scholarly journals Piperidinium-based ionic liquid electrolyte with linear solvent and LiODFB for LiFePO4/Li cells at room and high temperature

RSC Advances ◽  
2017 ◽  
Vol 7 (79) ◽  
pp. 50135-50142 ◽  
Author(s):  
Ximei Gao ◽  
Qunting Qu ◽  
Guobin Zhu ◽  
Tian Gao ◽  
Feng Qian ◽  
...  

Lithium difluoro(oxalato)borate (LiODFB) combines the advantages of the salts LiBOB and LiBF4 when used in electrolytes for lithium ion cells.

2019 ◽  
Vol 25 (1) ◽  
pp. 1647-1657 ◽  
Author(s):  
Mathieu Martinez ◽  
Cristina Iojoiu ◽  
Patrick Judeinstein ◽  
L. Cointeaux ◽  
Jean-Claude Lepretre ◽  
...  

2018 ◽  
Vol 283 ◽  
pp. 111-120 ◽  
Author(s):  
Fuxiao Liang ◽  
Jiali Yu ◽  
Jiahui Chen ◽  
Dong Wang ◽  
Chengdong Lin ◽  
...  

2017 ◽  
Vol 164 (4) ◽  
pp. A701-A708 ◽  
Author(s):  
Solveig Böhme ◽  
Manfred Kerner ◽  
Johan Scheers ◽  
Patrik Johansson ◽  
Kristina Edström ◽  
...  

2011 ◽  
Vol 56 (3) ◽  
pp. 1344-1351 ◽  
Author(s):  
Larisa S. Plashnitsa ◽  
Eiji Kobayashi ◽  
Shigeto Okada ◽  
Jun-ichi Yamaki

2021 ◽  
Author(s):  
Thushan Pathirana ◽  
Dmitrii Rakov ◽  
Fangfang Chen ◽  
Maria Forsyth ◽  
Robert Kerr ◽  
...  

<p>ABSTRACT </p><p>Cell formation of lithium-ion cells impacts the evolution of the solid electrolyte interphase (SEI) and the cell cycle stability. Lithium metal anodes are an important step in the development of high energy density batteries owing to the high theoretical specific capacity of lithium metal. However, most lithium metal battery research has used a conventional lithium-ion formation protocol; this is time consuming, costly and does not account for the different properties of the lithium metal electrode. Here, we have used a recently reported promising phosphonium bis(fluorosulfonyl)imide ionic liquid electrolyte coupled with an NMC622 high areal capacity cathode (>3.5 mAh/cm2) to investigate the effect of cell formation rates. A faster formation protocol comprised of a pulsed 1.25C current decreased the formation time by 56 % and gave a 38 % greater capacity retention after 50 cycles when compared to formation at C/20. Electrochemical impedance spectroscopy measurements showed that the fast formation gave rise to a lower-resistance SEI. Column-like lithium deposits with reduced porous lithium domains between the particles were observed using scanning electron microscope imaging. To underline the excellent performance of these high energy-density cells, a 56 % greater stack specific energy was achieved compared to the analogous graphite-based lithium-ion cell chemistries. </p>


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