Recent progresses in high-energy-density all pseudocapacitive-electrode-materials-based asymmetric supercapacitors

2017 ◽  
Vol 5 (20) ◽  
pp. 9443-9464 ◽  
Author(s):  
Jinfeng Sun ◽  
Chen Wu ◽  
Xiaofei Sun ◽  
Hong Hu ◽  
Chunyi Zhi ◽  
...  

This review elaborately summarizes the latest progress in all-pseudocapacitive asymmetric supercapacitors, including aqueous/nonaqueous faradaic electrode materials, the operating principles, system design/engineering, and rational optimization.

RSC Advances ◽  
2016 ◽  
Vol 6 (46) ◽  
pp. 40602-40614 ◽  
Author(s):  
Bingshu Guo ◽  
Zhongai Hu ◽  
Yufeng An ◽  
Ning An ◽  
Pengfei Jia ◽  
...  

The organic molecules (TCBQ, AQ) with multi-electron redox center are selected to modify nitrogen-doped heterostructure carbon (NHC) by noncovalent interaction and the electrode materials show good performances and potential self-matching behaviors.


Author(s):  
Leiyun Han ◽  
Xilong Liu ◽  
zheng cui ◽  
Yingjie Hua ◽  
Chongtai Wang ◽  
...  

Hierarchical copper cobalt sulfide nanobelt array structures with well-defined morphology control are first reported as high energy density electrode materials for asymmetric supercapacitors using a simple two-step solvothermal method. Through...


RSC Advances ◽  
2015 ◽  
Vol 5 (52) ◽  
pp. 41721-41728 ◽  
Author(s):  
Jia-Jia Li ◽  
Mao-Cheng Liu ◽  
Ling-Bin Kong ◽  
Dan Wang ◽  
Yu-Mei Hu ◽  
...  

Ni3(PO4)2@GO and Fe2O3@GO have been successfully synthesized as electrode materials, and they have been used to assemble an asymmetric supercapacitor (Fe2O3@GO//Ni3(PO4)2@GO), which exhibited a high energy density.


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Chen Li ◽  
Xiong Zhang ◽  
Kai Wang ◽  
Xianzhong Sun ◽  
Yanan Xu ◽  
...  

AbstractLithium-ion capacitors are envisaged as promising energy-storage devices to simultaneously achieve a large energy density and high-power output at quick charge and discharge rates. However, the mismatched kinetics between capacitive cathodes and faradaic anodes still hinder their practical application for high-power purposes. To tackle this problem, the electron and ion transport of both electrodes should be substantially improved by targeted structural design and controllable chemical doping. Herein, nitrogen-enriched graphene frameworks are prepared via a large-scale and ultrafast magnesiothermic combustion synthesis using CO2 and melamine as precursors, which exhibit a crosslinked porous structure, abundant functional groups and high electrical conductivity (10524 S m−1). The material essentially delivers upgraded kinetics due to enhanced ion diffusion and electron transport. Excellent capacities of 1361 mA h g−1 and 827 mA h g−1 can be achieved at current densities of 0.1 A g−1 and 3 A g−1, respectively, demonstrating its outstanding lithium storage performance at both low and high rates. Moreover, the lithium-ion capacitor based on these nitrogen-enriched graphene frameworks displays a high energy density of 151 Wh kg−1, and still retains 86 Wh kg−1 even at an ultrahigh power output of 49 kW kg−1. This study reveals an effective pathway to achieve synergistic kinetics in carbon electrode materials for achieving high-power lithium-ion capacitors.


2017 ◽  
Vol 322 ◽  
pp. 582-589 ◽  
Author(s):  
Mengyao Yao ◽  
Xin Zhao ◽  
Lei Jin ◽  
Fangyuan Zhao ◽  
Junxian Zhang ◽  
...  

2008 ◽  
Vol 62 (26) ◽  
pp. 4210-4212 ◽  
Author(s):  
Daliang Liu ◽  
Shiying Zhan ◽  
Gang Chen ◽  
Wencheng Pan ◽  
Chunzhong Wang ◽  
...  

2021 ◽  
Vol 16 (7) ◽  
pp. 1134-1142
Author(s):  
Wenduo Yang ◽  
Jun Xiang ◽  
Sroeurb Loy ◽  
Nan Bu ◽  
Duo Cui ◽  
...  

NiCo2O4 as an electrode material for supercapacitors (SCs) has been studied by a host of researchers due to its unique structural characteristics and high capacitance. However, its performance has not yet reached the level of practical applications.it is an effective strategy to synthesize composite electrode materials for tackling the problem. Herein, NiCo2O4@ZnCo2O4 as a novel core–shell composite electrode material has been fabricated through a two-step simple hydrothermal method. The as-prepared sample can be directly used as cathode material of a supercapacitor, and its specific capacitance is 463.1 C/g at 1 A/g. An assembled capacitor has an energy density of 77 Wh·kg−1 at 2700 W·kg−1, and after 8000 cycles, 88% of the initial capacity remains.


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