scholarly journals A 2D approach to surface-tension-confined fluidics on parylene C

RSC Advances ◽  
2017 ◽  
Vol 7 (26) ◽  
pp. 15964-15970 ◽  
Author(s):  
Paola Calcagnile ◽  
Tommaso Dattoma ◽  
Elisa Scarpa ◽  
Antonio Qualtieri ◽  
Laura Blasi ◽  
...  
Keyword(s):  
Surface Tension ◽  
Surface Energy ◽  
Pure Water ◽  
Parylene C ◽  
Water Based

Parylene C-based 2D STC fluidics, where pure water and water-based solutions can flow strictly confined by differences in surface energy.

The nucleation of cavities at grain boundaries

1987 ◽  
Vol 45 ◽  
pp. 288-291
Author(s):  
P. J. Goodhew
Keyword(s):  
Surface Tension ◽  
Surface Energy ◽  
Grain Boundaries ◽  
Radiation Damage ◽  
Impurity Concentration ◽  
Driving Force ◽  
Nucleation And Growth ◽  
Phase Boundaries ◽  
Cavity Nucleation ◽  
Spherical Bubble

Cavity nucleation and growth at grain and phase boundaries is of concern because it can lead to failure during creep and can lead to embrittlement as a result of radiation damage. Two major types of cavity are usually distinguished: The term bubble is applied to a cavity which contains gas at a pressure which is at least sufficient to support the surface tension (2g/r for a spherical bubble of radius r and surface energy g). The term void is generally applied to any cavity which contains less gas than this, but is not necessarily empty of gas. A void would therefore tend to shrink in the absence of any imposed driving force for growth, whereas a bubble would be stable or would tend to grow. It is widely considered that cavity nucleation always requires the presence of one or more gas atoms. However since it is extremely difficult to prepare experimental materials with a gas impurity concentration lower than their eventual cavity concentration there is little to be gained by debating this point.

The Surface Energy between Rubber and Fillers

1930 ◽  
Vol 3 (2) ◽  
pp. 215-228 ◽  
Author(s):  
Fritz Hartner
Keyword(s):  
Surface Tension ◽  
Surface Energy ◽  
Calorimetric Method ◽  
Sources Of Error ◽  
Aging Phenomenon ◽  
Rubber Filler

Abstract The purpose of this research was to increase the reliability and accuracy of the calorimetric method elaborated by Bostroem, and to discover and overcome any difficulties or sources of error in order that the method might be applicable to the investigation of problems concerning the chemistry and technology of rubber. The following points were to be considered: 1. The dependence of the “reinforcing” action of a filler on its concentration, and the utilization of the surface energy between rubber and filler. 2. The evaluation of the surface tension in the system raw rubber/filler. 3. The aging phenomenon of rubber and the possibility of making it reversible 4. The comparison of various commercial gas blacks at a given concentration.

Thermal Performance of Water-Based Suspensions of Phase Change Nanocapsules in a Natural Circulation Loop

2013 ◽  
Author(s):  
C. J. Ho ◽  
Chi-Ming Lai
Keyword(s):  
Heat Transfer ◽  
Phase Change ◽  
Natural Circulation ◽  
Pure Water ◽  
Circulation Loop ◽  
Core Material ◽  
Working Fluid ◽  
Outer Diameter ◽  
Natural Circulation Loop ◽  
Water Based

Experiments were conducted to investigate the heat transfer characteristics of water-based suspensions of phase change nanocapsules in a natural circulation loop with mini-channel heat sinks and heat sources. A total of 23 and 34 rectangular mini-channels, each with width 0.8 mm, depth 1.2 mm, length 50 mm and hydraulic diameter 0.96 mm, were evenly placed on the copper blocks as the heat source and heat sink, respectively. The adiabatic sections of the circulation loop were constructed using PMMA tubes with an outer diameter of 6 mm and an inner diameter of 4 mm, which were fabricated and assembled to construct a rectangular loop with a height of 630 mm and a width of 220 mm. Using a core material of n-eicosane and a shell of urea-formaldehyde resin, the phase change material nanocapsules of mean particle size 150 nm were fabricated successfully and then dispersed in pure water as the working fluid to form the water-based suspensions with mass fractions of the nanocapsules in the range 0.1–1 wt.%. The results clearly indicate that water-based suspensions of phase change nanocapsules can markedly enhance the heat transfer performance of the natural circulation loop considered.

scholarly journals On the contribution of Aitken mode particles to cloud droplet populations at continental background areas – a parametric sensitivity study

2007 ◽  
Vol 7 (3) ◽  
pp. 6077-6112
Author(s):  
T. Anttila ◽  
V.-M. Kerminen
Keyword(s):  
Surface Tension ◽  
Particle Size ◽  
Chemical Composition ◽  
Pure Water ◽  
Particle Surface ◽  
Chemical Properties ◽  
Sensitivity Study ◽  
Geometric Standard Deviation ◽  
Cloud Droplets ◽  
Aitken Mode

