On the incompatibility of lithium–O2 battery technology with CO2

Shiyu Zhang; Matthew J. Nava; Gary K. Chow; Nazario Lopez; Gang Wu; David R. Britt; Daniel G. Nocera; Christopher C. Cummins

doi:10.1039/c7sc01230f

On the incompatibility of lithium–O2 battery technology with CO2

Chemical Science ◽

10.1039/c7sc01230f ◽

2017 ◽

Vol 8 (9) ◽

pp. 6117-6122 ◽

Cited By ~ 14

Author(s):

Shiyu Zhang ◽

Matthew J. Nava ◽

Gary K. Chow ◽

Nazario Lopez ◽

Gang Wu ◽

...

Keyword(s):

Reactive Species ◽

Organic Media ◽

Radical Anions ◽

Carbonate Radical ◽

Battery Technology

The peroxide dianion reacts with CO2 in polar aprotic organic media to afford the hydroperoxycarbonate and carbonate radical anions. These highly reactive species, if formed in lithium–O2 cells, can lead to cell degradation via oxidation of the electrolyte and electrode.

Download Full-text

Carbonate-radical-anions, and not hydroxyl radicals, are the products of the Fenton reaction in neutral solutions containing bicarbonate

Free Radical Biology and Medicine ◽

10.1016/j.freeradbiomed.2018.11.015 ◽

2019 ◽

Vol 131 ◽

pp. 1-6 ◽

Cited By ~ 22

Author(s):

Erzsébet Illés ◽

Amir Mizrahi ◽

Vered Marks ◽

Dan Meyerstein

Keyword(s):

Hydroxyl Radicals ◽

Fenton Reaction ◽

Radical Anions ◽

Carbonate Radical

Download Full-text

Oxidation of single-stranded oligonucleotides by carbonate radical anions: generating intrastrand cross-links between guanine and thymine bases separated by cytosines

Nucleic Acids Research ◽

10.1093/nar/gkm1092 ◽

2007 ◽

Vol 36 (3) ◽

pp. 742-755 ◽

Cited By ~ 55

Author(s):

Conor Crean ◽

Yuriy Uvaydov ◽

Nicholas E. Geacintov ◽

Vladimir Shafirovich

Keyword(s):

Radical Anions ◽

Carbonate Radical ◽

Cross Links

Download Full-text

Oxidation of Guanine and 8-oxo-7,8-Dihydroguanine by Carbonate Radical Anions: Insight from Oxygen-18 Labeling Experiments

Angewandte Chemie International Edition ◽

10.1002/anie.200500991 ◽

2005 ◽

Vol 44 (32) ◽

pp. 5057-5060 ◽

Cited By ~ 51

Author(s):

Conor Crean ◽

Nicholas E. Geacintov ◽

Vladimir Shafirovich

Keyword(s):

Radical Anions ◽

Carbonate Radical

Download Full-text

ESR study of dialkyl carbonate radical anions and their thermal and photochemical dissociation in the solid state

The Journal of Physical Chemistry ◽

10.1021/j150605a012 ◽

1981 ◽

Vol 85 (5) ◽

pp. 510-517 ◽

Cited By ~ 9

Author(s):

Reggie L. Hudson ◽

Ffrancon Williams

Keyword(s):

Solid State ◽

Radical Anions ◽

Carbonate Radical ◽

Dialkyl Carbonate

Download Full-text

Kinetic Selectivity of Lithium Alkyl Carbonate Formation from Combination Reactions of Ethylene Carbonate Radical Anions

The Journal of Physical Chemistry C ◽

10.1021/acs.jpcc.0c08858 ◽

2020 ◽

Vol 124 (47) ◽

pp. 25754-25759

Author(s):

Mathew J. Boyer ◽

Gyeong S. Hwang

Keyword(s):

Ethylene Carbonate ◽

Radical Anions ◽

Carbonate Radical ◽

Carbonate Formation ◽

Kinetic Selectivity

Download Full-text

CO2 Elimination from Vinylene Carbonate Radical Anions and Charge Reversal in C2H2O⊙⊖: Reactions Involving the Radical Anion and Cation of Oxirene?

