scholarly journals Highly transparent and flame-retardant epoxy composites based on a hybrid multi-element containing POSS derivative

RSC Advances ◽  
2017 ◽  
Vol 7 (73) ◽  
pp. 46139-46147 ◽  
Author(s):  
Cheng Liu ◽  
Ting Chen ◽  
Conghui Yuan ◽  
Ying Chang ◽  
Guorong Chen ◽  
...  

Epoxy resin modified with ODMAS comprising a POSS core and sixteen DOPO groups possess high transparency, excellent flame retardant property and enhanced mechanical strength.

2021 ◽  
pp. 51230
Author(s):  
Fu‐Qu Pang ◽  
Xin‐Duo Liu ◽  
Xian‐Ting Zheng ◽  
Yu‐Cai Lin ◽  
Rong‐Kun Jian

2019 ◽  
Vol 30 (8) ◽  
pp. 2136-2142 ◽  
Author(s):  
Zinan Zhang ◽  
Haifeng Pan ◽  
Wenbin Ma ◽  
Jieli Liang ◽  
Qi Shen ◽  
...  

Nanomaterials ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 625 ◽  
Author(s):  
Shin Young Park ◽  
Simyub Yook ◽  
Sooim Goo ◽  
Wanhee Im ◽  
Hye Jung Youn

Cellulose nanofibrils (CNFs) have been used as reinforcing elements in optically transparent composites by combination with polymer matrices. In this study, strong, optically transparent, and thick CNF/epoxy composites were prepared by immersing two or four layers of CNF sheets in epoxy resin. The morphology of the CNF, the preparation conditions of the CNF sheet, and the grammage and layer numbers of the CNF sheets were controlled. The solvent-exchanged CNF sheets resulted in the production of a composite with high transparency and low haze. The CNF with smaller width and less aggregated fibrils, which are achieved by carboxymethylation, and a high number of grinding passes are beneficial in the production of optically transparent CNF/epoxy composites. Both the grammage and number of stacked layers of sheets in a composite affected the optical and mechanical properties of the composite. A composite with a thickness of 450–800 μm was prepared by stacking two or four layers of CNF sheets in epoxy resin. As the number of stacked sheets increased, light transmittance was reduced and the haze increased. The CNF/epoxy composites with two layers of low grammage (20 g/m2) sheets exhibited high light transmittance (>90%) and low haze (<5%). In addition, the composites with the low grammage sheet had higher tensile strength and elastic modulus compared with neat epoxy and those with high grammage sheets.


2013 ◽  
Vol 652-654 ◽  
pp. 84-88
Author(s):  
Jian Xiong Wei ◽  
Gui Long Xu ◽  
Jian Hu ◽  
Jin Yang

By modifying O-cresol Formaldehyde epoxy resin with DOPO and Diethanolamine, and then neutralized by acetic acid, phosphorous-containing epoxy emulsion with excellent flame retardancy can be obtained under strong agitation. Diethanolamine opening rate and neutralized degree to the formation of epoxy emulsion were optimized. The flame-retardant property of the cured phosphorous-containing epoxy resin was test by UL-94, LOI and TGA method. The result shows that when the opening rate of Diethanolamine is 25.0% and the neutralized degree is 95.0%, stable epoxy emulsion can be obtained. When phosphorus content of the epoxy resin was 3.0wt%, the LOI value of the resin can be reach to 39.2 and pass the UL-94 test,the 700°C char remaining is 30.0wt%. The result shows that the flame retardant mechanism of the phosphorous-containing epoxy resin is mainly through a condensed- phase mechanism.


Author(s):  
Zhong Liu ◽  
Zhao Yu ◽  
Tang Qiaolin ◽  
Zhang Kaixin ◽  
Deng Weihao ◽  
...  

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