Synthesis and self-assembly of a dual-responsive monocleavable ABCD star quaterpolymer

2017 ◽  
Vol 8 (44) ◽  
pp. 6865-6878 ◽  
Author(s):  
Huanhuan Liu ◽  
Jian Zhang ◽  
Wenxue Dai ◽  
Youliang Zhao

A modularly synthesized core-functionalized PEG-PSt-PCL-PAA miktoarm star can self-assemble into hollow nanocapsules that are sensitive to pH/redox stimuli and H-bond/polyion complexation.

2017 ◽  
Vol 6 (4) ◽  
pp. 426-430 ◽  
Author(s):  
Fugui Xu ◽  
Dongdong Wu ◽  
Yinjuan Huang ◽  
Hao Wei ◽  
Yong Gao ◽  
...  

2018 ◽  
Vol 9 (9) ◽  
pp. 1095-1108 ◽  
Author(s):  
Xiaoqi Zhao ◽  
Wentao Wu ◽  
Jian Zhang ◽  
Wenxue Dai ◽  
Youliang Zhao

The stimuli-tunable LCST-type phase transition and self-assembly behaviors of a multi-responsive 3-miktoarm star bearing O2/redox-sensitive and H-bond-switchable Y junctions were revealed.


2021 ◽  
pp. 2102027
Author(s):  
Da‐xia Zhang ◽  
Jiang Du ◽  
Rui Wang ◽  
Jian Luo ◽  
Tong‐fang Jing ◽  
...  

2021 ◽  
Author(s):  
Yanfen Jiang ◽  
Shuqi Dong ◽  
Guoyang Qin ◽  
Li Liu ◽  
Hanying Zhao

Alkylation of thioether-containing block copolymer simultaneously incorporated sulfoniums and phenylboronic acid moieties. The co-assembly of this cationic polymer and protein generated micelles with an H2O2-and ATP-responsive release profile.


2012 ◽  
Vol 25 (3) ◽  
pp. 422-426 ◽  
Author(s):  
Sanjib Das ◽  
Priyadarshi Ranjan ◽  
Pradipta Sankar Maiti ◽  
Gurvinder Singh ◽  
Gregory Leitus ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (34) ◽  
pp. 21328-21335 ◽  
Author(s):  
Rujiang Ma ◽  
Chuan Zhang ◽  
Yong Liu ◽  
Chang Li ◽  
Yanling Xu ◽  
...  

Iminoboronate-based dual-responsive micelles were fabricated via simple subcomponent self-assembly for delivery of hydrophilic 1,2-diol-containing drugs.


2013 ◽  
Vol 538 ◽  
pp. 181-184 ◽  
Author(s):  
Xin De Tang ◽  
Ye Chen ◽  
Fa Qi Yu ◽  
Mei Shan Pei

Organic/inorganic hybrid materials based upon stimuli-responsive copolymers have attracted an inceasing attention. Compared with the polymeric materials, these hybrid materials can form aggregates in aqueous solution with much more stable shape-persistance due to the inorganic structure, which facilitate the mass delivery and long-term life. A novel hybrid material based on a new reactive block copolymer, poly(ethylene oxide)-block-poly{3-(trimethoxysilyl)propyl methacrylate-co-N-isopropylacrylamide-co-6-[4-(4-methoxyphenylazo)phenoxy]hexyl methacrylate} [PEO-P(TMSPMA-NIPAM-AzoMA)] was synthesized via atom transfer radical polymerization (ATRP). The vesicles were obtained by self-assembly of the resulting block copolymer in a selective solvent, and then the PTMSPMA block was subjected to hydrolysis and polycondensation reaction to fix vesicle wall in the presence of triethylamine as a catalyst. The photo- and thermo- dual-responsive properties of the vesicles were investigated.


2021 ◽  
Author(s):  
Daniela M. Zanata ◽  
Maria Isabel Felisberti

Amphiphilic and stimuli-responsive triblock copolymers are an important class of smart materials due to their low critical micellar concentration in solution and capacity of self-assembly into different structures depending on...


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