scholarly journals Effects of Cu addition on the corrosion behavior of NiCoCrMo alloys in neutral chloride solution

RSC Advances ◽  
2017 ◽  
Vol 7 (65) ◽  
pp. 40779-40790 ◽  
Author(s):  
Biaobiao Yang ◽  
Jiaxiang Li ◽  
Xiaojuan Gong ◽  
Yan Nie ◽  
Yunping Li

The influence of Cu addition (0–4 mass%) on the corrosion behavior of Ni–30Co–16Cr–15Mo alloy in neutral chloride solution is investigated by electrochemical measurements. Some essential surface analysis are also conducted to explain the corrosion mechanism.

2014 ◽  
Vol 789 ◽  
pp. 622-626
Author(s):  
Peng Chao Zhang ◽  
Jian Zhang ◽  
Jin Chuan Jie ◽  
Yuan Gao ◽  
Yong Dong ◽  
...  

The effect of different alloying elements on corrosion behavior of copper alloys was investigated using electrochemical corrosion and salt spray corrosion test in NaCl solution. Cu-Ag has the most stable corrosion current in the potentiostatic scanning test, exhibiting a better corrosion resistant performance. It can be analyzed from corrosion surface morphologies that Cu-Ag presents exfoliation corrosion mechanism while Cu-Sn shows crevice corrosion mechanism. Cu-Mg has a complex corrosion process caused by multiple corrosion mechanism. In the salt spray corrosion test, the corrosion degree of Cu-Ag is lighter than those of Cu-Sn and Cu-Mg after 24h test. Therefore, the Cu-Ag alloy exhibits the best corrosion resistance in chloride solution.


Materials ◽  
2019 ◽  
Vol 12 (13) ◽  
pp. 2069 ◽  
Author(s):  
Jian Ding ◽  
Xin Liu ◽  
Yujiang Wang ◽  
Wei Huang ◽  
Bo Wang ◽  
...  

The effect of Sn addition on the microstructure and corrosion behavior of extruded Mg–5Zn–4Al–xSn (0, 0.5, 1, 2, and 3 wt %) alloys was investigated by optical microscopy (OM), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), electrochemical measurements, and immersion tests. Microstructural results showed that the average grain size decreased to some degree and the amount of precipitates increased with the increasing amount of Sn. The extruded Mg–5Zn–4Al–xSn alloy mainly consisted of α-Mg, Mg32(Al,Zn)49, and Mg2Sn phases as the content of Sn was above 1 wt %. Electrochemical measurements indicated that the extruded Mg–5Zn–4Al–1Sn (ZAT541) alloy presented the best corrosion performances, with corrosion potential (Ecorr) and corrosion current density (Icorr) values of −1.3309 V and 6.707 × 10−6 A·cm−2, respectively. Furthermore, the corrosion mechanism of Sn is discussed in detail.


2012 ◽  
Vol 472-475 ◽  
pp. 161-164
Author(s):  
Yu Gao Liu

This paper represents a summary of experimental results dealing with the time dependence of surface diffusion alloyed microstructure and its corrosion behavior at given temperature. The experiments were performed at 485°C for different solid diffusion time (6h, 12h, 18h ) and thus the surface alloyed microstructure of pure magnesium has been obtained. Optical and electrical microscopy and EDS compositions analysis were used to examine the cross sectional microstructure characteristics of alloyed layers of treated samples. It is shown that the new phases formed and its continuity, depending on the diffusion treated time at given temperature, have a noticeable influence on corrosion resistance and corrosion mechanism. The new formed phase Al5Mg11Zn4 was inert to the chloride solution compared with pure magnesium and acted as a corrosion barrier. It was concluded that the continuous Al5Mg11Zn4 phase was beneficial from the point of view of corrosion resistance.


Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 517
Author(s):  
Bin Sun ◽  
Lei Cheng ◽  
Chong-Yang Du ◽  
Jing-Ke Zhang ◽  
Yong-Quan He ◽  
...  

The atmospheric corrosion behavior of a hot-rolled strip with four types (I–IV) of oxide scale was investigated using the accelerated wet–dry cycle corrosion test. Corrosion resistance and porosity of oxide scale were studied by potentiometric polarization measurements. Characterization of samples after 80 cycles of the wet–dry corrosion test showed that scale comprised wüstite and magnetite had strongest corrosion resistance. Oxide scale composed of inner magnetite/iron (>70%) and an outer magnetite layer had the weakest corrosion resistance. The corrosion kinetics (weight gain) of each type of oxide scale followed an initial linear and then parabolic (at middle to late corrosion) relationship. This could be predicted by a simple kinetic model which showed good agreement with the experimental results. Analysis of the potentiometric polarization curves, obtained from oxide coated steel electrodes, revealed that the type I oxide scale had the highest porosity, and the corrosion mechanism resulted from the joint effects of electrochemical behavior and the porosity of the oxide scale. In the initial stage of corrosion, the corrosion product nucleated and an outer rust layer formed. As the thickness of outer rust layer increased, the corrosion product developed on the scale defects. An inner rust layer then formed in the localized pits as crack growth of the scale. This attacked the scale and expanded into the substrate during the later stage of corrosion. At this stage, the protective effect of the oxide scale was lost.


1993 ◽  
Vol 34 (1) ◽  
pp. 27-40 ◽  
Author(s):  
E. Akiyama ◽  
H. Yoshioka ◽  
J.H. Kim ◽  
H. Habazaki ◽  
A. Kawashima ◽  
...  

2019 ◽  
Vol 22 (suppl 1) ◽  
Author(s):  
Stephania Cappellari de Rezende ◽  
Isabela Dainezi ◽  
Raíra Chefer Apolinario ◽  
Lucíola Lucena de Sousa ◽  
Neide Aparecida Mariano

CORROSION ◽  
2003 ◽  
Vol 59 (7) ◽  
pp. 597-605 ◽  
Author(s):  
S. Z. Luo ◽  
Y. G. Zheng ◽  
M. C. Li ◽  
Z. M. Yao ◽  
W. Ke

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