Phosphorus-based materials for high-performance rechargeable batteries

2017 ◽  
Vol 4 (9) ◽  
pp. 1424-1444 ◽  
Author(s):  
Xinyu Qin ◽  
Bingyi Yan ◽  
Jia Yu ◽  
Jie Jin ◽  
Yao Tao ◽  
...  

A review of P based materials used in LIB/NIB and their synthesis strategies, tailored materials properties and different electrochemical performances.

2018 ◽  
Vol 6 (27) ◽  
pp. 12816-12841 ◽  
Author(s):  
Huajun Tian ◽  
Tianyi Wang ◽  
Fan Zhang ◽  
Shuoqing Zhao ◽  
Steven Wan ◽  
...  

A review focusing on the tunable pore structure design, surface chemistry, composition, and electrochemical performances of PCSs in various types of rechargeable batteries in order to provide insight and inspiration for promoting the development of next-generation high-performance batteries.


Author(s):  
Yongseok Lee ◽  
Jung-Keun Yoo ◽  
Hyunyoung Park ◽  
Wonseok Ko ◽  
Jungmin Kang ◽  
...  

A nano-sized CuSO4/carbon (N-CSO/C) composite achieves outstanding electrochemical performances with a high average operating voltage of ∼2.8 V (vs. K+/K).


Author(s):  
Xiaohui Zhao ◽  
Chonglong Wang ◽  
Ziwei Li ◽  
Xuechun Hu ◽  
Amir A. Razzaq ◽  
...  

The lithium sulfur (Li-S) batteries have a high theoretical specific capacity (1675 mAh g-1) and energy density (2600 Wh kg-1), exerting a high perspective as the next-generation rechargeable batteries for...


Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2400
Author(s):  
Leandra P. Santos ◽  
Douglas S. da Silva ◽  
Thais H. Morari ◽  
Fernando Galembeck

Many materials and additives perform well as fire retardants and suppressants, but there is an ever-growing list of unfulfilled demands requiring new developments. This work explores the outstanding dispersant and adhesive performances of cellulose to create a new effective fire-retardant: exfoliated and reassembled graphite (ERG). This is a new 2D polyfunctional material formed by drying aqueous dispersions of graphite and cellulose on wood, canvas, and other lignocellulosic materials, thus producing adherent layers that reduce the damage caused by a flame to the substrates. Visual observation, thermal images and surface temperature measurements reveal fast heat transfer away from the flamed spots, suppressing flare formation. Pinewood coated with ERG underwent standard flame resistance tests in an accredited laboratory, reaching the highest possible class for combustible substrates. The fire-retardant performance of ERG derives from its thermal stability in air and from its ability to transfer heat to the environment, by conduction and radiation. This new material may thus lead a new class of flame-retardant coatings based on a hitherto unexplored mechanism for fire retardation and showing several technical advantages: the precursor dispersions are water-based, the raw materials used are commodities, and the production process can be performed on commonly used equipment with minimal waste.


Small Science ◽  
2021 ◽  
pp. 2100012
Author(s):  
Yu Li ◽  
Feng Wu ◽  
Ji Qian ◽  
Minghao Zhang ◽  
Yanxian Yuan ◽  
...  

Nanoscale ◽  
2018 ◽  
Vol 10 (33) ◽  
pp. 15588-15599 ◽  
Author(s):  
Zoya Sadighi ◽  
Jiapeng Liu ◽  
Francesco Ciucci ◽  
Jang-Kyo Kim

Ternary metal sulfides and ternary metal oxides have received much attention as potential electrodes for high performance rechargeable batteries.


RSC Advances ◽  
2015 ◽  
Vol 5 (117) ◽  
pp. 96660-96664 ◽  
Author(s):  
Sheng Han ◽  
Yani Ai ◽  
Yanping Tang ◽  
Jianzhong Jiang ◽  
Dongqing Wu

Carbonized polyaniline coupled molybdenum disulfide and graphene show excellent electrochemical performances as an anode material for lithium ion batteries.


