scholarly journals Porous SnO2 hexagonal prism-attached Pd/rGO with enhanced electrocatalytic activity for methanol oxidation

RSC Advances ◽  
2017 ◽  
Vol 7 (47) ◽  
pp. 29909-29915 ◽  
Author(s):  
Yiran Hu ◽  
Tao Mei ◽  
Jinhua Li ◽  
Jianying Wang ◽  
Xianbao Wang
Keyword(s):  
Methanol Oxidation ◽  
Electrocatalytic Activity ◽  
Hexagonal Prism ◽  
Catalytic Activities ◽  
Oxidation Of Methanol

Herein, we chose porous SnO2 hexagonal prisms as a new promoter for Pd/rGO electrocatalyst. The as-prepared catalyst exhibited excellent electrochemical catalytic activities and enhanced durability for the oxidation of methanol.

Fabrication of CuO–1.5ZrO2 composite thin film, from heteronuclear molecular complex and its electrocatalytic activity towards methanol oxidation

RSC Advances ◽  
2015 ◽  
Vol 5 (126) ◽  
pp. 103852-103862 ◽  
Author(s):  
Muhammad Ali Ehsan ◽  
Abbas Saeed Hakeem ◽  
Hamid Khaledi ◽  
Muhammad Mazhar ◽  
Muhammad Mehmood Shahid ◽  
...  
Keyword(s):  
Thin Film ◽  
Methanol Oxidation ◽  
Molecular Complex ◽  
Electrocatalytic Activity ◽  
Composite Thin Film ◽  
Composite Electrodes ◽  
Single Source ◽  
Oxidation Of Methanol ◽  
Single Source Precursor

CuO–1.5ZrO2 composite electrodes fabricated from a single source precursor [Cu4Zr6(μ-O)8(dmap)4(OAc)12]·H2O have been utilized for the oxidation of methanol.

scholarly journals Carbon Supported Au-Pd-PdO with Low Metal Loading for Electro-oxidation of Methanol in Alkaline Medium

2014 ◽  
Vol 17 (3) ◽  
pp. 133-138
Author(s):  
V-H Ramos-Sánchez ◽  
Diana Brito-Picciotto ◽  
Ramón Gómez-Vargas ◽  
David Chávez-Flores ◽  
Edgar Valenzuela
Keyword(s):  
Methanol Oxidation ◽  
Alkaline Medium ◽  
Electrocatalytic Activity ◽  
Chemical Reduction ◽  
Active Phase ◽  
Metal Loading ◽  
Oxidation Of Methanol ◽  
Electro Oxidation

The present work examined two Pd-based alloys supported on carbon: AuPd and Au2Pd, both synthesized by chemical reduction with NaBH4. The low Au-Pd loading electrocatalysts were physicochemically and electrochemically characterized. Electrocatalytic activity for methanol oxidation was found exclusively in AuPd/C. However, it was revealed that such reaction was promoted by PdO occurring in the actual active phase of the supported electrocatalyst, through the formation of Au-Pd-PdO ensemble sites.

Phase-segregated Pt–Ni chain-like nanohybrids with high electrocatalytic activity towards methanol oxidation reaction

Nanoscale ◽  
2014 ◽  
Vol 6 (9) ◽  
pp. 4635-4641 ◽  
Author(s):  
Li-Li Wang ◽  
Dong-Feng Zhang ◽  
Lin Guo
Keyword(s):  
Methanol Oxidation ◽  
Electrocatalytic Activity ◽  
Oxidation Reaction ◽  
Methanol Oxidation Reaction ◽  
Catalytic Activities

We report the fabrication of phase-segregated Pt-Ni chain-like nanohybrids composed of monometallic counterparts attached to each other, which exhibit high catalytic activities towards the methanol oxidation reaction (MOR).

scholarly journals Catalytic activities for methanol oxidation on ultrathin CuPt3 wavy nanowires with/without smart polymer

2016 ◽  
Vol 7 (8) ◽  
pp. 5414-5420 ◽  
Author(s):  
Gengtao Fu ◽  
Xiaoxiao Yan ◽  
Zhiming Cui ◽  
Dongmei Sun ◽  
Lin Xu ◽  
...  
Keyword(s):  
Methanol Oxidation ◽  
Electrocatalytic Activity ◽  
Oxidation Reaction ◽  
Methanol Oxidation Reaction ◽  
Smart Polymer ◽  
Catalytic Activities

CuPt3 nanowires are synthesized with a thermosensitive amine-terminated poly(N-isopropylacrylamide) polymer, displaying “smart” temperature-controllable electrocatalytic activity towards the methanol oxidation reaction.

Improved electrocatalytic activity of Pt catalyst supported on core-shell CMs@NiO for methanol oxidation

2021 ◽  
Author(s):  
Yongping Luo ◽  
Wei Zhong ◽  
Ping Huang ◽  
Hui Ou ◽  
Haiyan Fu ◽  
...  
Keyword(s):  
Methanol Oxidation ◽  
Electrocatalytic Activity ◽  
Electrocatalytic Oxidation ◽  
Pt Catalyst ◽  
Core Shell ◽  
Support Material ◽  
Carbon Microspheres ◽  
Oxidation Of Methanol ◽  
Glass Carbon

The enhancement for electrocatalytic oxidation of methanol was achieved by utilizing core-shell carbon microspheres@NiO (CMs@NiO) deposited on glass carbon (GC) as the support material of Pt catalyst. The resultant CMs@NiO/Pt...

scholarly journals Synthesis and Characterization of Electrodeposited C-PANI-Pd-Ni Composite Electrocatalyst for Methanol Oxidation

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
S. S. Mahapatra ◽  
S. Shekhar ◽  
B. K. Thakur ◽  
H. Priyadarshi
Keyword(s):  
Methanol Oxidation ◽  
Electrocatalytic Activity ◽  
Electrochemical Impedance ◽  
Synergistic Effects ◽  
Catalytic Performance ◽  
Charge Transfer Resistance ◽  
Pani Film ◽  
Composite Electrodes ◽  
Transfer Resistance ◽  
Onset Potential

Electropolymerization of aniline at the graphite electrodes was achieved by potentiodynamic method. Electrodeposition of Pd (C-PANI-Pd) and Ni (C-PANI-Ni) and codeposition of Pd-Ni (C-PANI-Pd-Ni) microparticles into the polyaniline (PANI) film coated graphite (C-PANI) were carried out under galvanostatic control. The morphology and composition of the composite electrodes were obtained using scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX) techniques. The electrochemical behavior and electrocatalytic activity of the electrode were characterized using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and chronoamperometric (CA) methods in acidic medium. The C-PANI-Pd-Ni electrode showed an improved catalytic performance towards methanol oxidation in terms of lower onset potential, higher anodic oxidation current, greater stability, lower activation energy, and lower charge transfer resistance. The enhanced electrocatalytic activity might be due to the greater permeability of C-PANI films for methanol molecules, better dispersion of Pd-Ni microparticles into the polymer matrixes, and the synergistic effects between the dispersed metal particles and their matrixes.

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