scholarly journals Lanthanide contraction and chelating effect on a new family of lanthanide complexes with tetrakis(O-isopropyl)methyle-nediphosphonate: synthesis, structures and terahertz time-domain spectroscopy

RSC Advances ◽  
2017 ◽  
Vol 7 (66) ◽  
pp. 41651-41666 ◽  
Author(s):  
Yan Ma ◽  
Yong-Sheng Yang ◽  
Yu-Han Jiang ◽  
Yue-Xue Li ◽  
Min Liu ◽  
...  
Keyword(s):  
Time Domain ◽  
Lanthanide Complexes ◽  
Room Temperature ◽  
Terahertz Time Domain Spectroscopy ◽  
Time Domain Spectroscopy ◽  
New Family ◽  
Lanthanide Contraction ◽  
Chelating Effect

Sixteen lanthanide–diphosphate complexes have been synthesized by the reaction of lanthanide chlorides and tetrakis(O-isopropyl)methylenediphosphonate ligand in the solvent of acetonitrile (with ethanol or DMF) at room temperature.

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