scholarly journals [(Cp2M)2B9H11] (M = Zr or Hf): early transition metal ‘guarded’ heptaborane with strong covalent and electrostatic bonding

2018 ◽  
Vol 9 (7) ◽  
pp. 1976-1981 ◽  
Author(s):  
Anangsha De ◽  
Qian-Fan Zhang ◽  
Bijan Mondal ◽  
Ling Fung Cheung ◽  
Sourav Kar ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Early Transition Metal ◽  
Early Transition ◽  
Electrostatic Bonding

We have isolated and structurally characterized two new transition metal complexes of the heptaborane, [(Cp2M)2B9H11] (Cp = η5-C5H5; M = Zr or Hf).

New main-group and early transition-metal complexes of mono-pendant arm triazacyclononane ligands

2001 ◽  
pp. 170-180 ◽  
Author(s):  
Sergei Y. Bylikin ◽  
David A. Robson ◽  
Nigel A. H. Male ◽  
Leigh H. Rees ◽  
Philip Mountford ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Main Group ◽  
Early Transition Metal ◽  
Pendant Arm ◽  
Early Transition

End-on versus side-on bonding of dinitrogen to dinuclear early transition-metal complexes

1993 ◽  
Vol 115 (7) ◽  
pp. 2782-2792 ◽  
Author(s):  
Michael D. Fryzuk ◽  
T. S. Haddad ◽  
Murugesapillai Mylvaganam ◽  
David H. McConville ◽  
Steven J. Rettig
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Early Transition Metal ◽  
Early Transition
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