Synthesis of thiophosphates through a three-component reaction by using sulfur dioxide as the sulfur source

2017 ◽  
Vol 4 (11) ◽  
pp. 2221-2225 ◽  
Author(s):  
Xinxing Gong ◽  
Jiahao Chen ◽  
Jianhe Liu ◽  
Jie Wu
Keyword(s):  
Sulfur Dioxide ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Sulfur Source ◽  
Three Component Reaction

Generation of thiophosphates through a three-component reaction of diaryliodonium tetrafluoroborates, 1,4-diazabicyclo[2.2.2]octane-sulfur dioxide (DABCO·(SO2)2), and diarylphosphine oxides under visible light irradiation is described.

Photoinduced synthesis of (E)-vinyl sulfones through the insertion of sulfur dioxide

2018 ◽  
Vol 5 (21) ◽  
pp. 3153-3157 ◽  
Author(s):  
Tong Liu ◽  
Yechun Ding ◽  
Xiaona Fan ◽  
Jie Wu
Keyword(s):  
Sulfur Dioxide ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Mild Conditions ◽  
Three Component Reaction ◽  
Photoinduced Synthesis

Under visible light irradiation, a three-component reaction of potassium alkyltrifluoroborates, sulfur dioxide and alkynes with the assistance of photocatalysis and in the presence of copper(ii) triflate is described. This transformation affords (E)-vinyl sulfones efficiently with excellent regioselectivity and stereoselectivity under mild conditions.

Substituted Hantzsch esters as radical reservoirs with the insertion of sulfur dioxide under photoredox catalysis

2019 ◽  
Vol 55 (14) ◽  
pp. 2062-2065 ◽  
Author(s):  
Xuefeng Wang ◽  
Haozhe Li ◽  
Guanyinsheng Qiu ◽  
Jie Wu
Keyword(s):  
Sulfur Dioxide ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Photoredox Catalysis ◽  
Three Component Reaction ◽  
Vinyl Azides

A three-component reaction between 4-substituted Hantzsch esters, DABCO·(SO2)2, and vinyl azides in the presence of photoredox catalysts under visible light irradiation is developed. A range of (Z)-2-(alkylsulfonyl)-1-arylethen-1-amines is obtained in moderate to good yields with good regioselectivity and stereoselectivity.

A metal-free route to alkynyl sulfones under photoinduced conditions with the insertion of sulfur dioxide

2020 ◽  
Vol 22 (6) ◽  
pp. 1906-1910 ◽  
Author(s):  
Xinxing Gong ◽  
Min Yang ◽  
Jin-Biao Liu ◽  
Fu-Sheng He ◽  
Xiaona Fan ◽  
...  
Keyword(s):  
Sulfur Dioxide ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Room Temperature ◽  
Light Irradiation ◽  
Metal Free

A metal-free route to alkynyl sulfones under photoinduced conditions is accomplished, starting from 4-alkyl Hantzsch esters, sulfur dioxide, and alkynyl bromides under visible light irradiation at room temperature.

A photoinduced reaction of perfluoroalkyl halides with 1,3-diarylprop-2-yn-1-ones catalyzed by DABSO

2017 ◽  
Vol 4 (9) ◽  
pp. 1745-1750 ◽  
Author(s):  
Yuewen Li ◽  
Yiye Lu ◽  
Runyu Mao ◽  
Zhiming Li ◽  
Jie Wu
Keyword(s):  
Sulfur Dioxide ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Halogen Bond ◽  
Theoretical Calculations ◽  
Light Irradiation ◽  
Efficient Catalyst ◽  
Photoinduced Reaction ◽  
Plausible Mechanism ◽  
Perfluoroalkyl Halides

The sulfur dioxide surrogate of DABCO·(SO2)2 is used as an efficient catalyst for the cleavage of the perfluoroalkyl-halogen bond under visible-light irradiation. A plausible mechanism supported by theoretical calculations is proposed.

Three-component reaction access to S-alkyl dithiocarbamates under visible-light irradiation conditions in water

2022 ◽  
Author(s):  
Xuehao Li ◽  
Wenwen Cui ◽  
Qirong Deng ◽  
Xiuyan Song ◽  
Jian Lv ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Functional Group ◽  
Environmentally Friendly ◽  
Light Irradiation ◽  
Three Component Reaction

An efficient and environmentally friendly visible-light promoted method for the synthesis of S-alkyl dithiocarbamates with broad substrate scope and good functional group tolerance in water has been developed. Most appealingly,...

Synthesis of β-Sulfonyl Amides through a Multicomponent Reaction with the Insertion of Sulfur Dioxide under Visible Light Irradiation

2019 ◽  
Vol 21 (6) ◽  
pp. 1935-1938 ◽  
Author(s):  
Yu Zong ◽  
Yimin Lang ◽  
Min Yang ◽  
Xiaofang Li ◽  
Xiaona Fan ◽  
...  
Keyword(s):  
Sulfur Dioxide ◽  
Visible Light ◽  
Multicomponent Reaction ◽  
Visible Light Irradiation ◽  
Light Irradiation

Photoredox-catalyzed sulfonylation of alkenylcyclobutanols with the insertion of sulfur dioxide through semipinacol rearrangement

2019 ◽  
Vol 6 (11) ◽  
pp. 1873-1878 ◽  
Author(s):  
Fu-Sheng He ◽  
Youqian Wu ◽  
Xiaofang Li ◽  
Hongguang Xia ◽  
Jie Wu
Keyword(s):  
Sulfur Dioxide ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Semipinacol Rearrangement

A photoredox-catalyzed sulfonylation of alkenylcyclobutanols with the insertion of sulfur dioxide through semipinacol rearrangement under visible light irradiation is developed.

Photoredox-catalyzed hydrosulfonylation reaction of electron-deficient alkenes with substituted Hantzsch esters and sulfur dioxide

2019 ◽  
Vol 55 (43) ◽  
pp. 6010-6013 ◽  
Author(s):  
Xuefeng Wang ◽  
Min Yang ◽  
Wenlin Xie ◽  
Xiaona Fan ◽  
Jie Wu
Keyword(s):  
Sulfur Dioxide ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Room Temperature ◽  
Light Irradiation ◽  
Photoredox Catalysis

A sulfonylation reaction of 4-substituted Hantzsch esters, DABCO·(SO2)2, and electron-deficient alkenes at room temperature in the presence of photoredox catalysis under visible light irradiation is described.

Photoinduced synthesis of alkylalkynyl sulfones through a reaction of potassium alkyltrifluoroborates, sulfur dioxide, and alkynyl bromides

2020 ◽  
Vol 7 (7) ◽  
pp. 938-943 ◽  
Author(s):  
Xinxing Gong ◽  
Min Yang ◽  
Jin-Biao Liu ◽  
Fu-Sheng He ◽  
Jie Wu
Keyword(s):  
Sulfur Dioxide ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Room Temperature ◽  
Light Irradiation ◽  
Sodium Metabisulfite ◽  
Photoinduced Reaction ◽  
Photoinduced Synthesis

A photoinduced reaction of potassium alkyltrifluoroborates, sodium metabisulfite, and alkynyl bromides under visible light irradiation at room temperature is developed.

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