scholarly journals All acrylic-based thermoplastic elastomers with high upper service temperature and superior mechanical properties

2017 ◽  
Vol 8 (37) ◽  
pp. 5741-5748 ◽  
Author(s):  
Wei Lu ◽  
Yangyang Wang ◽  
Weiyu Wang ◽  
Shiwang Cheng ◽  
Jiahua Zhu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermoplastic Elastomers ◽  
Service Temperature ◽  
Superior Mechanical Properties

All acrylic-based thermoplastic elastomers (TPEs) offer potential alternatives to the widely-used styrenic TPEs.

Thermoreversible Crosslinking Rubber Using Supramolecular Hydrogen Bonding Networks

2002 ◽  
Vol 75 (4) ◽  
pp. 713-723 ◽  
Author(s):  
Keisuke Chino ◽  
Makoto Ashiura ◽  
Junichiro Natori ◽  
Masahiro Ikawa ◽  
Tetsuji Kawazura
Keyword(s):  
Mechanical Properties ◽  
Hydrogen Bonding ◽  
Solid Phase ◽  
Thermoplastic Elastomers ◽  
Scanning Calorimetry ◽  
Elongation At Break ◽  
Vulcanized Rubber ◽  
Superior Mechanical Properties ◽  
Hydrogen Bonding Networks ◽  
Isoprene Rubber

Abstract Thermoreversible crosslinking rubber (TRC-IR) was easily synthesized by modification of isoprene rubber (IR) with maleic anhydride followed by the addition of 3-amino-1,2,4-triazole (ATA), in solid phase. The mechanical properties of the resulting rubber were more similar to the sulfur-vulcanized rubber than general thermoplastic elastomers (ex. SEBS). Although the tensile strength and elongation at break were lower than those of a corresponding sulfur-vulcanized rubber, the moduli were as high as those of sulfur-cured rubber. Re-molding of TRC-IR could be repeated more than 10 times without significantly changing its mechanical properties. Differential scanning calorimetry (DSC) and infrared analyses revealed that the superior mechanical properties and good recyclability are attributable to the strong hydrogen bonding. The TRC-IR showed an endothermic transition peak at around 185 °C on the DSC chart, indicating cleavage of the hydrogen bonding. Infrared analyses also revealed that the absorption peaks of carboxylic acid were shifted to a lower region by the strong hydrogen bonding. The thermoreversible crosslinking system was also applied to EPM, EBM (ethylene-butene rubber), and IIR. These rubbers also showed superior mechanical properties as well as excellent recyclability.

Metallic Nanoneedles Arrays for TEM Sample Preparation “Lift-Out”

2012 ◽  
Author(s):  
Romaneh Jalilian ◽  
David Mudd ◽  
Neil Torrez ◽  
Jose Rivera ◽  
Mehdi M. Yazdanpanah ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Electron Microscope ◽  
Sample Preparation ◽  
Focused Ion Beam ◽  
Ion Beam ◽  
Beam System ◽  
Transmission Electron ◽  
Nanoneedle Array ◽  
Superior Mechanical Properties ◽  
And Performance

Abstract The sample preparation for transmission electron microscope can be done using a method known as "lift-out". This paper demonstrates a method of using a silver-gallium nanoneedle array for a quicker sharpening process of tungsten probes with better sample viewing, covering the fabrication steps and performance of needle-tipped probes for lift-out process. First, an array of high aspect ratio silver-gallium nanoneedles was fabricated and coated to improve their conductivity and strength. Then, the nanoneedles were welded to a regular tungsten probe in the focused ion beam system at the desired angle, and used as a sharp probe for lift-out. The paper demonstrates the superior mechanical properties of crystalline silver-gallium metallic nanoneedles. Finally, a weldless lift-out process is described whereby a nano-fork gripper was fabricated by attaching two nanoneedles to a tungsten probe.

scholarly journals Synthesis, Properties, and Biodegradability of Thermoplastic Elastomers Made from 2-Methyl-1,3-propanediol, Glutaric Acid and Lactide

Life ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 43
Author(s):  
Lamya Zahir ◽  
Takumitsu Kida ◽  
Ryo Tanaka ◽  
Yuushou Nakayama ◽  
Takeshi Shiono ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Glutaric Acid ◽  
Triblock Copolymers ◽  
Tensile Tests ◽  
Thermoplastic Elastomers ◽  
Proteinase K ◽  
Synthesis Properties

An innovative type of biodegradable thermoplastic elastomers with improved mechanical properties from very common and potentially renewable sources, poly(L-lactide)-b-poly(2-methyl-1,3-propylene glutarate)-b-poly(L-lactide) (PLA-b-PMPG-b-PLA)s, has been developed for the first time. PLA-b-PMPG-b-PLAs were synthesized by polycondensation of 2-methyl-1,3-propanediol and glutaric acid and successive ring-opening polymerization of L-lactide, where PMPG is an amorphous central block with low glass transition temperature and PLA is hard semicrystalline terminal blocks. The copolymers showed glass transition temperature at lower than −40 °C and melting temperature at 130–152 °C. The tensile tests of these copolymers were also performed to evaluate their mechanical properties. The degradation of the copolymers and PMPG by enzymes proteinase K and lipase PS were investigated. Microbial biodegradation in seawater was also performed at 27 °C. The triblock copolymers and PMPG homopolymer were found to show 9–15% biodegradation within 28 days, representing their relatively high biodegradability in seawater. The macromolecular structure of the triblock copolymers of PLA and PMPG can be controlled to tune their mechanical and biodegradation properties, demonstrating their potential use in various applications.

scholarly journals Effect of Acetylated SEBS/PP for Potential HVDC Cable Insulation

