Synthesis of late transition-metal nanoparticles by Na naphthalenide reduction of salts and their catalytic efficiency

2017 ◽  
Vol 4 (12) ◽  
pp. 2037-2044 ◽  
Author(s):  
Fangyu Fu ◽  
Angel M. Martinez-Villacorta ◽  
Ane Escobar ◽  
Joseba Irigoyen ◽  
Sergio Moya ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Nanoparticles ◽  
Catalytic Efficiency ◽  
Late Transition Metal ◽  
Coupling Reactions ◽  
Salting Out ◽  
Transition Metal Nanoparticles ◽  
Late Transition

Late transition-metal nanoparticles were synthesized using Na naphthalenide reduction of salts followed by salting-out purification catalyse click, redox and coupling reactions.

Transition-metal Nanoparticles Catalyzed Carbon-Carbon Coupling Reactions in Water

2019 ◽  
Vol 23 (6) ◽  
pp. 689-703 ◽  
Author(s):  
Atsushi Ohtaka
Keyword(s):  
Catalytic Activity ◽  
Transition Metal ◽  
Metal Nanoparticles ◽  
Catalytic System ◽  
High Catalytic Activity ◽  
Coupling Reactions ◽  
Transition Metal Nanoparticles ◽  
The Past ◽  
Ullmann Coupling

The use of transition-metal nanoparticles in catalysis has attracted much interest, and their use in carbon-carbon coupling reactions such as Suzuki, Heck, Sonogashira, Stille, Hiyama, and Ullmann coupling reactions constitutes one of their most important applications. The transition-metal nanoparticles are considered as one of the green catalysts because they show high catalytic activity for several reactions in water. This review is devoted to the catalytic system developed in the past 10 years in transition-metal nanoparticles-catalyzed carbon-carbon coupling reactions such as Suzuki, Heck, Sonogashira, Stille, Hiyama, and Ullmann coupling reactions in water.

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