Investigation on electrochemical behaviors of NiCo2O4 battery-type supercapacitor electrodes: the role of an aqueous electrolyte

2017 ◽  
Vol 4 (10) ◽  
pp. 1642-1648 ◽  
Author(s):  
Wei Jiang ◽  
Fang Hu ◽  
Qingyu Yan ◽  
Xiang Wu
Keyword(s):  
Electrochemical Performance ◽  
Electrode Materials ◽  
Aqueous Electrolyte ◽  
Electrochemical Behaviors

The electrochemical performance of the as-synthesized mesoporous NiCo2O4 flower-like products as electrode materials for battery-type supercapacitors is systematically investigated in detail.

Inorganic Electrolytes in Supercapacitor

2019 ◽  
Keyword(s):  
Energy Storage ◽  
Electrochemical Performance ◽  
Power Density ◽  
High Power ◽  
Electrode Materials ◽  
Storage Systems ◽  
Research Work ◽  
Wide Operating ◽  
Charge Discharge

Supercapacitors are considered promising energy storage systems due to their high power density, fast charge-discharge, long service lifetime, wide operating temperature range and excellent capacitance retention. The electrochemical performance of the supercapacitors depends upon numerous factors such as nature of electrode materials, type of electrolyte and separator thickness, etc. Among these factors, electrolyte used in supercapacitor plays an important role in deciding final characteristics of supercapacitors. In recent decades, tremendous research work has been on the development of novel electrolytes and electrode/electrolyte configurations. In this chapter, we aimed to focus on the role of inorganic electrolytes used in supercapacitors.

scholarly journals Peculiar role of the electrolyte viscosity in the electrochemical capacitor performance

2021 ◽  
Author(s):  
Przemyslaw Galek ◽  
Adam Slesinski ◽  
Krzysztof Fic ◽  
Jakub Menzel
Keyword(s):  
Electrochemical Performance ◽  
Carboxymethyl Cellulose ◽  
Aqueous Electrolyte ◽  
Electrochemical Capacitors ◽  
Electrochemical Capacitor ◽  
Capacitor Performance

This paper reports on the electrochemical performance of symmetric electrochemical capacitors operating in an aqueous electrolyte (1 mol L−1 Li2SO4 solution) whose viscosity is modified by various amounts of carboxymethyl cellulose additive.

Poly(aniline-co-pyrrole)-coated Ni-doped manganese dioxide as electrode materials for supercapacitors

2020 ◽  
Vol 13 (02) ◽  
pp. 2051007
Author(s):  
Jie Dong ◽  
Qinghao Yang ◽  
Qiuli Zhao ◽  
Zhenzhong Hou ◽  
Yue Zhou ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Manganese Dioxide ◽  
Specific Capacitance ◽  
Electrode Materials ◽  
High Specific Capacitance ◽  
Cycle Stability ◽  
Mass Ratio ◽  
Scan Rate ◽  
Poly Aniline ◽  
Inorganic And Organic

Electrode materials with a high specific capacitance, outstanding reversibility and excellent cycle stability are constantly pursued for supercapacitors. In this paper, we present an approach to improve the electrochemical performance by combining the advantages of both inorganic and organic. Ni-MnO2/PANi-co-PPy composites are synthesized, with the copolymer of aniline/pyrrole being coated on the surface of Ni-doped manganese dioxide nanospheres. The inorganic–organic composite enables a substantial increase in its specific capacitance and cycle stability. When the mass ratio of Ni-MnO2 to aniline and pyrrole mixed monomer is 1:5, the composite delivers high specific capacitance of 445.49[Formula: see text]F/g at a scan rate of 2[Formula: see text]mV/s and excellent cycle stability of 61.65% retention after 5000 cycles. The results indicate that the Ni-MnO2/PANi-co-PPy composites are promising electrode materials for future supercapacitors application.

