New copper(i) complex based initiating systems in redox polymerization and comparison with the amine/benzoyl peroxide reference

2017 ◽  
Vol 8 (28) ◽  
pp. 4088-4097 ◽  
Author(s):  
P. Garra ◽  
A. Kermagoret ◽  
A. Al Mousawi ◽  
F. Dumur ◽  
D. Gigmes ◽  
...  
Keyword(s):  
Free Radical ◽  
Benzoyl Peroxide ◽  
Radical Polymerization ◽  
Copper Complex ◽  
Free Radical Polymerization ◽  
Redox Polymerization ◽  
Mild Conditions

Novel copper complex based initiating systems for redox free radical polymerization (FRP) of methacrylate resins under mild conditions are proposed.

scholarly journals Ethylene free radical polymerization in supercritical ethylene/CO2 mixture

2020 ◽  
Vol 11 (5) ◽  
pp. 1001-1009
Author(s):  
Ali Al Rida Hmayed ◽  
Sébastien Norsic ◽  
Vincent Monteil ◽  
Jean Raynaud
Keyword(s):  
Free Radical ◽  
Benzoyl Peroxide ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Mild Conditions

Ethylene free radical polymerization in supercritical CO2/ethylene mixture under mild conditions (<100 °C and <300 bar) has been achieved to produce polyethylene, functionalized with benzoate moieties when benzoyl peroxide was used as initiator.

Mechanosynthesized copper(i) complex based initiating systems for redox polymerization: towards upgraded oxidizing and reducing agents

2017 ◽  
Vol 8 (38) ◽  
pp. 5884-5896 ◽  
Author(s):  
P. Garra ◽  
F. Dumur ◽  
A. Al Mousawi ◽  
B. Graff ◽  
D. Gigmes ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Reducing Agents ◽  
Redox Polymerization ◽  
Dibenzoyl Peroxide

Significant improvements of the recently proposed Cu(i)/VitC + water/dibenzoyl peroxide (BPO) system for the redox free radical polymerization of methacrylates in air are presented here.

scholarly journals Novel ketone derivative-based photoinitiating systems for free radical polymerization under mild conditions and 3D printing

2020 ◽  
Vol 11 (36) ◽  
pp. 5767-5777 ◽  
Author(s):  
Yangyang Xu ◽  
Guillaume Noirbent ◽  
Damien Brunel ◽  
Zhaofu Ding ◽  
Didier Gigmes ◽  
...  
Keyword(s):  
Free Radical ◽  
3D Printing ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Mild Conditions

Novel ketone derivatives as efficient photoinitiators for the free radical polymerization of acrylates and application in 3D printing.

Does bimolecular termination dominate in benzoyl peroxide initiated styrene free-radical polymerization?

Polymer ◽  
2020 ◽  
Vol 189 ◽  
pp. 122184
Author(s):  
Qimin Jiang ◽  
Deyong Xia ◽  
Chang Liu ◽  
Qilin Jiang ◽  
Jianhan Li ◽  
...  
Keyword(s):  
Free Radical ◽  
Benzoyl Peroxide ◽  
Radical Polymerization ◽  
Free Radical Polymerization
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