scholarly journals Rapid reversible borane to boryl hydride exchange by metal shuttling on the carborane cluster surface

2017 ◽  
Vol 8 (8) ◽  
pp. 5399-5407 ◽  
Author(s):  
Bennett J. Eleazer ◽  
Mark D. Smith ◽  
Alexey A. Popov ◽  
Dmitry V. Peryshkov

The ruthenium carboranyl pincer complex featuring fluxional ”cage-walking“ of the metal center is an efficient catalyst for cyclooctane transfer dehydrogenation.

2016 ◽  
Vol 358 (20) ◽  
pp. 3283-3292 ◽  
Author(s):  
Nerea Conde ◽  
Raul SanMartin ◽  
María Teresa Herrero ◽  
Esther Domínguez

2015 ◽  
Vol 51 (18) ◽  
pp. 3886-3888 ◽  
Author(s):  
Go Hamasaka ◽  
Fumie Sakurai ◽  
Yasuhiro Uozumi

Allylic arylation of allylic acetates by sodium tetraarylborates in the presence of ppb to ppm (molar) loadings of a palladium NNC-pincer complex catalyst in methanol at 50 °C gave the corresponding arylated products in excellent yields.


2015 ◽  
Author(s):  
Raul Sanmartin ◽  
Nerea Conde ◽  
Fátima Churruca ◽  
María Teresa Herrero ◽  
Esther Domínguez

RSC Advances ◽  
2016 ◽  
Vol 6 (43) ◽  
pp. 37093-37098 ◽  
Author(s):  
Fa-Liu Yang ◽  
Xinju Zhu ◽  
Dun-Kang Rao ◽  
Xiao-Niu Cao ◽  
Ke Li ◽  
...  

An ionic Ru pincer complex was demonstrated to be highly efficient catalyst for conversion of aldoximes and aldehydes into corresponding primary amides with environmental benignity, operational convenience and catalytic loading as low as 0.5 mol%.


1987 ◽  
Vol 6 (4) ◽  
pp. 902-902
Author(s):  
Jerome Silestre ◽  
Maria Calhorda ◽  
Roald Hoffman ◽  
Page Stoutland ◽  
Robert Bergman

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