Morphology formation mechanism and electrochemical performance of poly(o-phenylenediamine) based electrode materials

2021 ◽  
Vol 273 ◽  
pp. 116688
Author(s):  
Haidie Lan ◽  
Arzugul Muslim ◽  
Mehriban Hojiahmat ◽  
Lin Wang ◽  
Yu Meng ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Formation Mechanism ◽  
Electrode Materials

scholarly journals A Hierarchical Architecture of Functionalized Polyaniline/Manganese Dioxide Composite with Stable-Enhanced Electrochemical Performance

2021 ◽  
Vol 5 (5) ◽  
pp. 129
Author(s):  
Yapeng Wang ◽  
Yanxiang Wang ◽  
Chengjuan Wang ◽  
Yongbo Wang
Keyword(s):  
Electrochemical Performance ◽  
Manganese Dioxide ◽  
Specific Capacitance ◽  
Current Density ◽  
Electrode Materials ◽  
High Efficiency ◽  
Scanning Speed ◽  
Hierarchical Architecture ◽  
Electrochemical Window ◽  
A Current

As one of the most outstanding high-efficiency and environmentally friendly energy storage devices, the supercapacitor has received extensive attention across the world. As a member of transition metal oxides widely used in electrode materials, manganese dioxide (MnO2) has a huge development potential due to its excellent theoretical capacitance value and large electrochemical window. In this paper, MnO2 was prepared at different temperatures by a liquid phase precipitation method, and polyaniline/manganese dioxide (PANI/MnO2) composite materials were further prepared in a MnO2 suspension. MnO2 and PANI/MnO2 synthesized at a temperature of 40 °C exhibit the best electrochemical performance. The specific capacitance of the sample MnO2-40 is 254.9 F/g at a scanning speed of 5 mV/s and the specific capacitance is 241.6 F/g at a current density of 1 A/g. The specific capacitance value of the sample PANI/MnO2-40 is 323.7 F/g at a scanning speed of 5 mV/s, and the specific capacitance is 291.7 F/g at a current density of 1 A/g, and both of them are higher than the specific capacitance value of MnO2. This is because the δ-MnO2 synthesized at 40 °C has a layered structure, which has a large specific surface area and can accommodate enough electrolyte ions to participate the electrochemical reaction, thus providing sufficient specific capacitance.

Role of the Electrode Morphology, Thickness and Orientation in the Ferroelectric Performance of Epitaxial Pb(Zr,Ti)O3 Thin Films

2000 ◽  
Vol 655 ◽  
Author(s):  
Cesar Guerrero ◽  
Florencio Sánchez ◽  
José Roldán ◽  
Frank Güell ◽  
María V. García-Cuenca
Keyword(s):  
Electrode Materials ◽  
Stabilized Zirconia ◽  
Large Thickness ◽  
Low Dielectric ◽  
Thin Film Capacitors ◽  
Pzt Thin Film ◽  
Ferroelectric Layer ◽  
Ferroelectric Capacitors ◽  
Lattice Matched

AbstractA comparison of pulsed laser deposited PbZr0.53Ti0.47O3 (PZT) thin film capacitors with SrRuO3 (SRO) and LaNiO3 (LNO) electrodes on (001) yttria-stabilized zirconia (YSZ) and lattice matched (001) LaAlO3 substrates is presented. Both electrode materials allow for the formation of ferroelectric capacitors with large remnant polarization (20-30 μC/cm2) and negligible fatigue, although slight differences arise regarding the promotion of either the rhombohedral or tetragonal phases of PZT. Far more crucial seems to be the tendency of SrRuO3 to develop a rougher surface at either small (<30 nm) or large thickness (>100 nm), and on YSZ substrates. In those cases a highly defective and possibly low dielectric interface forms between the electrode and the ferroelectric layer, resulting in greatly degraded ferroelectric performance. LaNiO3 is free from these limitations except for the cracks forming at very large thickness (>300 nm), and therefore appears as a more versatile electrode material.

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