Self-adaptive water vapor permeability and its hydrogen bonding switches of bio-inspired polymer thin films

2017 ◽  
Vol 1 (10) ◽  
pp. 2027-2030 ◽  
Author(s):  
Jinlian Hu ◽  
You Wu ◽  
Cuili Zhang ◽  
Ben Zhong Tang ◽  
Shaojun Chen
Keyword(s):  
Thin Films ◽  
Hydrogen Bonding ◽  
Water Vapor ◽  
Water Molecule ◽  
Guard Cell ◽  
Polymer Thin Films ◽  
Water Vapor Permeability ◽  
Bonding Energy ◽  
Vapor Permeability ◽  
Moisture Sensitive

A polymer inspired by a leaf guard-cell and designed by introducing supramolecular hydrogen-bonding switches and moisture-sensitive SAWVP has been achieved, suggesting that hydrogen bonding can become a moisture-responsive switch when its bonding energy is smaller than the energy between the water molecule and the switch itself.

Properties of SiOx/PET Thin Films Prepared by RF Magnetron Sputtering

2011 ◽  
Vol 380 ◽  
pp. 238-243 ◽  
Author(s):  
Hui Zhi ◽  
Jing Lin ◽  
Bo Zhang
Keyword(s):  
Thin Films ◽  
Mechanical Properties ◽  
Water Vapor ◽  
Magnetron Sputtering ◽  
Process Parameters ◽  
Surface Composition ◽  
Water Vapor Permeability ◽  
Rf Magnetron Sputtering ◽  
Vapor Permeability ◽  
The Relationship

The SiOx thin films for food packaging were deposited by RF magnetron sputtering physical vapor technology on the substrates of 20μm polyethylene terephthalate (PET) by using a pure SiO2 target. The molecular structure of thin film surface composition were detected and analyzed by Fourier transform infrared spectroscopy (FTIR); and the barrier properties of the films were examined by MOCON water vapor permeability testing instrument, also，the relationship maps between permeability and process parameters were drew and the process parameters were optimized; The mechanical properties of thin films were tested by electronic tensile testing machine, and the curves of the relationship between the mechanical properties and process parameters depicted. The SiOx/PET thin films of the lowest water vapor permeability were prepared under the pressure of 7.5×10-3 Pa, the sputtering pressure of 0.23 Pa, the deposition time of 30min and the sputtering power of 1500W. The yield strength increased 4 times and elastic modulus increased 3 times when the water vapor permeability of the SiOx/PET thin films rose about 10 times of the blank.

Ultraviolet blocking and antioxidant polyvinyl alcohol films incorporated with baicalin extraction from Scutellaria baicalensis Georgi

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Jinshu Liu ◽  
Xiaoyan Ma ◽  
Wenzhao Shi ◽  
Jianwei Xing ◽  
Chaoqun Ma ◽  
...  
Keyword(s):  
Water Vapor ◽  
Polyvinyl Alcohol ◽  
Radical Scavenging Activity ◽  
Antioxidant Properties ◽  
Radical Scavenging ◽  
Water Vapor Permeability ◽  
Scutellaria Baicalensis ◽  
Vapor Permeability ◽  
Protective Film ◽  
Uv Blocking

Abstract Baicalin, an active flavonoid ingredient of Scutellaria baicalensis Georgi, was extracted by heat reflux extraction and showed the same significance UV absorption property with standard baicalin. Active films were prepared from polyvinyl alcohol (PVA) containing baicalin extract by casting method. The effect of baicalin extracts on the UV-blocking, optical, antioxidant property, water vapor permeability, swelling and mechanical properties of the films were studied. UV–vis transmittance spectra showed that PVA films incorporated with baicalin extract blocked ultraviolet light range from 280–400 nm even with low concentration of baicalin (0.5 wt%) and maintain the high transparency in visible spectrum. The outstanding UV-blocking properties of PVA films incorporated with baicalin extract were also confirmed by Rhodamine B degradation. Baicalin conferred antioxidant properties to PVA films as determined by DPPH radical scavenging activity. Due to the interaction between hydroxy groups of baicalin and PVA molecule, water vapor permeability, swelling and elongation at break of the films were decreased accompanied with the increasing in tensile strength and Young’s modulus. FTIR reveal that the interaction between PVA molecules was significant changed by the introduction of baicalin. These results suggest that PVA film incorporated with baicalin extract can be used for the development of functional protective film.

scholarly journals The Effect of Extraction Conditions on the Barrier and Mechanical Properties of Kefiran Films

Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 602
Author(s):  
Carmen Rodica Pop ◽  
Teodora Emilia Coldea ◽  
Liana Claudia Salanţă ◽  
Alina Lăcrămioara Nistor ◽  
Andrei Borşa ◽  
...  
Keyword(s):  
Water Vapor ◽  
Conformational Changes ◽  
Water Vapor Permeability ◽  
Edible Films ◽  
Film Structure ◽  
Water Soluble ◽  
Vapor Permeability ◽  
Water Molecules ◽  
Compact Structure ◽  
Technology Applications

