scholarly journals Design of micro-shell Cu–Al porous ceramometals as catalysts for the water–gas shift reaction

RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42443-42454 ◽  
Author(s):  
S. Tikhov ◽  
T. Minyukova ◽  
K. Valeev ◽  
S. Cherepanova ◽  
A. Salanov ◽  
...  

Development of a new type of ceramometal catalyst, CuAlO/CuAl, for WGS reaction with an oxide microshell.

Author(s):  
Yuanting Tang ◽  
Yongjie Chen ◽  
Xiao Liu ◽  
Chengxiong Wang ◽  
Yunkun Zhao ◽  
...  

The bifunctional role of noble metal/oxide interface in the activation of reactants is of vital importance in heterogeneous catalysis of water-gas shift (WGS) reaction. Herein, three types of shape-controlled TiO2...


2020 ◽  
Vol 8 (37) ◽  
pp. 19467-19472
Author(s):  
Chengcheng Shi ◽  
Dachao Yuan ◽  
Luping Ma ◽  
Yaguang Li ◽  
Yangfan Lu ◽  
...  

A new photothermal device is constructed by the Cr based selective light absorption film which can heat the 2D CuZnAl to 297 °C under 1 standard sun irradiation, leading to a 192 mmol g−1 h−1 of H2 production rate from 1 sun irradiated WGS reaction.


Author(s):  
Marc Ziemba ◽  
Veronica Ganduglia-Pirovano ◽  
Christian Hess

The mechanism of the low-temperature water–gas shift (LT-WGS) reaction over Au/CeO2 catalysts with different ceria terminations, i.e., (111), (110), and (100) facets, was investigated. Using combined operando Raman and UV-Vis...


2017 ◽  
Vol 19 (3) ◽  
pp. 2201-2206 ◽  
Author(s):  
Ming-Wen Chang ◽  
Wen-Shyan Sheu

Au+ falls into a relatively favorable condition for catalyzing the WGS reaction due to a compromise between attractive interaction and Coulomb repulsion between the Au and the transferred proton.


2015 ◽  
Vol 5 (5) ◽  
pp. 2752-2760 ◽  
Author(s):  
Ajay Jha ◽  
Dae-Woon Jeong ◽  
Jae-Oh Shim ◽  
Won-Jun Jang ◽  
Yeol-Lim Lee ◽  
...  

Incorporation of both Cu and Ni together into the crystalline lattice of Fe2O3 results in a significant increase in the catalytic activity and also suppresses the methanation reaction in the high-temperature water-gas shift (HT-WGS) reaction.


2019 ◽  
Vol 9 (9) ◽  
pp. 2125-2131 ◽  
Author(s):  
Fuli Liu ◽  
Lizhu Song ◽  
Shuxin Ouyang ◽  
Hua Xu

Cu–ZnO catalyst with a well-designed nanojunction structure was fabricated for the photothermal catalysis of the water-gas shift (WGS) reaction.


Author(s):  
Yong Min Park ◽  
Jae Min Cho ◽  
Gui Young Han ◽  
Jong Wook Bae

Highly ordered mesoporous Fe-Ni bimetal oxides (m-FeNi) prepared by a nanocasting method using a hard template of KIT-6 were investigated for an alternative high temperature water-gas shift (HT-WGS) reaction. As-synthesized...


Author(s):  
Qijun Pei ◽  
Teng He ◽  
Yang Yu ◽  
Zijun Jing ◽  
Jintao Wang ◽  
...  

Water-gas shift (WGS) reaction is a key chemical process for CO removal and hydrogen generation that convert CO and H2O to CO2 and H2. The activation of H2O at the...


RSC Advances ◽  
2016 ◽  
Vol 6 (58) ◽  
pp. 52754-52760 ◽  
Author(s):  
Hyun-Suk Na ◽  
Chang-Il Ahn ◽  
Ajay Jha ◽  
Kyung Soo Park ◽  
Won-Jun Jang ◽  
...  

In this study, we report an investigation of the low temperature water–gas shift (LT-WGS) reaction over a series of non-noble metal doped (Me = Mn, Fe, Co, and Ni) mesoporous Co3O4 catalysts.


2014 ◽  
Vol 16 (16) ◽  
pp. 7521-7530 ◽  
Author(s):  
Nina Perkas ◽  
Poernomo Gunawan ◽  
Galina Amirian ◽  
Zhan Wang ◽  
Ziyi Zhong ◽  
...  

The CuO–ZnO/TiO2 catalyst prepared by the ultrasound assisted method demonstrates superior activity in water gas shift reaction in comparison with the catalysts synthesized by incipient wetness impregnation. The sonochemical preparation offers at least two advantages: (1) generation of mesopores on the catalyst surface and (2) doping of Zn into the CuO phase.


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