Combinatorial synthesis of soluble conjugated polymeric nanoparticles and tunable multicolour fluorescence sensing

2017 ◽  
Vol 8 (37) ◽  
pp. 5734-5740 ◽  
Author(s):  
Peng Zhao ◽  
Yanan Dai ◽  
Yusen Wu ◽  
Lili Wang ◽  
Binlei Huang ◽  
...  
Keyword(s):  
Polymeric Nanoparticles ◽  
Combinatorial Synthesis ◽  
Fluorescence Sensing ◽  
Polymerization Method

Combinatorial polymerization method has been exploited to prepare a library of soluble conjugated polymeric nanoparticles (SCPNs), by varying symmetrical monomers, Ax and By (x > 2, y ≥ 2), plus modification with variant terminal groups.

scholarly journals Controlled synthesis of soluble conjugated polymeric nanoparticles for fluorescence detection

RSC Advances ◽  
2017 ◽  
Vol 7 (41) ◽  
pp. 25740-25745 ◽  
Author(s):  
Yanan Dai ◽  
Peng Zhao ◽  
Lili Wang ◽  
Yun Ding ◽  
Aiguo Hu
Keyword(s):  
Fluorescence Detection ◽  
Polymeric Nanoparticles ◽  
Controlled Synthesis ◽  
Fluorescence Sensing

Highly fluorescent soluble conjugated polymeric nanoparticles (SCPNs) were synthesized in confined nanoreactors and used for fluorescence sensing of glucose and Fe ion.

scholarly journals Self-Stabilized Precipitation Polymerization and Its Application

Research ◽  
2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Zhenjie Liu ◽  
Dong Chen ◽  
Jinfang Zhang ◽  
Haodong Liao ◽  
Yanzhao Chen ◽  
...  
Keyword(s):  
Polymeric Nanoparticles ◽  
Reaction Medium ◽  
Value Added ◽  
Nucleation And Growth ◽  
Huge Amount ◽  
Uniform Size ◽  
Synthetic Strategy ◽  
Heterogeneous Polymerization ◽  
Supernatant Liquid ◽  
Polymerization Method

An effective, value-added use of the large amounts of olefinic compounds produced in the processing of petroleum, aside from ethylene and propylene, has been a long outstanding challenge. Here, we developed a novel heterogeneous polymerization method, beyond emulsion/dispersion/suspension, termed self-stabilized precipitation (2SP) polymerization, which involves the nucleation and growth of nanoparticles (NPs) of a well-defined size without the use of any stabilizers and multifunctional monomers (crosslinker). This technique leads to two revolutionary advances: (1) the generation of functional copolymer particles from single olefinic monomer or complex olefinic mixtures (including C4/C5/C9 fractions) in large quantities, which open a new way to transform huge amount of unused olefinic compounds in C4/C5/C9 fractions into valuable copolymers, and (2) the resultant polymeric NPs possess a self-limiting size and narrow size distribution, therefore being one of the most simple, efficient, and green strategies to produce uniform, size-tunable, and functional polymeric nanoparticles. More importantly, the separation of the NPs from the reaction medium is simple and the supernatant liquid can be reused; hence this new synthetic strategy has great potential for industrial production.

Fluorescent electronic tongue based on soluble conjugated polymeric nanoparticles for the discrimination of heavy metal ions in aqueous solution

2019 ◽  
Vol 10 (18) ◽  
pp. 2256-2262 ◽  
Author(s):  
Chuying Feng ◽  
Peng Zhao ◽  
Lili Wang ◽  
Tao Yang ◽  
Yusen Wu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Heavy Metal ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Polymeric Nanoparticles ◽  
Electronic Tongue ◽  
Rapid Identification ◽  
Fluorescence Sensing

A fluorescence sensing array (or fluorescent electronic tongue) based on six sorts of soluble conjugated polymeric nanoparticles (SCPNs) decorated with PEG chains is designed for the rapid identification of heavy metal ions in water.

Effects of surfactant and polymerization method on the synthesis of magnetic colloidal polymeric nanoparticles

2016 ◽  
Vol 18 (7) ◽  
Author(s):  
Luis A. Puentes-Vara ◽  
Karla M. Gregorio-Jauregui ◽  
Ana M. Bolarín ◽  
Ma. E. Navarro-Clemente ◽  
Héctor J. Dorantes ◽  
...  
Keyword(s):  
Polymeric Nanoparticles ◽  
Polymerization Method

Miniaturised preparation of polymeric nanoparticles using droplet manipulation on open surfaces

2019 ◽  
Vol 14 (13) ◽  
pp. 1312-1316 ◽  
Author(s):  
Alsaeed M. Abualsayed ◽  
Sara A. Abouelmagd ◽  
Mohamed Abdelgawad
Keyword(s):  
Polymeric Nanoparticles ◽  
Droplet Manipulation

Optical and Electrical Properties of Organic Conducting Polymers

2014 ◽  
Vol 8 (1) ◽  
pp. 1457-1463
Author(s):  
Salah Abdulla Hasoon
Keyword(s):  
Electrical Properties ◽  
Conjugated Polymer ◽  
Polymeric Materials ◽  
Quantum Mechanical ◽  
Optical And Electrical Properties ◽  
Electrically Conducting ◽  
Temperature Ranges ◽  
Lithium Tetrafluoroborate ◽  
Absorbance Peak ◽  
Polymerization Method

Novel electrically conducting polymeric materials are prepared in this work. Polythiophene (PT) and poly (3-Methelthiophene) (P3MT) films were prepared by electro-polymerization method using cyclic voltammetry in acetonitrile as a solvent and lithium tetrafluoroborate as the electrolyte on a gold electrode. Electrical properties of P3MT have been examined in different environments using UV-Vis absorption spectroscopy and quantum mechanical ab initio calculations, The observed absorption peaks at 314 and 415 nm, were attributed to the n-π* and π-π* transitions, respectively in the conjugated polymer chain, in contrast, the observed absorbance peak at 649 nm, is responsible for electric conduction. The temperature dependence of the conductivity can be fitted to the Arrhenius and the VTF equations in different temperature ranges.

Novel Electro Polymerization Method to Synthesized Anti-corrosion Coated Layer on Stainless Steel Surface from (N-Benzothiazolyl Maleamic Acid) and Study its Biological Activity

2018 ◽  
Vol 9 (3) ◽  
Author(s):  
Muna I Khalaf ◽  
Khulood A Saleh ◽  
Khalil S Khalil
Keyword(s):  
Stainless Steel ◽  
Chemical Structure ◽  
Inhibition Efficiency ◽  
Steel Plate ◽  
Polymeric Coating ◽  
Stainless Steel Surface ◽  
Plate Electrode ◽  
Before And After ◽  
Maleamic Acid ◽  
Polymerization Method

Electro polymerization of N-benzothiazolyl maleamic acid (NBM) was carried out on stainless steel plate electrode in a protic medium of monomer aqueous solution using electrochemical oxidation procedure in electrochemical cell.Spectroscopic characterization techniques were investigated to obtain information about the chemical structure of polymer. The anti-corrosion action of polymer was investigated on stainless steel by electrochemical polarization method. In addition, the effect of adding nanomaterial (TiO2, ZnO (bulk-nano)) to monomer solution on the corrosion behavior of stainless steel was investigated. The results obtained showed that the corrosion rate of S-steel increased with temperature increase from 293K to 323K and the values of inhibition efficiency by coating polymer increase with nanomaterial addition. Apparent energies of activation have been calculated for the corrosion process of S-steel in acidic medium before and after polymeric coating. Furthermore were studied the effect of the preparing polymer on some strain of bacteria.

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