Zhao ◽  
Zheng Xu ◽  
Bo Qiao ◽  
...  
Keyword(s):  
Solar Cells ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
High Performance ◽  
Short Circuit ◽  
Photovoltaic Performance ◽  
Short Circuit Current ◽  
Production Costs ◽  
Higher Carrier Mobility ◽  
Carrier Transportation

At present, most high-performance non-fullerene materials are centered on fused rings. With the increase in the number of fused rings, production costs and production difficulties increase. Compared with other non-fullerenes, small molecule INTIC has the advantages of easy synthesis and strong and wide infrared absorption. According to our previous report, the maximum power conversion efficiency (PCE) of an organic solar cell using PTB7-Th:INTIC as the active layer was 7.27%. In this work, other polymers, PTB7, PBDB-T and PBDB-T-2F, as the donor materials, with INTIC as the acceptor, are selected to fabricate cells with the same structure to optimize their photovoltaic performance. The experimental results show that the optimal PCE of PBDB-T:INTIC based organic solar cells is 11.08%, which, thanks to the open voltage (VOC) increases from 0.80 V to 0.84 V, the short circuit current (JSC) increases from 15.32 mA/cm2 to 19.42 mA/cm2 and the fill factor (FF) increases from 60.08% to 67.89%, then a 52.4% improvement in PCE is the result, compared with the devices based on PTB7-Th:INTIC. This is because the PBDB-T:INTIC system has better carrier dissociation and extraction, carrier transportation and higher carrier mobility.

scholarly journals All-small-molecule organic solar cells with over 14% efficiency by optimizing hierarchical morphologies

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Ruimin Zhou ◽  
Zhaoyan Jiang ◽  
Chen Yang ◽  
Jianwei Yu ◽  
Jirui Feng ◽  
...  
Keyword(s):  
Solar Cells ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
High Performance ◽  
High Efficiency ◽  
Bulk Heterojunction ◽  
Photovoltaic Performance ◽  
Photovoltaic System ◽  
Active Layers ◽  
Donor Acceptor

AbstractThe high efficiency all-small-molecule organic solar cells (OSCs) normally require optimized morphology in their bulk heterojunction active layers. Herein, a small-molecule donor is designed and synthesized, and single-crystal structural analyses reveal its explicit molecular planarity and compact intermolecular packing. A promising narrow bandgap small-molecule with absorption edge of more than 930 nm along with our home-designed small molecule is selected as electron acceptors. To the best of our knowledge, the binary all-small-molecule OSCs achieve the highest efficiency of 14.34% by optimizing their hierarchical morphologies, in which the donor or acceptor rich domains with size up to ca. 70 nm, and the donor crystals of tens of nanometers, together with the donor-acceptor blending, are proved coexisting in the hierarchical large domain. All-small-molecule photovoltaic system shows its promising for high performance OSCs, and our study is likely to lead to insights in relations between bulk heterojunction structure and photovoltaic performance.

Large active layer thickness toleration of high-efficiency small molecule solar cells

2015 ◽  
Vol 3 (44) ◽  
pp. 22274-22279 ◽  
Author(s):  
Qian Zhang ◽  
Bin Kan ◽  
Xiangjian Wan ◽  
Hua Zhang ◽  
Feng Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Layer Thickness ◽  
Active Layer ◽  
Small Molecule ◽  
High Efficiency ◽  
Power Conversion ◽  
Photovoltaic Performance ◽  
Thickness Dependence ◽  
Active Layer Thickness ◽  
Conversion Efficiencies

The thickness dependence of the photovoltaic performance for devices based on the small molecule DR3TSBDT:PC71BM was systematically investigated and the power conversion efficiencies are found to be relatively insensitive to the thickness.

A review of organic small molecule-based hole-transporting materials for meso-structured organic–inorganic perovskite solar cells

2016 ◽  
Vol 4 (41) ◽  
pp. 15788-15822 ◽  
Author(s):  
Chin Hoong Teh ◽  
Rusli Daik ◽  
Eng Liang Lim ◽  
Chi Chin Yap ◽  
Mohd Adib Ibrahim ◽  
...  
Keyword(s):  
Solar Cells ◽  
Small Molecule ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Core Structure ◽  
Intrinsic Conductivity ◽  
Inorganic Perovskite ◽  
Hole Transporting ◽  
Hole Transporting Materials

HTMs with a planar core structure, extended-π system and electron-rich groups exhibited better intrinsic conductivity, which enhanced the photovoltaic performance.

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