scholarly journals Pyridinic and pyrrolic nitrogen-rich ordered mesoporous carbon for efficient oxygen reduction in microbial fuel cells

RSC Advances ◽  
2017 ◽  
Vol 7 (24) ◽  
pp. 14669-14677 ◽  
Author(s):  
Leiyu Feng ◽  
Xutao Chen ◽  
Yue Cao ◽  
Yunzhi Chen ◽  
Feng Wang ◽  
...  

Pyridinic and pyrrolic nitrogen-rich, ordered mesoporous carbon was used as the cathode catalyst in MFCs and showed excellent power generation capabilities.

2011 ◽  
Vol 110-116 ◽  
pp. 508-513
Author(s):  
Ling Bin Kong ◽  
Ru Tao Wang ◽  
Xiao Wei Wang ◽  
Zhen Sheng Yang ◽  
Yong Chun Luo ◽  
...  

Metal nanocatalysts, as the anodic materials, have become increasingly important in fuel cells due to their unique physical and chemical properties. Here we report the ordered mesoporous carbon (CMK-3) supported silver nanocatalysts have been prepared through the wet chemical reduction by using the reduction of formaldehyde. The electrochemical properties of the Ag/CMK-3 nanocatalysts for formaldehyde oxidation are studied by cyclic voltammograms (CV) and chronoamperometric curves (i-t) in alkaline aqueous solutions. The results show that the peak current density (from CV) of the Ag/CMK-3 electrode is 112 mA cm-2, above 2 times higher than that of Ag/XC-72 at the same Ag loading (14.15 μg cm-2). Furthermore, the i-t curves demonstrate that the Ag/CMK-3 nanocatalysts are efficient and stable electrocatalysts for anodic oxidation of formaldehyde in alkaline solutions. Our results indicate that the application potential of Ag/CMK-3 nanocatalysts with the improved electrocatalytic activity has far reaching effects on fuel cells and sensors.


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