Preparing bulk ultrafine-microstructure high-entropy alloys via direct solidification

Nanoscale ◽  
2018 ◽  
Vol 10 (4) ◽  
pp. 1912-1919 ◽  
Author(s):  
Yiping Lu ◽  
Xiaoxia Gao ◽  
Yong Dong ◽  
Tongmin Wang ◽  
Hai-Lin Chen ◽  
...  

In the past three decades, nanostructured (NS) and ultrafine-microstructure (UFM) materials have received extensive attention due to their excellent mechanical properties such as high strength.

2014 ◽  
Vol 1036 ◽  
pp. 101-105
Author(s):  
Gheorghe Buluc ◽  
Iulia Florea ◽  
Oana Bălţătescu ◽  
Costel Roman ◽  
Ioan Carcea

This paper presents the microstructure and the mechanical properties of FeNiCrCuAl high entropy alloys. The microstructure and mechanical properties of the annealed FeNiCrCuAl high entropy alloys were investigated using scanning electron microscopy, and X-ray diffraction. High entropy alloys have been known as a new type of materials and have been defined as having five or more principal elements, each one having a concentration between 5 and 35 at.%. Previous researches show that HEAs can be processed to form simple solid solution structures instead of intermetallics and other complicated compounds. This phenomenon is commonly attributed to the high configurational entropy in the solid solution state of HEAs. Furthermore, HEAs have also exhibited interesting properties such as high hardness and high strength, good thermal stability outstanding wear and oxidation resistance which offer great potential for engineering applications. The HEA systems explored in the past decade show that metallic elements are the most commonly used, e.g. Al, Cr, Fe, Co, Ni, Cu,Ti, etc. A wide range of HEAs exhibit high hardness, high strength, distinctive electrical and magnetic properties, high-temperature softening resistance, as well as favorable combination of compression strength and ductility. This combination of properties and the particular structures of HEAs are attractive for a number of potential engineering applications.


2018 ◽  
Vol 142 ◽  
pp. 03003 ◽  
Author(s):  
Xiang Yin ◽  
Shuqiong Xu

As a consequence of multi-components, the high entropy alloys embodied serious cocktail party effect and lattice distortion. So high entropy alloys have high strength and hardness possess many comprehensive properties such as thermostability and corrosion resistance. Because of excellent mechanical properties and chemical properties, high entropy alloys have immeasurable potential of development. This paper mainly introduces the properties, preparations and applications of high entropy alloys, and finally summarizes them.


2021 ◽  
Vol 64 (4) ◽  
pp. 249-258
Author(s):  
K. A. Osintsev ◽  
V. E. Gromov ◽  
S. V. Konovalov ◽  
Yu. F. Ivanov ◽  
I. A. Panchenko

The article considers a brief review of the foreign publications on the study of the structure, phase composition and properties of five-component high-entropy alloys (HEAs) in different structural states in a wide temperature range over the past two decades. HEAs attract the attention of scientists with their unique and unusual properties. The difficulties of comparative analysis and generalization of data are noted due to different methods of obtaining HEAs, modes of mechanical tests for uniaxial compression and tension, sizes and shapes of the samples, types of thermal treatments, and phase composition (bcc and fcc crystal lattices). It is noted that the HEA with a bcc lattice has mainly high strength and low plasticity, and the HEA  with a fcc lattice has low strength and increased plasticity. A significant increase in the properties of the FeMnCoCrNi HEA with a fcc lattice can be achieved by alloying with boron and optimizing the parameters of thermal mechanical treatment at alloying with carbon in the amount of 1 % (at.). The deformation curves analyzed in the temperature range –196 ÷ 800 °C indicate an increase in the yield strength with a decrease in the grain size from 150 to 5 microns. As the temperature decreases, the yield strength and elongation increase. The effect of deformation rate on the mechanical properties is an increase in the ultimate strength and yield strength, which is most noticeable at high rates of 10–2 ÷ 103 s–1. The features of HEAs deformation behavior in the mono- and poly-crystalline states are noted. The complex of high operational properties of HEAs makes it possible to use them in various industries. There are good prospects of using energy treatment to modify the surface layers and further improve HEAs properties.


