Photocatalytic N-formylation of amines via a reductive quenching cycle in the presence of air

2017 ◽  
Vol 15 (12) ◽  
pp. 2536-2540 ◽  
Author(s):  
Tamal Ghosh ◽  
Amrita Das ◽  
Burkhard König
Keyword(s):  
Superoxide Radical ◽  
Reaction Pathway ◽  
Radical Cations ◽  
Radical Anions ◽  
Mechanistic Investigations ◽  
Superoxide Radical Anions

Photochemical N-formylation of amines was achieved without any additional formylating agents in the presence of air. Mechanistic investigations suggest a reaction pathway proceeding via the addition of in situ formed radical cations of enamines with photochemically generated superoxide radical anions.

Gas-phase reactions of oxide and superoxide radical anions with C6F6

1998 ◽  
Vol 109 (21) ◽  
pp. 9632-9633 ◽  
Author(s):  
W. B. Knighton ◽  
T. M. Miller ◽  
A. A. Viggiano ◽  
R. A. Morris ◽  
J. M. Van Doren
Keyword(s):  
Gas Phase ◽  
Superoxide Radical ◽  
Radical Anions ◽  
Gas Phase Reactions ◽  
Superoxide Radical Anions

Synthesis of selenoxides by oxidation of selenides with superoxide radical anions and 2-nitrobenzenesulfonyl chloride

2005 ◽  
Vol 46 (31) ◽  
pp. 5165-5168 ◽  
Author(s):  
Marcello Tiecco ◽  
Lorenzo Testaferri ◽  
Andrea Temperini ◽  
Raffaella Terlizzi ◽  
Luana Bagnoli ◽  
...  
Keyword(s):  
Superoxide Radical ◽  
Radical Anions ◽  
Superoxide Radical Anions

Superoxide radical anions protect enkephalin from oxidation if the amine group is blocked

2007 ◽  
Vol 43 (2) ◽  
pp. 229-240 ◽  
Author(s):  
Olivier Mozziconacci ◽  
Jacek Mirkowski ◽  
Filippo Rusconi ◽  
Pascal Pernot ◽  
Krzysztof Bobrowski ◽  
...  
Keyword(s):  
Superoxide Radical ◽  
Radical Anions ◽  
Amine Group ◽  
Superoxide Radical Anions
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