scholarly journals Multiple-responsive shape memory polyacrylonitrile/graphene nanocomposites with rapid self-healing and recycling properties

RSC Advances ◽  
2018 ◽  
Vol 8 (3) ◽  
pp. 1225-1231 ◽  
Author(s):  
Chenting Cai ◽  
Yue Zhang ◽  
Mei Li ◽  
Yan Chen ◽  
Rongchun Zhang ◽  
...  

A Diels–Alder covalent bond based crosslinked polyacrylonitrile/graphene nanocomposite is reported, which has the multiple-responsive properties of shape memory, self-healing, and reprocessing in addition to enhanced mechanical property.

2016 ◽  
Vol 7 (47) ◽  
pp. 7278-7286 ◽  
Author(s):  
Jian Zhao ◽  
Rui Xu ◽  
Gaoxing Luo ◽  
Jun Wu ◽  
Hesheng Xia

The poly(siloxane-urethane) elastomers with microphase separation structure and Diels–Alder bonds show high healing efficiency, good mechanical property and good biocompatibility.


RSC Advances ◽  
2017 ◽  
Vol 7 (73) ◽  
pp. 46336-46343 ◽  
Author(s):  
Chenting Cai ◽  
Yue Zhang ◽  
Xueting Zou ◽  
Rongchun Zhang ◽  
Xiaoliang Wang ◽  
...  

A rapid self-healing and recyclable high-performance crosslinked epoxy resin (ER)/graphene nanocomposite is reported by simultaneously incorporating thermally reversible Diels–Alder (DA) covalent bonds and multiple-responsive graphene into the ER matrix.


2018 ◽  
Vol 26 (4) ◽  
pp. 365-373 ◽  
Author(s):  
Lei Ling ◽  
Jinhui Li ◽  
Guoping Zhang ◽  
Rong Sun ◽  
Ching-Ping Wong

Author(s):  
Yi-Huan Lee ◽  
Chao-Lin Cheng ◽  
Chin-Hsien Chiang ◽  
Zheng-Hao Tong ◽  
Lyu-Ying Wang ◽  
...  

In this study, a novel self-healing material with a dual-network composed of cross-linked structure by Diels–Alder (DA) chemistry interconnected with self-assembled π-conjugated polymer nanofibrils was developed for application in electromagnetic...


Author(s):  
Felipe Orozco ◽  
Mahsa Kaveh ◽  
Dian S. Santosa ◽  
Guilherme Macedo R. Lima ◽  
Diego Ribas Gomes ◽  
...  

2020 ◽  
Vol 55 (25) ◽  
pp. 11325-11338 ◽  
Author(s):  
Ying Cao ◽  
Jiatian Zhang ◽  
Dandan Zhang ◽  
Yan Lv ◽  
Jie Li ◽  
...  

Author(s):  
Yunseon Heo ◽  
Henry A. Sodano

Thermally responsive self-healing polyurethanes (1DA1T, 1.5DA1T, and 2DA1H) with shape memory property were developed and the fully reversible Diels-Alder (DA) and retro Diels-Alder (rDA) reactions were employed for the healing mechanism. The transition temperatures of the DA and rDA reactions were confirmed through a differential scanning calorimetry and the molecular level of analysis on the reversibility and the repeatability between the DA and rDA reactions were completed though a variable temperature proton nuclear magnetic resonance at the reaction temperatures. Also, compact tension specimens were made to observe the healing efficiencies. These specimens were healed without the use of external forces to close the crack surfaces after testing for the repeatable healing ability with three cycles. As a result, the average first healing cycle efficiencies of 80%, 84%, and 96% for 1DA1T, 1.5DA1T and 2DA1H, respectively, were achieved and small drops for the second and third healing cycles were observed. Then, using two of the self-healing polyurethanes as resins, continuous carbon fiber fabric reinforced polymer matrix composites (C1.5DA1T and C2DA1H) were fabricated and short beam shear testing was conducted to determine the healing capability on the delamination. Accordingly, the first healing efficiencies of 88% and 85% were measured without any additional treatments on the fibers; however, an external pressure was applied during the composite healing process.


Polymer ◽  
2018 ◽  
Vol 140 ◽  
pp. 150-157 ◽  
Author(s):  
Changhong Lin ◽  
Dekun Sheng ◽  
Xiangdong Liu ◽  
Shaobin Xu ◽  
Fance Ji ◽  
...  

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