Author(s):  
Wen-Wei Song ◽  
Bing Wang ◽  
Xiao-Man Cao ◽  
Qiang Chen ◽  
Zhengbo Han

Metal-organic frameworks (MOFs)-derived transition-metal oxides and transition-metal phosphides have great application potential as electrode materials for supercapacitors, owing to the excellent redox activity and high conductivity. However, their electrochemical performances...


2021 ◽  
Vol 18 ◽  
Author(s):  
Qurratul Ain Zakirah Mohd Zamram ◽  
Hannis Fadzillah Mohsin ◽  
Mashani Mohamad Mohamad ◽  
Nurul Aqmar Mohamad Nor Hazalin ◽  
Khuriah Abdul Hamid

Aim: Formulating topical products for skin delivery has always been a challenge for pharmaceutical scientists to fulfil good formulation criteria. Despite the challenges, gel-based drug delivery offers some advantages such that it is non-invasive, painless, avoidance of the first-pass metabolism and has satisfactory patient compliance. Objectives: In this study, Chromolaena odorata gel and quercetin gel (bioactive flavonoid compound) were successfully formulated and compared with placebo and conventional wound aid gel. The chromatographic profilling was conducted to screen the presence of phytoconstituents. Subsequently, all formulated gels were subjected to physical characteristic and stability study. Methods: Reverse Phase High-Performance Liquid Chromatography (RP-HPLC) of C.odorata methanolic leaves extract shows a distinct compound separation at retention time 8.4min to 34.8 min at 254nm. All gels were characterised by evaluating their rheological properties including storage modulus, loss modulus and plastic viscosity. Besides, texture analysis was performed to measure the gels’ firmness, consistency, cohesiveness, and viscosity index. Results: From the observation, C. odorata gel demonstrated better spreadability as compared to the other gels, which acquired less work and favourable to be applied onto the skin. Moreover, C. odorata gel showed no changes in organoleptic properties and proven to be stable after 30 days of accelerated stability study at 40°C ± 2°C with relative humidity (RH) of 75%± 5%. Conclusion: C. odorata gel has shown to be stable, reflecting the combination of materials used in the formulation, which did not degrade throughout the study. This work suggests the potential of this gel as a vehicle to deliver the active ingredients of C. odorata to the skin, which can be further explored as a topical application in antimicrobial wound management or other skin diseases study.


Micromachines ◽  
2018 ◽  
Vol 9 (8) ◽  
pp. 412 ◽  
Author(s):  
Evans Bernardin ◽  
Christopher Frewin ◽  
Richard Everly ◽  
Jawad Ul Hassan ◽  
Stephen Saddow

Intracortical neural interfaces (INI) have made impressive progress in recent years but still display questionable long-term reliability. Here, we report on the development and characterization of highly resilient monolithic silicon carbide (SiC) neural devices. SiC is a physically robust, biocompatible, and chemically inert semiconductor. The device support was micromachined from p-type SiC with conductors created from n-type SiC, simultaneously providing electrical isolation through the resulting p-n junction. Electrodes possessed geometric surface area (GSA) varying from 496 to 500 K μm2. Electrical characterization showed high-performance p-n diode behavior, with typical turn-on voltages of ~2.3 V and reverse bias leakage below 1 nArms. Current leakage between adjacent electrodes was ~7.5 nArms over a voltage range of −50 V to 50 V. The devices interacted electrochemically with a purely capacitive relationship at frequencies less than 10 kHz. Electrode impedance ranged from 675 ± 130 kΩ (GSA = 496 µm2) to 46.5 ± 4.80 kΩ (GSA = 500 K µm2). Since the all-SiC devices rely on the integration of only robust and highly compatible SiC material, they offer a promising solution to probe delamination and biological rejection associated with the use of multiple materials used in many current INI devices.


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