The electron injection rate in CdSe quantum dot sensitized solar cells: from a bifunctional linker and zinc oxide morphology

Nanoscale ◽  
2017 ◽  
Vol 9 (43) ◽  
pp. 16806-16816 ◽  
Author(s):  
Wei-Lu Ding ◽  
Xing-Liang Peng ◽  
Zhu-Zhu Sun ◽  
Ze-Sheng Li
Keyword(s):  
Zinc Oxide ◽  
Solar Cells ◽  
Quantum Dot ◽  
Electron Injection ◽  
Injection Rate ◽  
Cdse Qds ◽  
Oxide Morphology ◽  
Cdse Quantum Dot ◽  
Sensitized Solar Cells

L1 mediated ZnO-NWs and CdSe QDs achieving an ultrafast electron injection on the order of hundreds of femtoseconds.

scholarly journals A Suitable Polysulfide Electrolyte for CdSe Quantum Dot-Sensitized Solar Cells

2013 ◽  
Vol 2013 ◽  
pp. 1-10 ◽  
Author(s):  
H. K. Jun ◽  
M. A. Careem ◽  
A. K. Arof
Keyword(s):  
Solar Cells ◽  
Quantum Dot ◽  
Liquid Electrolyte ◽  
Solvent Ratio ◽  
Cdse Qds ◽  
Pure Ethanol ◽  
Cell Efficiency ◽  
Polysulfide Electrolyte ◽  
Cdse Quantum Dot ◽  
Sensitized Solar Cells

A polysulfide liquid electrolyte is developed for the application in CdSe quantum dot-sensitized solar cells (QDSSCs). A solvent consisting of ethanol and water in the ratio of 8 : 2 by volume has been found as the optimum solvent for preparing the liquid electrolytes. This solvent ratio appears to give higher cell efficiency compared to pure ethanol or water as a solvent. Na2S and S give rise to a good redox couple in the electrolyte for QDSSC operation, and the optimum concentrations required are 0.5 M and 0.1 M, respectively. Addition of guanidine thiocyanate (GuSCN) to the electrolyte further enhances the performance. The QDSSC with CdSe sensitized electrode prepared using 7 cycles of successive ionic layer adsorption and reaction (SILAR) produces an efficiency of 1.41% with a fill factor of 44% on using a polysulfide electrolyte of 0.5 M Na2S, 0.1 M S, and 0.05 M GuSCN in ethanol/water (8 : 2 by volume) under the illumination of 100 mW/cm2white light. Inclusion of small amount of TiO2nanoparticles into the electrolyte helps to stabilize the polysulfide electrolyte and thereby improve the stability of the CdSe QDSSC. The CdSe QDs are also found to be stable in the optimized polysulfide liquid electrolyte.

scholarly journals Effect of CdS/Mg-Doped CdSe Cosensitized Photoanode on Quantum Dot Solar Cells

2015 ◽  
Vol 2015 ◽  
pp. 1-6
Author(s):  
Yingxiang Guan ◽  
Xiaoping Zou ◽  
Sheng He
Keyword(s):  
Quantum Dots ◽  
Solar Cells ◽  
Quantum Dot ◽  
High Performance ◽  
Low Cost ◽  
Energy Conversion Efficiency ◽  
Cdse Qds ◽  
Cdse Quantum Dot ◽  
Sensitized Solar Cells ◽  
Mg Doped

Quantum dots have emerged as a material platform for low-cost high-performance sensitized solar cells. And doping is an effective method to improve the performance of quantum dot sensitized solar cells (QDSSCs). Since Kwak et al. from South Korea proved the incorporation of Mg in the CdSe quantum dots (QDs) in 2007, the Mg-doped CdSe QDs have been thoroughly studied. Here we report a new attempt on CdS/Mg-doped CdSe quantum dot cosensitized solar cells (QDCSSC). We analyzed the performance of CdS/Mg-doped CdSe quantum dot cosensitized solar cells via discussing the different doping concentration of Mg and the different SILAR cycles of CdS. And we studied the mechanism of CdS/Mg-doped CdSe QDs in detail for the reason why the energy conversion efficiency had been promoted. It is a significant instruction on the development of Mg-doped CdSe quantum dot sensitized solar cells (QDSSCs).

