Dramatic enhancement of the photocatalytic activity of Cd0.5Zn0.5S nanosheets via phosphorization calcination for visible-light-driven H2 evolution

2017 ◽  
Vol 5 (28) ◽  
pp. 14682-14688 ◽  
Author(s):  
Xing Liu ◽  
Xiangqing Li ◽  
Lixia Qin ◽  
Jin Mu ◽  
Shi-Zhao Kang

In the present work, phosphorized Cd0.5Zn0.5S nanosheets were prepared through a hydrothermal process followed by phosphorization calcination at 500 °C.

2019 ◽  
Vol 7 (36) ◽  
pp. 20742-20749 ◽  
Author(s):  
Heng Yang ◽  
Ming Zhao ◽  
Jing Zhang ◽  
Ji Ma ◽  
Pengyan Wu ◽  
...  

This study provides fundamental insights into the role of porosity in photocatalytic activity and might inform the ongoing efforts toward the noble-metal-free photocatalytic systems via BODIPY-based MOFs for visible-light-promoted H2 evolution.


2020 ◽  
Vol 8 (7) ◽  
pp. 3882-3891 ◽  
Author(s):  
Hai-Bo Huang ◽  
Zhi-Bin Fang ◽  
Kai Yu ◽  
Jian Lü ◽  
Rong Cao

Twinning CdZnS solid solution nanocrystals with rich sulfur vacancies show enhanced photocatalytic activity and stability for water splitting.


2017 ◽  
Vol 7 (17) ◽  
pp. 3802-3811 ◽  
Author(s):  
Hong Liu ◽  
Jingchai Meng ◽  
Jiang Zhang

3D flowerlike Mn0.8Cd0.2S hierarchical microspheres assembled from nanosheets with excellent photocatalytic activity and stability were fabricated by a facile PVP-assisted solvothermal method.


Proceedings ◽  
2020 ◽  
Vol 41 (1) ◽  
pp. 43
Author(s):  
Afsaneh Rashidizadeh ◽  
Hossein Ghafuri ◽  
Zeynab Rezazadeh

In recent years, heterogeneous semiconductor photocatalysts have attracted great attention in the arena of environmental remediation and solar energy conversion; because, sunlight energy is a renewable, cheap, and accessible source of energy and also converting solar energy to chemical energy can be declined the energy crisis and global warming. Development of visible light heterogeneous photocatalysts with high efficiency and chemical stability is important for catalysis researchers. Among different types of semiconductor material, polymeric graphitic carbon nitride (g-C3N4) with a medium band gap of about 2.7 eV has been widely applied in photodegradation of organic pollutants, water splitting, CO2 reduction, solar cells, energy storage, and organic synthesis. Unfortunately, due to the high rate recombination of photoinduced carriers, the photocatalytic performance of the bare g-C3N4 is still poor. Hence, many strategies including metal doping, noble metal deposition, and coupling with semiconductor composites have been employed to modify g-C3N4. Herein, we report the synthesis of g-C3N4/CuWO4 nanocomposite via a hydrothermal process. The prepared visible-light-driven nanocomposite exhibited an enhanced photocatalytic activity compared with bare g-C3N4 for the degradation of methylene blue (MB) under LED light irradiation.


2021 ◽  
Vol 11 (22) ◽  
pp. 10854
Author(s):  
Jingyun Mao ◽  
Huiling Zhong ◽  
Xinpin Liu ◽  
Qingrong Qian ◽  
Yongjin Luo ◽  
...  

The development of a facile method for the synthesis of GaN:ZnO solid solution, an attractive material with a wurtzite-type structure, is vital to enhance its photocatalytic activity toward H2 evolution. Herein, GaN:ZnO solid solution nanorods with diameters of around 180 nm were fabricated by combining the electro-spun method with a sequentially calcinating process. Photocatalytic water-splitting activities of the as-obtained samples loaded with Rh2−yCryO3 co-catalyst were estimated by H2 evolution under visible-light irradiation. The as-prepared GaN:ZnO nanorods at a nitridation temperature of 850 °C showed the optimal performance. Careful characterization of the GaN:ZnO solid solution nanorods indicated that the nitridation temperature is an important parameter affecting the photocatalytic performance, which is related to the specific surface area and the absorbable visible-light wavelength range. Finally, the mechanism of the GaN:ZnO solid solution nanorods was also investigated. The proposed synthesis strategy paves a new way to realize excellent activity and recyclability of GaN:ZnO solid solution nanorod photocatalysts for hydrogen generation.


ACS Omega ◽  
2019 ◽  
Vol 4 (5) ◽  
pp. 7919-7930 ◽  
Author(s):  
Zhongyi Jiao ◽  
Zhendong Liu ◽  
Zhen Ma

Author(s):  
R. Rameshbabu ◽  
Gina Pecchi ◽  
Eduardo J. Delgado ◽  
R.V. Mangalaraja ◽  
M. Sathish

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