scholarly journals Corrosion properties of steel in 1-butyl-3-methylimidazolium hydrogen sulfate ionic liquid systems for desulfurization application

RSC Advances ◽  
2017 ◽  
Vol 7 (77) ◽  
pp. 48526-48536 ◽  
Author(s):  
Qian Zeng ◽  
Jinwei Zhang ◽  
Hongye Cheng ◽  
Lifang Chen ◽  
Zhiwen Qi
Keyword(s):  
Weight Loss ◽  
Ionic Liquid ◽  
Hydrogen Sulfate ◽  
Corrosion Properties ◽  
Liquid Systems

The corrosivity of [BMIM]HSO4-based systems for desulfurization applications were investigated by weight loss and surface analyses.

1, 1’-Sulfinyldiethylammonium Bis (Hydrogen Sulfate) as a Recyclable Dicationic Ionic Liquid Catalyst for the Efficient Solvent-free Synthesis of 3, 4-Dihydropyrimidin-2(1H)-ones via Biginelli Reaction

2020 ◽  
Vol 23 (2) ◽  
pp. 157-167
Author(s):  
Zainab Ehsani-Nasab ◽  
Ali Ezabadi
Keyword(s):  
Ionic Liquid ◽  
Biginelli Reaction ◽  
Aromatic Aldehydes ◽  
Solvent Free ◽  
Hydrogen Sulfate ◽  
One Pot ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid ◽  
Solvent Free Conditions ◽  
Dicationic Ionic Liquid

Objective: A facile and efficient method for synthesis of 3, 4-dihydropyrimidin-2(1H)-ones via Biginelli reaction catalyzed by a novel dicationic Brönsted acidic ionic liquid, [(EtNH2)2SO][HSO4]2, has been successfully developed. Material and Method:: 3, 4-Dihydropyrimidin-2(1H)-ones were synthesized through one-pot condensation of aromatic aldehydes, ethyl acetoacetate, and urea under solvent-free conditions using [(EtNH2)2SO][HSO4]2 as a novel catalyst. The progress of the reaction was monitored by thin-layer chromatography (ethyl acetate / n-hexane = 1 / 5). The products have been characterized by IR, 1H NMR, 13C NMR, and also by their melting points. Results: In this research, a library of dihydropyrimidinone derivatives was synthesized via Biginelli reaction under solvent-free conditions at 120oC using [(EtNH2)2SO][HSO4]2 as a catalyst. Various aromatic aldehydes, as well as heteroaromatic aldehydes, were employed, affording good to high yields of the corresponding products and illustrating the substrate generality of the present method. In addition, the prepared dicationic Brönsted acidic ionic liquid can be easily recovered and reused. Conclusion: 1, 1’-Sulfinyldiethylammonium bis (hydrogen sulfate), as a novel dicationic ionic liquid, can act as a highly efficient catalyst for the synthesis of 3, 4-dihydropyrimidin-2(1H)-ones under solvent-free conditions.

scholarly journals Leaching Chalcopyrite with an Imidazolium-Based Ionic Liquid and Bromide

Metals ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 183 ◽  
Author(s):  
Marcelo Rodríguez ◽  
Luís Ayala ◽  
Pedro Robles ◽  
Rossana Sepúlveda ◽  
David Torres ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Ionic Liquid ◽  
Acid Leaching ◽  
High Thermal Stability ◽  
Complexing Agent ◽  
Hydrogen Sulfate ◽  
Operational Conditions ◽  
Bromide Ions ◽  
Novel Applications ◽  
Ionic Liquid Concentration

The unique properties of ionic liquids (ILs) drive the growing number of novel applications in different industries. The main features of ILs are high thermal stability, recyclability, low flash point, and low vapor pressure. This study investigated pure chalcopyrite dissolution in the presence of the ionic liquid 1-butyl-3-methylimidazolium hydrogen sulfate, [BMIm]HSO4, and a bromide-like complexing agent. The proposed system was compared with acid leaching in sulfate media with the addition of chloride and bromide ions. The results demonstrated that the use of ionic liquid and bromide ions improved the chalcopyrite leaching performance. The best operational conditions were at a temperature of 90 °C, with an ionic liquid concentration of 20% and 100 g/L of bromide.

Modeling Corrosion Property of High Chromium Cast Iron under H3PO4 Medium Condition Using Artificial Intelligence

2010 ◽  
Vol 150-151 ◽  
pp. 1054-1057
Author(s):  
Song Min Zhang ◽  
Liu Jie Xu
Keyword(s):  
Neural Network ◽  
Weight Loss ◽  
Cast Iron ◽  
Bp Neural Network ◽  
Corrosion Property ◽  
Corrosion Properties ◽  
High Chromium ◽  
High Chromium Cast Iron ◽  
Chromium Cast Iron ◽  
Corrosion Time

The components in slurry pump suffer serious corrosion and abrasion in the phosphorus fertilizer manufacturing process because they undergo corrosion of H3PO4 medium and impact of particles at the same time. Presently, High chromium cast irons are often used to produce the components in slurry pump. In order to reveal the corrosive law, the corrosion properties of high chromium cast iron with 26wt.%Cr content (Cr26) were tested under different H3PO4 medium concentration conditions. Using back-propagation (BP) neural network, the non-linear relationship between the corrosion weight losses (W) and H3PO4 concentration, corrosion time (C, t) is established on the base of the dealing with experimental data. The results show that the well-trained BP neural network can predict the wear weight loss precisely according to H3PO4 concentration and corrosion time. The prediction results reveal that corrosion weight loss rises linearly with increasing corrosion time. The H3PO4 concentration has obvious effect on corrosion property. When H3PO4 concentration is lower than about 0.5mol/L, high chromium cast iron has well resistance to H3PO4 corrosion. However, the corrosion resistance of high chromium cast iron rapidly decreases when the H3PO4 concentration exceed about 0.8 mol/L. It is suggest the high chromium cast iron be used under the condition of H3PO4 concentration of lower 0.8 mol/L.

Radionuclide and tensiometry approaches to studying lysozyme behaviors in water–ionic liquid systems

2017 ◽  
Vol 27 (3) ◽  
pp. 296-298 ◽  
Author(s):  
Maria G. Chernysheva ◽  
Alena E. Averina ◽  
Oxana A. Soboleva ◽  
Gennadii A. Badun
Keyword(s):  
Ionic Liquid ◽  
Approaches To Studying ◽  
Liquid Systems

Interfacial tension and wetting behavior of air/oil/ionic liquid systems

2007 ◽  
Vol 285 (14) ◽  
pp. 1601-1605 ◽  
Author(s):  
Takashi Matsuda ◽  
Yu Mishima ◽  
Saeid Azizian ◽  
Hiroki Matsubara ◽  
Takanori Takiue ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Interfacial Tension ◽  
Wetting Behavior ◽  
Liquid Systems
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