Nanoscale ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 3965-3976 ◽  
Author(s):  
Gang Qin ◽  
Ruirun Chen ◽  
Peter K. Liaw ◽  
Yanfei Gao ◽  
Liang Wang ◽  
...  

High-entropy alloys (HEAs) with good ductility and high strength are usually prepared by a combination of forging and heat-treatment processes.


Author(s):  
Gangjie Luo ◽  
Li Li ◽  
Qihong Fang ◽  
Jia Li ◽  
Yuanyuan Tian ◽  
...  

AbstractHigh entropy alloys (HEAs) attract remarkable attention due to the excellent mechanical performance. However, the origins of their high strength and toughness compared with those of the traditional alloys are still hardly revealed. Here, using a microstructure-based constitutive model and molecular dynamics (MD) simulation, we investigate the unique mechanical behavior and microstructure evolution of FeCoCrNiCu HEAs during the indentation. Due to the interaction between the dislocation and solution, the high dislocation density in FeCoCrNiCu leads to strong work hardening. Plentiful slip systems are stimulated, leading to the good plasticity of FeCoCrNiCu. The plastic deformation of FeCoCrNiCu is basically affected by the motion of dislocation loops. The prismatic dislocation loops inside FeCoCrNiCu are formed by the dislocations with the Burgers vectors of $${a \over 6}\left[ {\bar 11\bar 2} \right]$$ a 6 [ 1 ¯ 1 2 ¯ ] and $${a \over 6}\left[ {1\bar 12} \right]$$ a 6 [ 1 1 ¯ 2 ] , which interact with each other, and then emit along the 〈111〉 slip direction. In addition, the mechanical properties of FeCoCrNiCu HEA can be predicted by constructing the microstructure-based constitutive model, which is identified according to the evolution of the dislocation density and the stress-strain curve. Strong dislocation strengthening and remarkable lattice distortion strengthening occur in the deformation process of FeCoCrNiCu, and improve the strength. Therefore, the origins of high strength and high toughness in FeCoCrNiCu HEAs come from lattice distortion strengthening and the more activable slip systems compared with Cu. These results accelerate the discovery of HEAs with excellent mechanical properties, and provide a valuable reference for the industrial application of HEAs.


2020 ◽  
Vol 2020 (4) ◽  
pp. 16-22
Author(s):  
A.I. Ustinov ◽  
◽  
V.S. Skorodzievskii ◽  
S.A. Demchenkov ◽  
S.S. Polishchuk ◽  
...  

2021 ◽  
Vol 282 ◽  
pp. 128736 ◽  
Author(s):  
Qingkai Shen ◽  
Xiangdong Kong ◽  
Xizhang Chen ◽  
Xukai Yao ◽  
Vladislav B. Deev ◽  
...  

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4223
Author(s):  
Po-Sung Chen ◽  
Yu-Chin Liao ◽  
Yen-Ting Lin ◽  
Pei-Hua Tsai ◽  
Jason S. C. Jang ◽  
...  

Most high-entropy alloys and medium-entropy alloys (MEAs) possess outstanding mechanical properties. In this study, a series of lightweight nonequiatomic Al50–Ti–Cr–Mn–V MEAs with a dual phase were produced through arc melting and drop casting. These cast alloys were composed of body-centered cubic and face-centered cubic phases. The density of all investigated MEAs was less than 5 g/cm3 in order to meet energy and transportation industry requirements. The effect of each element on the microstructure evolution and mechanical properties of these MEAs was investigated. All the MEAs demonstrated outstanding compressive strength, with no fractures observed after a compressive strain of 20%. Following the fine-tuning of the alloy composition, the Al50Ti20Cr10Mn15V5 MEA exhibited the most compressive strength (~1800 MPa) and ductility (~34%). A significant improvement in the mechanical compressive properties was achieved (strength of ~2000 MPa, strain of ~40%) after annealing (at 1000 °C for 0.5 h) and oil-quenching. With its extremely high specific compressive strength (452 MPa·g/cm3) and ductility, the lightweight Al50Ti20Cr10Mn15V5 MEA demonstrates good potential for energy or transportation applications in the future.


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