scholarly journals Synthesis of core–shell SAPO-34@SAPO-18 composites by the epitaxial growth method and their catalytic properties for the MTO reaction

RSC Advances ◽  
2017 ◽  
Vol 7 (86) ◽  
pp. 54866-54875 ◽  
Author(s):  
Zhiqiang Xu ◽  
Jianwen Li ◽  
Weixin Qian ◽  
Hongfang Ma ◽  
Haitao Zhang ◽  
...  

A core/shell-structured SAPO-34@SAPO-18 composite catalyst was hydrothermally synthesized through the epitaxial growth method.

2019 ◽  
Vol 2019 ◽  
pp. 1-7
Author(s):  
Peng Wang ◽  
Zhongyang Zhang ◽  
Hua Wang ◽  
Tieqiang Zhang ◽  
Haining Cui ◽  
...  

Electrochemical deposition as a liquid phase epitaxial growth method is widely used to fabricate different kinds of hierarchical structures. As a typical heterostructure, TiO2/PbS is widely utilized in the areas of photovoltaics and photocatalysis. Oriented TiO2 nanorod (NR) arrays can provide direct pathways for the electron transport of photoanode. However, the lattice mismatch between TiO2 NR sides and PbS is very large; PbS nanoparticles (NPs) only formed on the top of TiO2 NRs. To solve this problem, TiO2/CdS core/shell nanocables were firstly prepared electrochemically because the lattice ratio between TiO2 and CdS was 0.916; and then, PbS NPs were successfully deposited over CdS shells (the lattice ratio between CdS and PbS was 0.697) to form TiO2/CdS/PbS hierarchical heterostructures. Experimental results demonstrated that the CdS interlayer could effectively promote the growth of PbS NPs on the surface and improve the fill factor and short current density of the photoanodes.


RSC Advances ◽  
2017 ◽  
Vol 7 (31) ◽  
pp. 19205-19210 ◽  
Author(s):  
Jing Yan ◽  
Honghu Yao ◽  
Junhao Li ◽  
Shiman He ◽  
Qili Wu ◽  
...  

Rare earth ions-doped hexagonal β-Na(Y,Yb)F4 nanorods can be coated perfectly with either optically active or inert shells to improve and/or tailor the upconversion emission through a one-step epitaxial growth method from α-phased nanoparticles.


CrystEngComm ◽  
2020 ◽  
Vol 22 (37) ◽  
pp. 6182-6188
Author(s):  
Xueshuai Chen ◽  
Rongli Jiang ◽  
Huilin Hou ◽  
Zihan Zhou ◽  
Xingwen Wang

ZSM-5/SAPO-34 zeolite composites were successfully synthesized via a secondary growth method, and the SAPO-34 part of ZSM-5/SAPO-34 was synthesized from LAPONITE®.


Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 1007
Author(s):  
Azam Ali ◽  
Mariyam Sattar ◽  
Fiaz Hussain ◽  
Muhammad Humble Khalid Tareen ◽  
Jiri Militky ◽  
...  

The versatile one-pot green synthesis of a highly concentrated and stable colloidal dispersion of silver nanoparticles (Ag NPs) was carried out using the self-assembled tannic acid without using any other hazardous chemicals. Tannic acid (Plant-based polyphenol) was used as a reducing and stabilizing agent for silver nitrate in a mild alkaline condition. The synthesized Ag NPs were characterized for their concentration, capping, size distribution, and shape. The experimental results confirmed the successful synthesis of nearly spherical and highly concentrated (2281 ppm) Ag NPs, capped with poly-tannic acid (Ag NPs-PTA). The average particle size of Ag NPs-PTA was found to be 9.90 ± 1.60 nm. The colloidal dispersion of synthesized nanoparticles was observed to be stable for more than 15 months in the ambient environment (25 °C, 65% relative humidity). The synthesized AgNPs-PTA showed an effective antimicrobial activity against Staphylococcus Aureus (ZOI 3.0 mM) and Escherichia coli (ZOI 3.5 mM). Ag NPs-PTA also exhibited enhanced catalytic properties. It reduces 4-nitrophenol into 4-aminophenol in the presence of NaBH4 with a normalized rate constant (Knor = K/m) of 615.04 mL·s−1·mg−1. For comparison, bare Ag NPs show catalytic activity with a normalized rate constant of 139.78 mL·s−1·mg−1. Furthermore, AgNPs-PTA were stable for more than 15 months under ambient conditions. The ultra-high catalytic and good antimicrobial properties can be attributed to the fine size and good aqueous stability of Ag NPs-PTA. The unique core-shell structure and ease of synthesis render the synthesized nanoparticles superior to others, with potential for large-scale applications, especially in the field of catalysis and medical.


CrystEngComm ◽  
2021 ◽  
Vol 23 (15) ◽  
pp. 2793-2800
Author(s):  
Xueshuai Chen ◽  
Rongli Jiang ◽  
Yu Gao ◽  
Zihan Zhou ◽  
Xingwen Wang

Nano-sized ZSM-5 with superior catalytic properties was synthesized from LAPONITE® as one of the Si sources by a dry gel conversion method.


Author(s):  
Yangyang Ren ◽  
Chuanliang Li ◽  
Baosong Li ◽  
Fan Gao ◽  
Xinghua Zhang ◽  
...  

PtPd nanoframes with excellent catalytic properties were obtained by etching Pd@PdPt core–shell RDs with Fe3+ in an acid environment.


Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 788
Author(s):  
Jian-Huan Wang ◽  
Ting Wang ◽  
Jian-Jun Zhang

Controllable growth of wafer-scale in-plane nanowires (NWs) is a prerequisite for achieving addressable and scalable NW-based quantum devices. Here, by introducing molecular beam epitaxy on patterned Si structures, we demonstrate the wafer-scale epitaxial growth of site-controlled in-plane Si, SiGe, and Ge/Si core/shell NW arrays on Si (001) substrate. The epitaxially grown Si, SiGe, and Ge/Si core/shell NW are highly homogeneous with well-defined facets. Suspended Si NWs with four {111} facets and a side width of about 25 nm are observed. Characterizations including high resolution transmission electron microscopy (HRTEM) confirm the high quality of these epitaxial NWs.


CrystEngComm ◽  
2015 ◽  
Vol 17 (8) ◽  
pp. 1765-1768 ◽  
Author(s):  
Zhiqiang Cheng ◽  
Mingyue Yu ◽  
Guixia Yang ◽  
Lijuan Kang

With the help of bio-molecule l-lysine, a seeded growth method has been developed and Pt–ZnO porous nanoribbons have been successfully obtained. For the catalytic applications of CO oxidation and the photocatalytic degradation of MO, the hybrid nanomaterial exhibits remarkably enhanced catalytic properties.


1997 ◽  
Vol 119 (30) ◽  
pp. 7019-7029 ◽  
Author(s):  
Xiaogang Peng ◽  
Michael C. Schlamp ◽  
Andreas V. Kadavanich ◽  
A. P. Alivisatos
Keyword(s):  

ACS Nano ◽  
2015 ◽  
Vol 9 (4) ◽  
pp. 4006-4016 ◽  
Author(s):  
Arian Ghorbanpour ◽  
Abhishek Gumidyala ◽  
Lars C. Grabow ◽  
Steven P. Crossley ◽  
Jeffrey D. Rimer

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