Angewandte Chemie International Edition in English ◽

10.1002/anie.198701401 ◽

1987 ◽

Vol 26 (2) ◽

pp. 140-142 ◽

Cited By ~ 5

Author(s):

Ben L. M. van Baar ◽

Nikolaus Heinrich ◽

Wolfram Koch ◽

Ron Postma ◽

Johan K. Terlouw ◽

...

Keyword(s):

Radical Anion ◽

Radical Anions ◽

Charge Reversal ◽

Carbonate Radical ◽

Vinylene Carbonate ◽

Co2 Elimination

Download Full-text

Oxidation of Guanine and 8-oxo-7,8-Dihydroguanine by Carbonate Radical Anions: Insight from Oxygen-18 Labeling Experiments

Angewandte Chemie ◽

10.1002/ange.200500991 ◽

2005 ◽

Vol 117 (32) ◽

pp. 5185-5188 ◽

Cited By ~ 4

Author(s):

Conor Crean ◽

Nicholas E. Geacintov ◽

Vladimir Shafirovich

Keyword(s):

Radical Anions ◽

Carbonate Radical

Download Full-text

Oxidation of Guanine in G, GG, and GGG Sequence Contexts by Aromatic Pyrenyl Radical Cations and Carbonate Radical Anions: Relationship between Kinetics and Distribution of Alkali-Labile Lesions

The Journal of Physical Chemistry B ◽

10.1021/jp076777x ◽

2008 ◽

Vol 112 (6) ◽

pp. 1834-1844 ◽

Cited By ~ 34

Author(s):

Young Ae Lee ◽

Alexander Durandin ◽

Peter C. Dedon ◽

Nicholas E. Geacintov ◽

Vladimir Shafirovich

Keyword(s):

Radical Cations ◽

Radical Anions ◽

Carbonate Radical

Download Full-text

Reactions of Reactive Nitrogen Species and Carbonate Radical Anions with DNA

Radical and Radical Ion Reactivity in Nucleic Acid Chemistry ◽

10.1002/9780470526279.ch11 ◽

2009 ◽

pp. 325-355 ◽

Cited By ~ 3

Author(s):

Vladimir Shafirovich ◽

Conor Crean ◽

Nicholas E. Geacintov

Keyword(s):

Reactive Nitrogen Species ◽

Reactive Nitrogen ◽

Radical Anions ◽

Nitrogen Species ◽

Carbonate Radical

Download Full-text

A selectivity study of reaction of the carbonate radical anion with methyl β-d-cellobioside and methyl β-d-glucoside in oxygenated aqueous solutions

Holzforschung ◽

10.1515/hf.2006.021 ◽

2006 ◽

Vol 60 (2) ◽

pp. 130-136 ◽

Cited By ~ 2

Author(s):

Magnus Carlsson ◽

Johan Lind ◽

Gábor Merényi

Keyword(s):

Radical Anion ◽

Hydrogen Abstraction ◽

Radical Anions ◽

Bleaching Agent ◽

Hydrogen Atoms ◽

Carbonate Radical ◽

Abstraction Reaction ◽

Carbonate Radical Anion ◽

Hydrogen Abstraction Reaction

Abstract In the presence of oxygen, radiolytically generated carbonate radical anions, CO3 •–, were reacted with methyl β-D-cellobioside and methyl β-D-glucoside. From the ensuing product pattern, it was concluded that CO3 •– abstracts hydrogen atoms predominantly from glucosidic C1–H bonds. This high intramolecular selectivity was rationalised mainly in terms of a polar effect on the transition state of the hydrogen abstraction reaction. The present findings are in sharp contrast to the relative inertness of CO3 •– towards glucosidic C1–H bonds previously observed in cotton linters. The reasons for this discrepancy are discussed in light of a possible future role of CO3 •– as a bleaching agent for pulp.

Download Full-text