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1596
Author(s):  
Peng Zhang ◽  
Yongqi Zhang ◽  
Xuan Wang ◽  
Jiaming Yang ◽  
Wenbin Han
Keyword(s):  
Mechanical Properties ◽  
Field Strength ◽  
Thermoplastic Elastomer ◽  
High Energy ◽  
Thermoplastic Elastomers ◽  
Electrical Strength ◽  
Voltage Stabilizer ◽  
Breakdown Field ◽  
Cable Insulation ◽  
Breakdown Field Strength

Blending thermoplastic elastomers into polypropylene (PP) can make it have great potential for high-voltage direct current (HVDC) cable insulation by improving its toughness. However, when a large amount of thermoplastic elastomer is blended, the electrical strength of PP will be decreased consequently, which cannot meet the electrical requirements of HVDC cables. To solve this problem, in this paper, the inherent structure of thermoplastic elastomer SEBS was used to construct acetophenone structural units on its benzene ring through Friedel–Crafts acylation, making it a voltage stabilizer that can enhance the electrical strength of the polymer. The DC electrical insulation properties and mechanical properties of acetylated SEBS (Ac-SEBS)/PP were investigated in this paper. The results showed that by doping 30% Ac-SEBS into PP, the acetophenone structural unit on Ac-SEBS remarkably increased the DC breakdown field strength of SEBS/PP by absorbing high-energy electrons. When the degree of acetylation reached 4.6%, the DC breakdown field strength of Ac-SEBS/ PP increased by 22.4% and was a little higher than that of PP. Ac-SEBS, with high electron affinity, is also able to reduce carrier mobility through electron capture, resulting in lower conductivity currents in SEBS/PP and suppressing space charge accumulation to a certain extent, which enhances the insulation properties. Besides, the highly flexible Ac-SEBS can maintain the toughening effect of SEBS, resulting in a remarkable increase in the tensile strength and elongation at the break of PP. Therefore, Ac-SEBS/PP blends possess excellent insulation properties and mechanical properties simultaneously, which are promising as insulation materials for HVDC cables.

Dually cross-linked single network poly(acrylic acid) hydrogels with superior mechanical properties and water absorbency

Soft Matter ◽  
2016 ◽  
Vol 12 (24) ◽  
pp. 5420-5428 ◽  
Author(s):  
Ming Zhong ◽  
Yi-Tao Liu ◽  
Xiao-Ying Liu ◽  
Fu-Kuan Shi ◽  
Li-Qin Zhang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Acrylic Acid ◽  
Water Absorbency ◽  
Superior Mechanical Properties ◽  
Poly Acrylic Acid

Effect of Interfacial Properties on the Mechanical Behavior of Bone-Like Materials: A Numerical Study

2017 ◽  
Vol 09 (01) ◽  
pp. 1750014 ◽  
Author(s):  
Xingguo Li ◽  
Bingbing An ◽  
Dongsheng Zhang
Keyword(s):  
Mechanical Properties ◽  
Plastic Deformation ◽  
Numerical Study ◽  
Element Model ◽  
Interfacial Behavior ◽  
Yield Behavior ◽  
Bonding Property ◽  
The Matrix ◽  
Bonding Properties ◽  
Superior Mechanical Properties

Interfacial behavior in the microstructure and the plastic deformation in the protein matrix influence the overall mechanical properties of biological hard tissues. A cohesive finite element model has been developed to investigate the inelastic mechanical properties of bone-like biocomposites consisting of hard mineral crystals embedded in soft biopolymer matrix. In this study, the complex interaction between plastic dissipation in the matrix and bonding properties of the interface between minerals and matrix is revealed, and the effect of such interaction on the toughening of bone-like biocomposites is identified. For the case of strong and intermediate interfaces, the toughness of biocomposites is controlled by the post yield behavior of biopolymer; the matrix with low strain hardening can undergo significant plastic deformation, thereby promoting enhanced fracture toughness of biocomposites. For the case of weak interfaces, the toughness of biocomposites is governed by the bonding property of the interface, and the post-yield behavior of biopolymer shows negligible effect on the toughness. The findings of this study help to direct the path for designing bioinspired materials with superior mechanical properties.

Exploitation Load Impact on Electrochemical Properties of Shipbuilding 7xxx Series Aluminum Alloy Joints Prepared with TIG and FSW Methods

2015 ◽  
Vol 236 ◽  
pp. 53-61
Author(s):  
Wojciech Jurczak
Keyword(s):  
Mechanical Properties ◽  
Corrosion Potential ◽  
Tensile Load ◽  
Electrochemical Corrosion ◽  
High Strength ◽  
Shipbuilding Industry ◽  
Friction Stir ◽  
Superior Mechanical Properties ◽  
Series Aluminum Alloy ◽  
Joint Quality

The paper presents the results of investigations on mechanical properties and electrochemical potential distribution within arc welded (TIG) and friction stir welded (FSW) joints subjected to slow strain rate tests. The materials investigated were high-strength 7xxx series (7020 and its modification 7020M) aluminum alloys intended for shipbuilding. The objectives were joint quality assessment and comparison of the advantages of new FSW method with the traditional TIG methods commonly utilized in shipbuilding industry. Joint quality was evaluated based on mechanical investigations, hardness distribution tests and simultaneous electrochemical corrosion potential measurements at various locations within the welded joints.Initiation of corrosion processes on TIG and FSW joints was identified as a radical decrease in corrosion potential related to load followed by oxide layer cracking. Arc welded (TIG) joints of 7xxx series alloys undergo corrosion at lower values of tensile load applied as compared to the FSW joints. Superior mechanical properties and higher corrosion resistance of the FSW joints make this technology well-suited for joining high-strength 7xxx series alloys.

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