scholarly journals Spectral properties of ionic benzotristhiazole based donor–acceptor NLO-phores in polymer matrices and their one- and two-photon cellular imaging ability

2017 ◽  
Vol 16 (12) ◽  
pp. 1832-1844 ◽  
Author(s):  
M. Danko ◽  
P. Hrdlovič ◽  
A. Martinická ◽  
A. Benda ◽  
M. Cigáň

Spectral properties of ionic benzotristhiazolium (BTT) push–pull chromophores exhibited rigidochromic effect and their one- and two-photon mitochondria imaging ability were investigated.

2012 ◽  
Vol 22 (4) ◽  
pp. 1165-1176 ◽  
Author(s):  
Martin Danko ◽  
Filip Bureš ◽  
Jiří Kulhánek ◽  
Pavol Hrdlovič

2019 ◽  
Vol 21 (11) ◽  
pp. 3891-3894 ◽  
Author(s):  
Heejo Moon ◽  
Yuna Jung ◽  
Youngseo Kim ◽  
Byeong Wook Kim ◽  
Jin Gyu Choi ◽  
...  

2016 ◽  
Vol 8 (18) ◽  
pp. 11355-11365 ◽  
Author(s):  
Jinfeng Zhang ◽  
Wencheng Chen ◽  
Sergii Kalytchuk ◽  
King Fai Li ◽  
Rui Chen ◽  
...  

2019 ◽  
Author(s):  
Pralok K. Samanta ◽  
Md Mehboob Alam ◽  
Ramprasad Misra ◽  
Swapan K. Pati

Solvents play an important role in shaping the intramolecular charge transfer (ICT) properties of π-conjugated molecules, which in turn can affect their one-photon absorption (OPA) and two-photon absorption (TPA) as well as the static (hyper)polarizabilities. Here, we study the effect of solvent and donor-acceptor arrangement on linear and nonlinear optical (NLO) response properties of two novel ICT-based fluorescent sensors, one consisting of hemicyanine and dimethylaniline as electron withdrawing and donating groups (molecule 1), respectively and its boron-dipyrromethene (BODIPY, molecule 2)-fused counterpart (molecule 3). Density functional theoretical (DFT) calculations using long-range corrected CAM-B3LYP and M06-2X functionals, suitable for studying properties of ICT molecules, are employed to calculate the desired properties. The dipole moment (µ) as well as the total first hyperpolarizability (β<sub>total</sub>) of the studied molecules in the gas phase is dominantly dictated by the component in the direction of charge transfer. The ratios of vector component of first hyperpolarizability (β<sub>vec</sub>) to β<sub>total</sub> also reveal unidirectional charge transfer process. The properties of the medium significantly affect the OPA, hyperpolarizability and TPA properties of the studied molecules. Time dependent DFT (TDDFT) calculations suggest interchanging between two lowest excited states of molecule 3 from the gas phase to salvation. The direction of charge polarization and dominant transitions among molecular orbitals involved in the OPA and TPA processes are studied. The results presented are expected to be useful in tuning the NLO response of many ICT-based chromophores, especially those with BODIPY acceptors.<br>


2019 ◽  
Vol 4 (2) ◽  
pp. 449-449
Author(s):  
Brigitte Holzer ◽  
Markus Lunzer ◽  
Arnulf Rosspeintner ◽  
Giuseppe Licari ◽  
Maximilian Tromayer ◽  
...  

Correction for ‘Towards efficient initiators for two-photon induced polymerization: fine tuning of the donor/acceptor properties’ by Brigitte Holzer et al., Mol. Syst. Des. Eng., 2019, DOI: 10.1039/c8me00101d.


2019 ◽  
Vol 89 (12) ◽  
pp. 2577-2583
Author(s):  
W. Zhang ◽  
S. S. Zhou ◽  
G. F. Si ◽  
J. F. Wang ◽  
G. Y. Xu

2020 ◽  
Vol 124 (45) ◽  
pp. 24631-24643
Author(s):  
Yogajivan Rout ◽  
Alessio Cesaretti ◽  
Elena Ferraguzzi ◽  
Benedetta Carlotti ◽  
Rajneesh Misra

Nanoscale ◽  
2018 ◽  
Vol 10 (1) ◽  
pp. 109-117 ◽  
Author(s):  
Ping-Ching Wu ◽  
Jiu-Yao Wang ◽  
Wen-Lung Wang ◽  
Chia-Yuan Chang ◽  
Chia-Hung Huang ◽  
...  

N-doped GQDs conjugated with polymers demonstrate impressive two-photon properties and stability, and can be used as a contrast agent in deep tissue bioimaging.


2015 ◽  
Vol 3 (4) ◽  
pp. 742-749 ◽  
Author(s):  
Anna Purc ◽  
Krzysztof Sobczyk ◽  
Yusuke Sakagami ◽  
Akihiro Ando ◽  
Kenji Kamada ◽  
...  

Decorating diketopyrrolopyrroles with strongly electron-rich heterocycles led to donor–acceptor–donor architectures possessing two-photon brightness 850–1900 GM.


2012 ◽  
Vol 48 (54) ◽  
pp. 6833 ◽  
Author(s):  
Dokyoung Kim ◽  
Sunderraman Sambasivan ◽  
Hyoseok Nam ◽  
Ki Hean Kim ◽  
Jin Yong Kim ◽  
...  

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