Voltage-activated transport of ions through single-walled carbon nanotubes

Nanoscale ◽  
2017 ◽  
Vol 9 (33) ◽  
pp. 11976-11986 ◽  
Author(s):  
Khadija Yazda ◽  
Saïd Tahir ◽  
Thierry Michel ◽  
Bastien Loubet ◽  
Manoel Manghi ◽  
...  

SWCNTs of diameter of 1.2 to 2 nm can show a linear or a voltage-activatedI–Vdependence.

MRS Advances ◽  
2016 ◽  
Vol 1 (28) ◽  
pp. 2085-2090 ◽  
Author(s):  
Khadija Yazda ◽  
Sophie Roman ◽  
Saïd Tahir ◽  
François Henn ◽  
Vincent Jourdain

ABSTRACTStudying the transport of ions through single-walled carbon nanotubes (SWCNTs) necessitate the fabrication of a fluidic setup integrating carbon nanotubes. In this article, we report on the development of a simple fabrication protocol of SWCNTs fluidic devices. This protocol allows an excellent control of the system features and of the experimental conditions compared with previously published protocols. Our protocol based on the use of the popular SU-8, the preferred photoresist for the fabrication of high-aspect-ratio patterns, allows one to prepare sealed microfluidic devices incorporating one or several tens of individual carbon nanotubes of length between 20 and 80 µm.


MRS Advances ◽  
2016 ◽  
Vol 1 (28) ◽  
pp. 2079-2084
Author(s):  
Khadija Yazda ◽  
Saïd Tahir ◽  
Thierry Michel ◽  
François Henn ◽  
Vincent Jourdain

ABSTRACTThe electrophoretic transport of ions through single walled carbon nanotubes (SWCNTs) of diameters between 1.2 and 1.8 nm was studied for different monovalent chloride salts using microfluidic devices incorporating either a single or few SWCNTs in parallel. The ionic conductance was found to be about one order of magnitude higher than would be expected from simple bulk electrophoresis without any surface effect. Importantly, the ionic conductance measured for different cations did not scale with their bulk electrophoretic mobility thus indicating a selective cation transport through these sub-2 nm SWCNTs. The transport of Na+ was notably found to be favored in comparison to that of Li+, K+ and Cs+. These results highlight the influence of steric and surface effects induced by the nano-confinement on the transport of ions through sub-2 nm SWCNTs.


2013 ◽  
Vol 51 (2) ◽  
pp. 137-144
Author(s):  
Naesung Lee ◽  
Jeung Choon Goak ◽  
Tae Yang Kim ◽  
Jongwan Jung ◽  
Young-Soo Seo ◽  
...  

2012 ◽  
Vol 2 (2) ◽  
pp. 200-209 ◽  
Author(s):  
Jurgen Bachl ◽  
Thimo Huber ◽  
Dennis Kuhbeck ◽  
Eva-Maria Schon ◽  
Gabriele Brunner ◽  
...  

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