Puckered-layer-structured germanium monosulfide for superior rechargeable Li-ion battery anodes

2017 ◽  
Vol 5 (12) ◽  
pp. 5685-5689 ◽  
Author(s):  
Geon-Kyu Sung ◽  
Cheol-Min Park

Puckered-layer-structured germanium monosulfide (GeS) and corresponding amorphous-carbon-decorated nanocomposites (GeS–C) were synthesized and used to fabricate Li-ion battery anodes which displayed remarkable reversible capacity above 1050 mA h g−1after 100 cycles.

ACS Omega ◽  
2018 ◽  
Vol 3 (12) ◽  
pp. 17520-17527 ◽  
Author(s):  
Saúl Villagómez-Salas ◽  
Palanisamy Manikandan ◽  
Salvador Francisco Acuña Guzmán ◽  
Vilas G. Pol

2015 ◽  
Vol 17 (44) ◽  
pp. 29824-29833 ◽  
Author(s):  
Honglin Li ◽  
Ke Yu ◽  
Hao Fu ◽  
Bangjun Guo ◽  
Xiang Lei ◽  
...  

We studied the WS2 and reduced graphene oxide hybrid structure for use as anode material in lithium ion batteries. The composite delivered a significant enhanced reversible capacity and cycle stability compared with pristine WS2.


2020 ◽  
Vol 8 (21) ◽  
pp. 10998-11010 ◽  
Author(s):  
Maria Diaz-Lopez ◽  
Philip A. Chater ◽  
Yves Joly ◽  
Olivier Proux ◽  
Jean-Louis Hazemann ◽  
...  

The electrochemical activation of Li2O in densified nano-Li2MnO3 is responsible for the large reversible capacity (290 mA h g−1) in this system.


2008 ◽  
Vol 388 ◽  
pp. 37-40 ◽  
Author(s):  
Shinya Suzuki ◽  
Naoko Sakai ◽  
Masaru Miyayama

Thin films of titanate were prepared by electrophoretic deposition (EPD) of a colloidal suspension of nanosheets, and their lithium intercalation properties were examined. Thickness of the obtained film increased approximately in proportion to the increase in deposition time and concentration of the colloidal suspension used for EPD bath. EPD method was revealed to be a convenient method for layer lamination of nanosheets. The reversible capacity for the obtained film was approximately 170 mA h g-1, and it was in common with anatase-type TiO2 or conventional titanate. Lithium diffusion coefficient along the thickness direction was estimated to be 6 × 10-14 cm2 sec-1.


2016 ◽  
Vol 45 (47) ◽  
pp. 19109-19116 ◽  
Author(s):  
Teng Gong ◽  
Xiaobing Lou ◽  
Jia-Jia Fang ◽  
En-Qing Gao ◽  
Bingwen Hu

A Co(ii) coordination polymer with azide and a viologen-based tetracarboxylate ligand shows a relatively high reversible capacity with good cycling and rate performance as lithium-ion battery anode.


2014 ◽  
Vol 2 (13) ◽  
pp. 4714-4721 ◽  
Author(s):  
Yulong Liu ◽  
Hong Zhang ◽  
Pan Ouyang ◽  
Wenhao Chen ◽  
Ying Wang ◽  
...  

MoO2 thin films with hierarchical structure demonstrate excellent rate capability and reversible capacity, and the phase transformation mechanism was revealed.


2012 ◽  
Vol 1440 ◽  
Author(s):  
M. Taha Demirkan ◽  
Xin Li ◽  
Bingqing Wei ◽  
Tansel Karabacak

AbstractIn this work, we demonstrate a new density modulated multilayered silicon thin film anode approach that can provide a robust high capacity electrode for Li-ion batteries. These films have the ability to tolerate large volume changes due to their controlled microstructure. Silicon films with alternating layers of high/low material density were deposited using a DC sputtering system. Density of the individual layers was controlled by simply changing the working gas pressure during sputtering. Samples of Si films having thicknesses of 460 nm with different number of high/low density layers have been deposited on Cu current collectors. The electrochemical performance of the multilayered anode material was evaluated using a galvanostatic battery testing system at C/10 rate. After reaching a stabilized phase the battery cell showed a high coulombic efficiency of 96% to 99% and reversible specific capacity of 666 mAh g-1 (after 100 cycles). Low-density layers are believed to be acting as compliant sheets during volume expansion making the films more durable compared to conventional Si film anodes. The results indicate that density modulated multilayer Si thin films can be used to improve the mechanical properties of Li-ion battery anodes leading to high reversible capacity values even after high number of cycles.


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