Enhancement of interfacial bioelectrocatalysis in Shewanella microbial fuel cells by a hierarchical porous carbon–silica composite derived from distiller's grains

2018 ◽  
Vol 2 (3) ◽  
pp. 655-662 ◽  
Author(s):  
Xiaoshuai Wu ◽  
Yan Qiao ◽  
Zhuanzhuan Shi ◽  
Chang Ming Li

A synergistic effect of a hierarchically porous structure and a siliceous crust surface for an enhanced bioelectrocatalysis activity in a microbial fuel cell.

Polymers ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 664 ◽  
Author(s):  
Deng Wang ◽  
Ying Wang ◽  
Jing Yang ◽  
Xiu He ◽  
Rui-Jie Wang ◽  
...  

The flavin-based indirect electron transfer process between electroactive bacteria and solid electrode is crucial for microbial fuel cells (MFCs). Here, a cellulose-NaOH-urea mixture aerogel derived hierarchical porous carbon (CPC) is developed to promote the flavin based interfacial electron transfer. The porous structure of the CPC can be tailored via adjusting the ratio of urea in the cellulose aerogel precursor to obtain CPCs with different type of dominant pores. According to the electrocatalytic performance of different CPC electrodes, the CPCs with higher meso- and macropore area exhibit greatly improved flavin redox reaction. While, the CPC-9 with appropriate porous structure achieves highest power density in Shewanella putrefaciens CN32 MFC due to larger active surface for flavin mediated interfacial electron transfer and higher biofilm loading. Considering that the CPC is just obtained from the pyrolysis of the cellulose-NaOH-urea aerogel, this work also provides a facile approach for porous carbon preparation.


2020 ◽  
Vol 4 (11) ◽  
pp. 5697-5708 ◽  
Author(s):  
Mohammad Shaad Ansari ◽  
Thomas Nesakumar Jebakumar Immanuel Edison ◽  
Yong Rok Lee

A N/S co-doped hierarchical porous carbon-based electrode shows superior cycling stability and reversibility without a significant reduction in specific capacity.


2019 ◽  
Vol 7 (29) ◽  
pp. 17345-17356 ◽  
Author(s):  
Shifu Wang ◽  
Zuoyi Xiao ◽  
Shangru Zhai ◽  
Haisong Wang ◽  
Weijie Cai ◽  
...  

The design of advanced supercapacitors requires electrode materials that combine high surface area with a developed hierarchical porous structure to facilitate ion transport and electrolyte permeability.


2014 ◽  
Vol 69 (5) ◽  
Author(s):  
Nurul Najidah Mohamed ◽  
Lai Sin Yuan ◽  
Lee Siew Ling ◽  
Ho Chin Siong ◽  
Sheela Chandren ◽  
...  

In this study, a hierarchically porous carbon was prepared from a natural material, Averrhoa bilimbi, also known as bilimbi. The bilimbis were cut into preferred shape and size before drying by freeze drying method. The bilimbis were then subjected to pyrolysis at temperature of 400°C and transformed to porous carbon. Scanning electron microscopy (SEM) revealed that the bilimbis have a hierarchically porous structure in the macro-range. The diameter of the porosity decreased inwards from 30 to 8μm. Different types of motor oil, which were used to represent bulky molecules, were employed to test the diffusivity of these molecules from the bilimbi. It was found that the oils were able to diffuse through the hierarchically porous bilimbi in 2 to 3 hours, depending on the viscosity of the oils. Therefore, it can be concluded that, Averrhoa bilimbi possesses hierarchical porous structure with interconnected pores and capability to diffuse bulky molecules.     


Carbon ◽  
2021 ◽  
Author(s):  
Jin Wang ◽  
Hao Huang ◽  
Peng Wang ◽  
Shuang Wang ◽  
Jinping Li

2019 ◽  
Vol 23 (9) ◽  
pp. 2683-2693 ◽  
Author(s):  
Angélica María Baena-Moncada ◽  
Rusbel Coneo-Rodríguez ◽  
Adolfo La Rosa-Toro ◽  
Elena Pastor ◽  
Cesar Barbero ◽  
...  

2019 ◽  
Vol 6 (5) ◽  
pp. 1430-1442 ◽  
Author(s):  
Yajing Huang ◽  
Jingling Yang ◽  
Lingling Hu ◽  
Dehua Xia ◽  
Qing Zhang ◽  
...  

The mycelial pellet-derived hierarchical porous carbon nanosheets were fabricated facilely and showed high electrosorption capacity of 18.71 mg g−1 for capacitive deionization.


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