Kefiran is an exopolysaccharide classified as a heteropolysaccharide comprising glucose and galactose in equimolar quantities, and it is classified as a water-soluble glucogalactan. This work aimed to investigate the effect of different extraction conditions of kefiran on the structural and physical properties of the edible films obtained. Fourier-transform infrared spectroscopy and scanning electron microscopy were performed, together with a determinations of moisture content, solubility, water vapor permeability and degree of swelling. The kefiran films presented values of the water vapor permeability between 0.93 and 4.38 × 10−11 g/m.s.Pa. These results can be attributed to the development of a more compact structure, where glycerol had no power to increase the free volume and the water vapor diffusion through their structure. The possible conformational changes in the kefiran film structure, due to the interspersing of the plasticizers and water molecules that they absorb, could be the reason for producing flexible kefiran films in the case of using glycerol as a plasticizer at 7.5% w/w. Moreover, it was observed that the extraction conditions are a significant factor in the properties of these films and their food technology applications.

scholarly journals Development of PE/PCL Bilayer Films Modified with Casein and Aluminum Oxide

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3090
Author(s):  
Anita Ptiček Siročić ◽  
Ana Rešček ◽  
Zvonimir Katančić ◽  
Zlata Hrnjak-Murgić
Keyword(s):  
Mechanical Properties ◽  
Thermal Properties ◽  
Water Vapor ◽  
Aluminum Oxide ◽  
Water Vapor Permeability ◽  
Vapor Permeability ◽  
Mechanical And Thermal Properties ◽  
Oxide Compound ◽  
Bilayer Films ◽  
Oxide Particles

The studied samples were prepared from polyethylene (PE) polymer which was coated with modified polycaprolactone (PCL) film in order to obtain bilayer films. Thin PCL film was modified with casein/aluminum oxide compound to enhance vapor permeability as well as mechanical and thermal properties of PE/PCL films. Casein/aluminum oxide modifiers were used in order to achieve some functional properties of polymer film that can be used in various applications, e.g., reduction of water vapor permeability (WVTR) and good mechanical and thermal properties. Significant improvement was observed in mechanical properties, especially in tensile strength as well as in water vapor values. Samples prepared with aluminum oxide particles indicated significantly lower values up to 60%, and samples that were prepared with casein and 5% Al2O3 showed the lowest WVTR value.

scholarly journals Upcycling of Vine Shoots: Production of Fillers for PHBV-Based Biocomposite Applications

2020 ◽  
Author(s):  
Grégoire David ◽  
Laurent Heux ◽  
Stéphanie Pradeau ◽  
Nathalie Gontard ◽  
Hélène Angellier-Coussy
Keyword(s):  
Water Vapor ◽  
Gas Phase ◽  
Mechanical Performance ◽  
Low Cost ◽  
Water Vapor Permeability ◽  
Contact Angles ◽  
Vapor Permeability ◽  
Water Contact ◽  
Median Diameter ◽  
Cost Of Materials

Abstract This paper aims at investigating the potential of vine shoots (ViSh) upcycling as fillers in novel poly(3-hydroxybutyrate-3-hydroxyvalerate) (PHBV) based biocomposites. ViSh particles of around 50 µm (apparent median diameter) were obtained combining dry grinding processes, and mixed with PHBV using melt extrusion. Thermal stability and elongation at break of biocomposites were reduced with increasing contents of ViSh particles (10, 20 and 30 wt%), while Young’s modulus and water vapor permeability were increased. It was shown that a surface gas-phase esterification allowed to significantly increase the hydrophobicity of ViSh particles (increase of water contact angles from 59° to 114°), leading to a reduction of 27% in the water vapor permeability of the biocomposite filled with 30 wt% of ViSh. The overall mechanical performance was not impacted by gas-phase esterification, demonstrating that the interfacial adhesion between the virgin ViSh particles and the PHBV matrix was already good and that such filler surface treatment was not required in that case. It was concluded that ViSh particles can be interestingly used as low cost fillers in PHBV-based biocomposites to decrease the overall cost of materials.

Water-vapor permeability control of PDMS by the dispersion of collagen powder

2009 ◽  
Vol 4 (3) ◽  
pp. 442-449 ◽  
Author(s):  
Yuhua Zhang ◽  
Masatoshi Ishida ◽  
Yutaka Kazoe ◽  
Yohei Sato ◽  
Norihisa Miki
Keyword(s):  
Water Vapor ◽  
Water Vapor Permeability ◽  
Vapor Permeability ◽  
Collagen Powder

scholarly journals Incorporation of bentonite clay in cassava starch films for the reduction of water vapor permeability

2018 ◽  
Vol 105 ◽  
pp. 637-644 ◽  
Author(s):  
M.K.S. Monteiro ◽  
V.R.L. Oliveira ◽  
F.K.G. Santos ◽  
E.L. Barros Neto ◽  
R.H.L. Leite ◽  
...  
Keyword(s):  
Water Vapor ◽  
Water Vapor Permeability ◽  
Bentonite Clay ◽  
Cassava Starch ◽  
Vapor Permeability ◽  
Starch Films
Sign in / Sign up

Export Citation Format

Share Document