scholarly journals Functional metal–organic framework boosting lithium metal anode performance via chemical interactions

2017 ◽  
Vol 8 (6) ◽  
pp. 4285-4291 ◽  
Author(s):  
Wen Liu ◽  
Yingying Mi ◽  
Zhe Weng ◽  
Yiren Zhong ◽  
Zishan Wu ◽  
...  
Keyword(s):  
Ion Transport ◽  
Metal Organic Framework ◽  
Lithium Metal ◽  
Chemical Interactions ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Metal Organic ◽  
Li Ion ◽  
Li Metal Anode ◽  
Organic Framework

Stable-cycling Li metal anode is realized with a MOF layer regulating Li-ion transport and Li deposition via chemical interactions.

Stable artificial solid electrolyte interphase films for lithium metal anode via metal–organic frameworks cemented by polyvinyl alcohol

2020 ◽  
Vol 8 (1) ◽  
pp. 251-258 ◽  
Author(s):  
Lishuang Fan ◽  
Zhikun Guo ◽  
Yu Zhang ◽  
Xian Wu ◽  
Chenyang Zhao ◽  
...  
Keyword(s):  
Polyvinyl Alcohol ◽  
Metal Organic Framework ◽  
Solid Electrolyte Interphase ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Sei Film ◽  
Metal Organic ◽  
Li Metal Anode ◽  
The Stability

Polyvinyl alcohol (PVA) as a “glue” to cement the metal organic framework (Zn-MOF) sheet as a reasonable artificial SEI film. The artificial SEI film can efficiently adapt to the changes of the volume during the cycle, significantly improve the stability of the Li metal anode.

scholarly journals Metal Organic Framework Derivative Improving Lithium Metal Anode Cycling

2020 ◽  
Vol 30 (10) ◽  
pp. 1907579 ◽  
Author(s):  
Yiren Zhong ◽  
Fang Lin ◽  
Maoyu Wang ◽  
Yifang Zhang ◽  
Qing Ma ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Metal Organic ◽  
Organic Framework

Metal-organic framework derived electrical insulating-conductive double-layer configuration for stable lithium metal anode

2021 ◽  
Author(s):  
Jianzong Man ◽  
Wenlong Liu ◽  
Haibang Zhang ◽  
Kun Liu ◽  
Yongfu Cui ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anode ◽  
Lithium Dendrites ◽  
Dendrites Growth ◽  
Metal Organic

Controlling lithium dendrites growth and alleviating volume expansion of lithium metal anode are two key factors to develop high energy density lithium metal batteries. In this work, the planar Cu...

scholarly journals High-Power Li-Metal Anode Enabled by Metal-Organic Framework Modified Electrolyte

Joule ◽  
2018 ◽  
Vol 2 (10) ◽  
pp. 2117-2132 ◽  
Author(s):  
Songyan Bai ◽  
Yang Sun ◽  
Jin Yi ◽  
Yibo He ◽  
Yu Qiao ◽  
...  
Keyword(s):  
High Power ◽  
Metal Organic Framework ◽  
Metal Anode ◽  
Metal Organic ◽  
Li Metal Anode ◽  
Organic Framework

Zn-CxNy nanoparticle arrays derived from metal-organic framework for ultralow-voltage hysteresis and stable Li metal anodes

2021 ◽  
Author(s):  
Zilong Zhuang ◽  
Chang Liu ◽  
Yiyang Yan ◽  
Pengcheng Ma ◽  
Daniel Tan
Keyword(s):  
Energy Density ◽  
Metal Organic Framework ◽  
Dendrite Growth ◽  
Direct Application ◽  
Nanoparticle Arrays ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Metal Organic ◽  
Voltage Hysteresis

Lithium metal anode (LMA) possesses the largest energy density among all anode candidates, while dendrite growth is a huge barrier in the direct application of LMA in batteries. Herein, metal-organic...

Cross-Linked Chains of Metal–Organic Framework Afford Continuous Ion Transport in Solid Batteries

2021 ◽  
pp. 2434-2441
Author(s):  
Qinghan Zeng ◽  
Jia Wang ◽  
Xin Li ◽  
Yuan Ouyang ◽  
Wenchao He ◽  
...  
Keyword(s):  
Ion Transport ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

scholarly journals HKUST-1@IL-Li Solid-state Electrolyte with 3D Ionic Channels and Enhanced Fast Li+ Transport for Lithium Metal Batteries at High Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 736
Author(s):  
Man Li ◽  
Tao Chen ◽  
Seunghyun Song ◽  
Yang Li ◽  
Joonho Bae
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolyte ◽  
Metal Organic Framework ◽  
Ionic Channels ◽  
Transference Numbers ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Metal Organic ◽  
Organic Framework

The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10-4 S·cm-1 and 0.46, respectively, at 25 °C, and 6.85 × 10-4 S·cm-1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh g-1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.

scholarly journals Improving Cyclability of Lithium Metal Anode via Constructing Atomic Interlamellar Ion Channel for Lithium Sulfur Battery

2021 ◽  
Vol 16 (1) ◽  
Author(s):  
Mao Yang ◽  
Nan Jue ◽  
Yuanfu Chen ◽  
Yong Wang
Keyword(s):  
Ion Channel ◽  
Coulombic Efficiency ◽  
Specific Capacity ◽  
Absorption Capacity ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Li Ion ◽  
Sulfur Battery ◽  
Rapid Transfer

AbstractUniform migration of lithium (Li) ions between the separator and the lithium anode is critical for achieving good quality Li deposition, which is of much significance for lithium metal battery operation, especially for Li–sulfur (Li–S) batteries. Commercial separators such as polypropylene or polyethylene can be prepared by wet or dry processes, but they can indeed cause plentiful porosities, resulting in the uneven Li ion stripping/plating and finally the formation of Li dendrites. Thence, we constructed an atomic interlamellar ion channel by introducing the layered montmorillonite on the surface of the separator to guide Li ion flux and achieved stable Li deposition. The atomic interlamellar ion channel with a spacing of 1.4 nm showed strong absorption capacity for electrolytes and reserved capacity for Li ions, thus promoting rapid transfer of Li ions and resulting in even Li ion deposition at the anode. When assembled with the proposed separator, the Coulombic efficiency of Li||Cu batteries was 98.2% after 200 cycles and stable plating/stripping even after 800 h was achieved for the Li||Li symmetric batteries. Importantly, the proposed separator allows 140% specific capacity increase after 190 cycles as employing the Li–S batteries.

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