High-performance water oxidation electrocatalysis enabled by a Ni-MOF nanosheet array

2018 ◽  
Vol 5 (7) ◽  
pp. 1570-1574 ◽  
Author(s):  
Qin Liu ◽  
Lisi Xie ◽  
Xifeng Shi ◽  
Gu Du ◽  
Abdullah M. Asiri ◽  
...  

An Ni-MOF nanosheet array on Ni foam (Ni-MOF/NF) acts as a high-performance and durable electrocatalyst for the oxygen evolution reaction in 1.0 M KOH, needing an overpotential of 320 mV to drive 100 mA cm−2.

2017 ◽  
Vol 53 (92) ◽  
pp. 12446-12449 ◽  
Author(s):  
Qin Liu ◽  
Lisi Xie ◽  
Zhiang Liu ◽  
Gu Du ◽  
Abdullah M. Asiri ◽  
...  

A Zn-doped Ni3S2nanosheet array on Ni foam (Zn-Ni3S2/NF) acts as a high-performance and durable electrocatalyst for the oxygen evolution reaction in 1.0 M KOH, driving a catalytic current density of 100 mA cm−2at an overpotential of 330 mV, 90 mV less than that for Ni3S2/NF.


2018 ◽  
Vol 5 (2) ◽  
pp. 344-347 ◽  
Author(s):  
Xiaoping Zhang ◽  
Weidi Sun ◽  
Huitong Du ◽  
Rong-Mei Kong ◽  
Fengli Qu

A Co-MOF nanosheet array on Ni foam (Co-MOF/NF) acts as a superior electrocatalyst for the oxygen evolution reaction, needing an overpotential of only 311 mV to drive a geometrical catalytic current density of 50 mA cm−2 in 1.0 M KOH.


Author(s):  
Shuya Zhao ◽  
Yurui Xue ◽  
Zhongqiang Wang ◽  
Zhiqiang Zheng ◽  
Xiaoyu Luan ◽  
...  

Developing highly active, stable and low-cost electrocatalysts capable of an efficient oxygen evolution reaction (OER) is urgent and challenging.


Nanoscale ◽  
2020 ◽  
Author(s):  
Ning Xie ◽  
Dong-Dong Ma ◽  
Xintao Wu ◽  
Qi-Long Zhu

Constructing high-performance and cost-effective electrocatalysts for water oxidation, particularly for overall water splitting is extremely needed, whereas still challenging. Herein, based on an economical and facile one-step surface sulfurization strategy,...


Catalysts ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 459 ◽  
Author(s):  
Heng Luo ◽  
Hang Lei ◽  
Yufei Yuan ◽  
Yongyin Liang ◽  
Yi Qiu ◽  
...  

The rational design and development of the low-cost and effective electrocatalysts toward oxygen evolution reaction (OER) are essential in the storage and conversion of clean and renewable energy sources. Herein, a ternary copper-cobalt sulfide nanosheets electrocatalysts (denoted as CuCoS/CC) for electrochemical water oxidation has been synthesized on carbon cloth (CC) via the sulfuration of CuCo-based precursors. The obtained CuCoS/CC reveals excellent electrocatalytic performance toward OER in 1.0 M KOH. It exhibits a particularly low overpotential of 276 mV at current density of 10 mA cm−2, and a small Tafel slope (58 mV decade−1), which is superior to the current commercialized noble-metal electrocatalysts, such as IrO2. Benefiting from the synergistic effect of Cu and Co atoms and sulfidation, electrons transport and ions diffusion are significantly enhanced with the increase of active sites, thus the kinetic process of OER reaction is boosted. Our studies will serve as guidelines in the innovative design of non-noble metal electrocatalysts and their application in electrochemical water splitting


2019 ◽  
Vol 7 (31) ◽  
pp. 18380-18387
Author(s):  
Byunghoon Kim ◽  
Ju Seong Kim ◽  
Hyunah Kim ◽  
Inchul Park ◽  
Won Mo Seong ◽  
...  

For the high-performance oxygen evolution reaction catalysts, we introduce amorphous cobalt–iron phyllosilicates (ACFPs), which explore the chemical space of phyllosilicate materials.


2020 ◽  
Vol 44 (4) ◽  
pp. 1455-1462 ◽  
Author(s):  
Jingyi Wang ◽  
Zhi Yang ◽  
Meilin Zhang ◽  
Yaqiong Gong

The as-obtained CoFe2O4@Ni3S2/NF can serve as an active and stable water oxidation catalyst under electrochemical reaction conditions.


2017 ◽  
Vol 5 (41) ◽  
pp. 21740-21749 ◽  
Author(s):  
Xiumin Li ◽  
Chuncheng Li ◽  
Akihiro Yoshida ◽  
Xiaogang Hao ◽  
Zhijun Zuo ◽  
...  

A “top-down” tactic was offered to synthesize highly efficient electrocatalysts for the oxygen evolution reaction (OER), in which a CuO microcube supported Fe doped Co3O4 nanosheet composite was obtained using a UPED method combined with a thermal treatment.


2017 ◽  
Vol 5 (16) ◽  
pp. 7291-7294 ◽  
Author(s):  
Xiang Ren ◽  
Ruixiang Ge ◽  
Yong Zhang ◽  
Danni Liu ◽  
Dan Wu ◽  
...  

As a durable catalyst, cobalt–borate nanowire array on Ti mesh exhibits high activity for water oxidation in near-neutral media, thereby achieving a geometrical catalytic current density of 10 mA cm−2 at an overpotential of 420 mV.


2018 ◽  
Vol 2 (1) ◽  
pp. 743-753 ◽  
Author(s):  
Xui-Fang Chuah ◽  
Cheng-Ting Hsieh ◽  
Chun-Lung Huang ◽  
Duraisamy Senthil Raja ◽  
Hao-Wei Lin ◽  
...  

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