Synthesis, stereocomplex crystallization and homo-crystallization of enantiomeric poly(lactic acid-co-alanine)s with ester and amide linkages

2018 ◽  
Vol 9 (5) ◽  
pp. 565-575 ◽  
Author(s):  
Hideto Tsuji ◽  
Shotaro Sato ◽  
Noriaki Masaki ◽  
Yuki Arakawa ◽  
Akinori Kuzuya ◽  
...  

α-Hydroxy acid and α-amino acid-derived poly(l-lactic acid-co-l-alanine)s and poly(d-lactic acid-co-d-alanine)s with different alanine unit contents were synthesized and their stereocomplex crystallization and homo-crystallization were investigated.

1988 ◽  
Vol 20 (3) ◽  
pp. 281-284 ◽  
Author(s):  
Masaharu Asano ◽  
Masaru Yoshida ◽  
Isao Kaetsu ◽  
Ryoichi Katakai ◽  
Tooru Mashimo ◽  
...  

2011 ◽  
Vol 131 (5) ◽  
pp. 395-400 ◽  
Author(s):  
Toru Oi ◽  
Katsuyoshi Shinyama ◽  
Shigetaka Fujita

2014 ◽  
Vol 134 (4) ◽  
pp. 237-242
Author(s):  
Naru Matsugasaki ◽  
Katsuyoshi Shinyama ◽  
Shigetaka Fujita

2020 ◽  
Vol 62 (6) ◽  
pp. 732-743
Author(s):  
Chi-Hui Tsou ◽  
Jipeng Guo ◽  
Ji-Ang Lei ◽  
Manuel Reyes De Guzman ◽  
Maw-Cherng Suen
Keyword(s):  

2019 ◽  
Vol 821 ◽  
pp. 89-95
Author(s):  
Wanasorn Somphol ◽  
Thipjak Na Lampang ◽  
Paweena Prapainainar ◽  
Pongdhorn Sae-Oui ◽  
Surapich Loykulnant ◽  
...  

Poly (lactic acid) or PLA was reinforced by nanocellulose and polyethylene glycol (PEG), which were introduced into PLA matrix from 0 to 3 wt.% to enhance compatibility and strength of the PLA. The nanocellulose was prepared by TEMPO-mediated oxidation from microcrystalline cellulose (MCC) powder and characterized by TEM, AFM, and XRD to reveal rod-like shaped nanocellulose with nanosized dimensions, high aspect ratio and high crystallinity. Films of nanocellulose/PEG/PLA nanocomposites were prepared by solvent casting method to evaluate the mechanical performance. It was found that the addition of PEG in nanocellulose-containing PLA films resulted in an increase in tensile modulus with only 1 wt% of PEG, where higher PEG concentrations negatively impacted the tensile strength. Furthermore, the tensile strength and modulus of nanocellulose/PEG/PLA nanocomposites were higher than the PLA/PEG composites due to the existence of nanocellulose chains. Visual traces of crazing were detailed to describe the deformation mechanism.


2016 ◽  
Vol 107 ◽  
pp. 333-366 ◽  
Author(s):  
E. Castro-Aguirre ◽  
F. Iñiguez-Franco ◽  
H. Samsudin ◽  
X. Fang ◽  
R. Auras

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