scholarly journals Hybrid photocathode consisting of a CuGaO2 p-type semiconductor and a Ru(ii)–Re(i) supramolecular photocatalyst: non-biased visible-light-driven CO2 reduction with water oxidation

2017 ◽  
Vol 8 (6) ◽  
pp. 4242-4249 ◽  
Author(s):  
Hiromu Kumagai ◽  
Go Sahara ◽  
Kazuhiko Maeda ◽  
Masanobu Higashi ◽  
Ryu Abe ◽  
...  

A new Ru(ii)–Re(i)/CuGaO2 hybrid photocathode was developed and combined with a CoOx/TaON photoanode to drive non-biased visible-light-driven CO2 reduction with water oxidation.

Author(s):  
Ryutaro Kamata ◽  
Hiromu Kumagai ◽  
Yasuomi Yamazaki ◽  
Masanobu Higashi ◽  
Ryu Abe ◽  
...  

A durable molecular photocathode driving CO2 reduction with over 1200 of turnover number was developed by electropolymerization of Ru(ii) complexes. The cell with a suitable photoanode enabled CO2 reduction with H2O oxidation with no bias for 24 h.


2014 ◽  
Vol 50 (29) ◽  
pp. 3786-3788 ◽  
Author(s):  
Junkuo Gao ◽  
Jianwei Miao ◽  
Pei-Zhou Li ◽  
Wen Yuan Teng ◽  
Ling Yang ◽  
...  

Photoelectrochemical studies on a new Ti(iv)-based porous metal–organic framework (NTU-9, bandgap 1.72 eV) indicated that NTU-9 is a p-type semiconductor with visible-light-driven photoactivity.


2020 ◽  
Vol 22 (21) ◽  
pp. 7552-7559
Author(s):  
Bing-Cai He ◽  
Chao Zhang ◽  
Pei-Pei Luo ◽  
Yu Li ◽  
Tong-Bu Lu

A direct Z-scheme heterojunction of Co1-C3N4@α-Fe2O3 was constructed for efficient photocatalytic CO2 reduction coupled with water oxidation under visible-light irradiation, with a CO generation rate of 14.9 μmol g−1 h−1 and CO selectivity over 99%.


Nano Energy ◽  
2019 ◽  
Vol 60 ◽  
pp. 576-582 ◽  
Author(s):  
Luo Yu ◽  
Xin Ba ◽  
Ming Qiu ◽  
Yifei Li ◽  
Ling Shuai ◽  
...  

Sensors ◽  
2020 ◽  
Vol 20 (3) ◽  
pp. 850
Author(s):  
Qomaruddin Qomaruddin ◽  
Olga Casals ◽  
Andris Šutka ◽  
Tony Granz ◽  
Andreas Waag ◽  
...  

In this work, we present conductometric gas sensors based on p-type calcium iron oxide (CaFe2O4) nanoparticles. CaFe2O4 is a metal oxide (MOx) with a bandgap around 1.9 eV making it a suitable candidate for visible light-activated gas sensors. Our gas sensors were tested under a reducing gas (i.e., ethanol) by illuminating them with different light-emitting diode (LED) wavelengths (i.e., 465–640 nm). Regardless of their inferior response compared to the thermally activated counterparts, the developed sensors have shown their ability to detect ethanol down to 100 ppm in a reversible way and solely with the energy provided by an LED. The highest response was reached using a blue LED (465 nm) activation. Despite some responses found even in dark conditions, it was demonstrated that upon illumination the recovery after the ethanol exposure was improved, showing that the energy provided by the LEDs is sufficient to activate the desorption process between the ethanol and the CaFe2O4 surface.


2014 ◽  
Vol 136 (39) ◽  
pp. 13518-13521 ◽  
Author(s):  
Andreas Bachmeier ◽  
Samuel Hall ◽  
Stephen W. Ragsdale ◽  
Fraser A. Armstrong

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