Anisotropic Nanostructure ZnO Photoelectrodes for CdS/CdSe Quantum Dot Sensitized Solar Cells

2013 ◽  
Vol 873 ◽  
pp. 556-561
Author(s):  
Jian Jun Tian
Keyword(s):  
Quantum Dots ◽  
Solar Cells ◽  
Quantum Dot ◽  
Chemical Bath Deposition ◽  
Cdse Quantum Dots ◽  
Silar Method ◽  
Nanorods Array ◽  
Cdse Quantum Dot ◽  
Cbd Method ◽  
Sensitized Solar Cells

CdS/CdSe quantum dots co-sensitized solar cells (QDSCs) were prepared by combining the successive ion layer absorption and reaction (SILAR) method and chemical bath deposition (CBD) method for the fabrication of CdS and CdSe quantum dots, respectively. In this work, we designed anisotropic nanostructure ZnO photoelectrodes, such as nanorods/nanosheets and nanorods array, for CdS/CdSe quantum dots co-sensitized solar cells. Our study revealed that the performance of QDSCs could be improved by modifying surface of ZnO to increase the loading of quantum dots and reduce the charge recombination.

Influence of Electron Injection Rate in Triphenylamine Based Dye for Dye-Sensitized Solar Cells: A First Principle Study

2019 ◽  
Vol 233 (9) ◽  
pp. 1247-1259
Author(s):  
Madhu Prakasam
Keyword(s):  
Solar Cells ◽  
Absorption Spectra ◽  
Density Functional ◽  
Dye Sensitized Solar Cells ◽  
Visible Region ◽  
Electron Injection ◽  
Injection Rate ◽  
Visible Absorption ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Abstract In this work, we systematically investigate the impacts of electron-donor based on Triphenylamine (TPA). The Geometry structure, energy levels, light-harvesting ability and ultraviolet-visible absorption spectra were calculated by using Density Functional Theory (DFT) and Time-Dependent-DFT. The electron injection rate of the TPA-N(CH3)2 based dyes has 0.71 eV for high among the dye sensitizer. The First and Second order Hyperpolarizability of the 11.95 × 10−30 e.s.u and 12195.54 a.u, respectively for TPA-N(CH3)2 based dye. The calculated absorption spectra were showed in the ultra-violet visible region for power conversion region. The study reveals that the electron transfer character of TPA-N(CH3)2 based dyes can be made suitable for applications in Dye-Sensitized Solar Cells.

Efficient CdSe Quantum Dot-Sensitized Solar Cells Prepared by an Improved Successive Ionic Layer Adsorption and Reaction Process

Nano Letters ◽  
2009 ◽  
Vol 9 (12) ◽  
pp. 4221-4227 ◽  
Author(s):  
HyoJoong Lee ◽  
Mingkui Wang ◽  
Peter Chen ◽  
Daniel R. Gamelin ◽  
Shaik M. Zakeeruddin ◽  
...  
Keyword(s):  
Solar Cells ◽  
Quantum Dot ◽  
Reaction Process ◽  
Layer Adsorption ◽  
Cdse Quantum Dot ◽  
Sensitized Solar Cells ◽  
Ionic Layer

Effect of Cu2+ ions doped on the photovoltaic features of CdSe quantum dot sensitized solar cells

2018 ◽  
Vol 282 ◽  
pp. 16-23 ◽  
Author(s):  
Tan Phat Nguyen ◽  
Thanh Tung Ha ◽  
Thu Thao Nguyen ◽  
Nhat Phuong Ho ◽  
Thanh Dat Huynh ◽  
...  
Keyword(s):  
Solar Cells ◽  
Quantum Dot ◽  
Cdse Quantum Dot ◽  
Sensitized Solar Cells
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