Abstract. Aitken mode particles are potentially an important source of cloud droplets in continental background areas. In order to find out which physico-chemical properties of Aitken mode particles are most important regarding their cloud-nucleating ability, we applied a global sensitivity method to an adiabatic air parcel model simulating the number of cloud droplets formed on Aitken mode particles, CD2. The technique propagates uncertainties in the parameters describing the properties of Aitken mode to CD2. The results show that if the Aitken mode particles do not contain molecules that are able to reduce the particle surface tension more than 30% and/or decrease the mass accommodation coefficient of water, α, below 10−2, the chemical composition and modal properties may have roughly an equal importance at low updraft velocities characterized by maximum supersaturations <0.1%. For larger updraft velocities, however, the particle size distribution is clearly more important than the chemical composition. In general, CD2 exhibits largest sensitivity to the particle number concentration, followed by the particle size. Also the shape of the particle mode, characterized by the geometric standard deviation (GSD), can be as important as the mode mean size at low updraft velocities. Finally, the performed sensitivity analysis revealed also that the chemistry may dominate the total sensitivity of CD2 to the considered parameters if: 1) the value of α varies at least one order of magnitude more than what is expected for pure water surfaces (10−2–1), or 2) the particle surface tension varies more than roughly 30% under conditions close to reaching supersaturation.

scholarly journals Aerosol hygroscopicity at high (99 to 100%) relative humidities

2009 ◽  
Vol 9 (4) ◽  
pp. 15595-15640 ◽  
Author(s):  
C. R. Ruehl ◽  
P. Y. Chuang ◽  
A. Nenes
Keyword(s):  
Surface Tension ◽  
Inorganic Compounds ◽  
Droplet Diameter ◽  
Pure Water ◽  
Sodium Dodecyl ◽  
Bulk Solution ◽  
Active Compounds ◽  
Surface Active ◽  
Surface Active Compounds ◽  
Aerosol Hygroscopicity

Abstract. The hygroscopicity of an aerosol largely determines its influence on climate and, for smaller particles, atmospheric lifetime. While much aerosol hygroscopicity data is available at lower relative humidities (RH) and under cloud formation conditions (RH>100%), relatively little data is available at high RH (99.2 to 99.9%). We measured the size of droplets at high RH that had formed on particles composed of one of seven compounds with dry diameters between 0.1 and 0.5 μm, and calculated the hygroscopicity of these compounds. We use a parameterization of the Kelvin term, in addition to a standard parameterization (κ) of the Raoult term, to express the hygroscopicity of surface-active compounds. For inorganic compounds, hygroscopicity could reliably be predicted using water activity data and assuming a surface tension of pure water. In contrast, most organics exhibited a slight to mild increase in hygroscopicity with droplet diameter. This trend was strongest for sodium dodecyl sulfate (SDS), the most surface-active compound studied. The results suggest that partitioning of surface-active compounds away from the bulk solution, which reduces hygroscopicity, dominates any increases in hygroscopicity due to reduced surface tension. This is opposite to what is typically assumed for soluble surfactants. Furthermore, we saw no evidence that micellization limits SDS activity in micron-sized solution droplets, as observed in macroscopic solutions. These results suggest that while the high-RH hygroscopicity of inorganic compounds can be reliably predicted using readily available data, surface-activity parameters obtained from macroscopic solutions with organic solutes may be inappropriate for calculations of the hygroscopicity of micron-sized droplets.

The liquid blister test

2008 ◽  
Vol 464 (2099) ◽  
pp. 2887-2906 ◽  
Author(s):  
Julien Chopin ◽  
Dominic Vella ◽  
Arezki Boudaoud
Keyword(s):  
Surface Tension ◽  
Surface Energy ◽  
Vertical Displacement ◽  
Quantitative Agreement ◽  
Elastic Plates ◽  
Blister Test ◽  
Thin Liquid Layer ◽  
Theoretical Predictions ◽  
Thin Elastic Plates ◽  
Adhesive Forces

We consider a thin elastic sheet adhering to a stiff substrate by means of the surface tension of a thin liquid layer. Debonding is initiated by imposing a vertical displacement at the centre of the sheet and leads to the formation of a delaminated region or ‘blister’. This experiment reveals that the perimeter of the blister takes one of three different forms depending on the vertical displacement imposed. As this displacement is increased, we observe first circular, then undulating and finally triangular blisters. We obtain theoretical predictions for the observed features of each of these three families of blisters. The theory is built upon the Föppl–von Kármán equations for thin elastic plates and accounts for the surface energy of the liquid. We find good quantitative agreement between our theoretical predictions and experimental results, demonstrating that all three families are governed by different balances between elastic and capillary forces. Our results may bear on micrometric tapered devices and other systems, where elastic and adhesive forces are in competition.

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