Hydrophobic polypyrroles synthesized by aqueous chemical oxidative polymerization and their use as light-responsive liquid marble stabilizers

2017 ◽  
Vol 8 (17) ◽  
pp. 2609-2618 ◽  
Author(s):  
H. Kawashima ◽  
H. Mayama ◽  
Y. Nakamura ◽  
S. Fujii
Keyword(s):  
Oxidative Polymerization ◽  
Chemical Oxidative Polymerization ◽  
Liquid Marble

Hydrophobic polypyrroles doped with perfluoroalkyl dopants can function as a liquid marble stabilizer with photothermal properties.

Synthesis of poly(alkylaniline)s by aqueous chemical oxidative polymerization and their use as stimuli-responsive liquid marble stabilizer

Polymer ◽  
2021 ◽  
Vol 212 ◽  
pp. 123295
Author(s):  
Makoto Uda ◽  
Shinya Higashimoto ◽  
Tomoyasu Hirai ◽  
Yoshinobu Nakamura ◽  
Syuji Fujii
Keyword(s):  
Oxidative Polymerization ◽  
Stimuli Responsive ◽  
Chemical Oxidative Polymerization ◽  
Liquid Marble

scholarly journals Chemical Oxidative Polymerization of Methylene Blue: Reaction Mechanism and Aspects of Chain Structure

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2188
Author(s):  
Yaroslav O. Mezhuev ◽  
Igor Y. Vorobev ◽  
Ivan V. Plyushchii ◽  
Efrem G. Krivoborodov ◽  
Alexander A. Artyukhov ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Oxidative Polymerization ◽  
Chain Structure ◽  
Charge Transfer Complexes ◽  
Significant Weight Loss ◽  
Chemical Oxidative Polymerization ◽  
First Order ◽  
Initial Stage ◽  
Blue Reaction ◽  
Heating Up

The kinetic regularities of the initial stage of chemical oxidative polymerization of methylene blue under the action of ammonium peroxodisulfate in an aqueous medium have been established by the method of potentiometry. It was shown that the methylene blue polymerization mechanism includes the stages of chain initiation and growth. It was found that the rate of the initial stage of the reaction obeys the kinetic equation of the first order with the activation energy 49 kJ × mol−1. Based on the proposed mechanism of oxidative polymerization of methylene blue and the data of MALDI, EPR, and IR spectroscopy methods, the structure of the polymethylene blue chain is proposed. It has been shown that polymethylene blue has a metallic luster, and its electrical conductivity is probably the result of conjugation over extended chain sections and the formation of charge transfer complexes. It was found that polymethylene blue is resistant to heating up to a temperature of 440 K and then enters into exothermic transformations without significant weight loss. When the temperature rises above 480 K, polymethylene blue is subject to endothermic degradation and retains 75% of its mass up to 1000 K.

Zinc Oxide/Polyaniline Transparent Conductive Film Prepared by In Situ Polymerization Deposition

2014 ◽  
Vol 997 ◽  
pp. 368-370
Author(s):  
Ping Zhong ◽  
Lin Xiu Cheng ◽  
Xing Lu
Keyword(s):  
Zinc Oxide ◽  
Oxidative Polymerization ◽  
Optimal Conditions ◽  
Chemical Oxidative Polymerization ◽  
Reaction Conditions ◽  
Transparent Conductive Film ◽  
Conductive Film

In this paper，ZnO/PANI transparent conductive film has been prepared by in situ chemical oxidative polymerization, APS as an oxidant. The conductivity and transmittance of ZnO/PANI was measured. It has been investigated of the effects of reaction conditions and the doping component on conductivity, transmissivity and adhesion. With the increase of doping ZnO, the conductivity of ZnO/PANI transparent conductive film, transmittance and adhesion reduced. The optimal conditions is that the concentration of An, APS and PVA are 0.75 mol / L, 0.8 mol / L and 0.5wt%, respectively.

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