Self-assembly of PS-PNaSS-PS triblock copolymers from solution to the solid state

2017 ◽  
Vol 8 (21) ◽  
pp. 3357-3363 ◽  
Author(s):  
Sabrina Nehache ◽  
Mona Semsarilar ◽  
Martin In ◽  
Philippe Dieudonné-George ◽  
Joséphine Lai-Kee-Him ◽  
...  
Keyword(s):  
Solid State ◽  
Block Copolymer ◽  
Nanostructured Materials ◽  
Self Assembly ◽  
Triblock Copolymers ◽  
Morphological Development

Morphological development of block copolymer assemblies from solution to the solid state is explored to yield nanostructured materials.

Poly(methacrylic acid)-based AB and ABC block copolymer nano-objects prepared via RAFT alcoholic dispersion polymerization

2014 ◽  
Vol 5 (10) ◽  
pp. 3466-3475 ◽  
Author(s):  
M. Semsarilar ◽  
V. Ladmiral ◽  
A. Blanazs ◽  
S. P. Armes
Keyword(s):  
Block Copolymer ◽  
Methacrylic Acid ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Triblock Copolymers ◽  
Abc Triblock Copolymers

A series of well-defined amphiphilic methacrylic AB diblock and ABC triblock copolymers are synthesized via polymerization-induced self-assembly using an alcoholic dispersion polymerization formulation.

scholarly journals Single lithium-ion conducting poly(tetrafluorostyrene sulfonate) – polyether block copolymer electrolytes

2017 ◽  
Vol 8 (4) ◽  
pp. 785-794 ◽  
Author(s):  
Zhecheng Shao ◽  
Patric Jannasch
Keyword(s):  
Solid State ◽  
Block Copolymer ◽  
Triblock Copolymers ◽  
Lithium Ion ◽  
Block Copolymer Electrolytes ◽  
Ion Conducting ◽  
Very High

Well-designed BAB triblock copolymers with central polyether and flanking poly(lithium pentafluorostyrene sulfonate) blocks reach very high conductivities in the solid state.

Block Copolymer Self-Assembly in Mesostructured Silica Films Revealed by Real-Time FTIR and Solid-State NMR

Langmuir ◽  
2013 ◽  
Vol 29 (6) ◽  
pp. 1963-1969 ◽  
Author(s):  
Héloïse De Paz-Simon ◽  
Abraham Chemtob ◽  
Céline Croutxé-Barghorn ◽  
Séverinne Rigolet ◽  
Laure Michelin ◽  
...  
Keyword(s):  
Solid State ◽  
Block Copolymer ◽  
Real Time ◽  
Self Assembly ◽  
Solid State Nmr ◽  
Silica Films ◽  
Mesostructured Silica

scholarly journals Solid-State Nanostructured Materials from Self-Assembly of a Globular Protein–Polymer Diblock Copolymer

ACS Nano ◽  
2011 ◽  
Vol 5 (7) ◽  
pp. 5697-5707 ◽  
Author(s):  
Carla S. Thomas ◽  
Matthew J. Glassman ◽  
Bradley D. Olsen
Keyword(s):  
Solid State ◽  
Nanostructured Materials ◽  
Diblock Copolymer ◽  
Self Assembly ◽  
Globular Protein ◽  
Protein Polymer

Self-Assembly of Hydrogels From Elastin-Mimetic Block Copolymers

2002 ◽  
Vol 724 ◽  
Author(s):  
Elizabeth R. Wright ◽  
R. Andrew McMillan ◽  
Alan Cooper ◽  
Robert P. Apkarian ◽  
Vincent P. Conticello
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Triblock Copolymers ◽  
Variable Temperature ◽  
Inverse Temperature ◽  
Temperature Transition ◽  
Scanning Calorimetry ◽  
Design Synthesis ◽  
Inverse Temperature Transition ◽  
Functional Biomaterials

AbstractTriblock copolymers have traditionally been synthesized with conventional organic components. However, triblock copolymers could be synthesized by the incorporation of two incompatible protein-based polymers. The polypeptides would differ in their hydrophobicity and confer unique physiochemical properties to the resultant materials. One protein-based polymer, based on a sequence of native elastin, that has been utilized in the synthesis of biomaterials is poly (Valine-Proline-Glycine-ValineGlycine) or poly(VPGVG) [1]. This polypeptide has been shown to have an inverse temperature transition that can be adjusted by non-conservative amino acid substitutions in the fourth position [2]. By combining polypeptide blocks with different inverse temperature transition values due to hydrophobicity differences, we expect to produce amphiphilic polypeptides capable of self-assembly into hydrogels. Our research examines the design, synthesis and characterization of elastin-mimetic block copolymers as functional biomaterials. The methods that are used for the characterization include variable temperature 1D and 2D High-Resolution-NMR, cryo-High Resolutions Scanning Electron Microscopy and Differential Scanning Calorimetry.

The Self-Assembly of an Amphiphilic Block Copolymer: A Dissipative Particle Dynamics Study

2005 ◽  
Vol 42 (3) ◽  
pp. 180-183 ◽  
Author(s):  
S. G. Schulz ◽  
U. Frieske ◽  
H. Kuhn ◽  
G. Schmid ◽  
F. Müller ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Dissipative Particle Dynamics ◽  
Particle Dynamics ◽  
The Self ◽  
Amphiphilic Block Copolymer
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