scholarly journals Doping-template approach of porous-walled graphitic nanocages for superior performance anodes of lithium ion batteries

RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42083-42087 ◽  
Author(s):  
Zhao Min Sheng ◽  
Xin Jian Chang ◽  
Yu Hang Chen ◽  
Cheng Yang Hong ◽  
Na Na Li ◽  
...  

Removal of the N-doped template creates nanopores in the shells of nanocages. The created nanopores enhance fast ion diffusion.

2017 ◽  
Vol 5 (25) ◽  
pp. 13161-13167 ◽  
Author(s):  
Jennifer Heath ◽  
Hungru Chen ◽  
M. Saiful Islam

Developing rechargeable magnesium batteries has become an area of growing interest as an alternative to lithium-ion batteries largely due to their potential to offer increased energy density from the divalent charge of the Mg ion.


2020 ◽  
Author(s):  
Chuhong Wang ◽  
Koutarou Aoyagi ◽  
Muratahan Aykol ◽  
Tim Mueller

The development of all-solid-state lithium ion batteries has been hindered by the formation of a poorly conductive interphase at the interface between electrode and electrolyte materials. In the manuscript, we shed light on this problem by computationally evaluating potential lithium ion diffusion pathways through metastable arrangements of product phases that can form at 56 interfaces between common electrode and electrolyte materials. The evaluation of lithium-ion conductivities in the product phases is made possible by the use of machine-learned interatomic potentials trained on the fly. We identify likely reasons for the degradation of solid-state battery performance and discuss how these problems could be mitigated. These results provide enhanced understanding of how interface impedance growth limits the performance of all-solid-state lithium-ion batteries.


2020 ◽  
Vol 56 (64) ◽  
pp. 9142-9145 ◽  
Author(s):  
Jiakang Min ◽  
Xin Wen ◽  
Tao Tang ◽  
Xuecheng Chen ◽  
Kaifu Huo ◽  
...  

The 3D hollow carbon sphere/porous carbon flake hybrids are facilely prepared from the carbonization of both hydrocarbon and halogen-containing plastic wastes by a general template method, which exhibits superior performance in a lithium-ion battery.


2013 ◽  
Vol 1 (30) ◽  
pp. 8525 ◽  
Author(s):  
Huijuan Zhou ◽  
Lang Liu ◽  
Xingchao Wang ◽  
Fuxin Liang ◽  
Shujuan Bao ◽  
...  

2020 ◽  
Vol 8 (37) ◽  
pp. 19444-19453 ◽  
Author(s):  
Ke Wen Mu ◽  
Kai Xi Liu ◽  
Zhi Yong Wang ◽  
Shahid Zanman ◽  
Yan Hong Yin ◽  
...  

Surface/interface modification is developed to tune the electrolyte wettability of a carbon nanotube current collector for controlling the lithium ion diffusion and achieving high voltage foldable lithium-ion batteries.


Author(s):  
E. Thauer ◽  
G. S. Zakharova ◽  
E. I. Andreikov ◽  
V. Adam ◽  
S. A. Wegener ◽  
...  

AbstractFor the first time, ZnO/C composites were synthesized using zinc glycerolate as a precursor through one-step calcination under a nitrogen atmosphere. The effect of the heat treatment conditions on the structure, composition, morphology as well as on the electrochemical properties regarding application in lithium-ion batteries are investigated. The products obtained by calcination of the precursor in nitrogen at 400—800 °C consist of zinc oxide nanoparticles and amorphous carbon that is in-situ generated from organic components of the glycerolate precursor. When used as anode material for lithium-ion batteries, the as-prepared ZnO/C composite synthesized at a calcination temperature of 700 °C delivers initial discharge and charge capacities of 1061 and 671 mAh g−1 at a current rate of 100 mA g−1 and hence 1.5 times more than bare ZnO, which reaches only 749/439 mAh g−1. The native carbon improves the conductivity, allowing efficient electronic conductivity and Li-ion diffusion. By means of ex-situ XRD studies a two-step storage mechanism is proven.


2018 ◽  
Vol 165 (5) ◽  
pp. A939-A946 ◽  
Author(s):  
Hai Li ◽  
Bin Zhang ◽  
Bin Lin ◽  
Yanzhang Yang ◽  
Yang Zhao ◽  
...  

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